Abstract
A thorough investigation is performed on the catalytic activity of aluminosilicate FSM’s, produced via a new successful short time synthesis route using leached saponite and low concentration of CTAB. The influence of an additional Al incorporation, utilizing sodium aluminate, aluminum nitrate, and aluminum isopropoxide is also studied.
The catalytic activity of the samples is tested in the hydroisomerization of octane. All the samples have a lower catalytic activity compared to the BETA zeolite, but, the combined selectivity to isomers and aromatics is better for the original acidified FSMSap H+ sample and the sample with additional incorporation of Al(NO3)3, which indicates to a certain extent, the suitability of these materials as reforming catalysts.
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References
C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, and J.S. Beck, Nature 359, 710 (1992).
S. Inagaki, Y. Fukushima, and K. Kuroda, J. Chem. Soc., Chem. Commun. 8, 680 (1993).
S. O’Brien, R.J. Francis, S.J. Price, D. O’Hare, S.M. Clark, N. Okazaki, and K. Kuroda, J. Chem. Soc., Chem. Comm. 2423 (1995).
R. Mokaya, J. Chem. Soc., Chem. Comm. 1891 (2000).
A. Corma, V. Fornés, M.T. Navarro, and J. Pérez-Pariente, J. Catal. 148, 569 (1994).
H. Kosslick, G. Lischke, B. Parlitz, W. Storek, and R. Fricke, Appl. Catal. A 184, 49 (1999).
K.M. Reddy and C. Song, Catal. Lett. 36, 103 (1996).
S. Inagaki, Y. Yamada, and Y. Fukushima, in Progress in Zeolite and Microporous Materials, Studies in Surface Science and Catalysis, edited by H. Chon, S.-K. Ihm, and Y.S. Uh (Elsevier, Amsterdam, 1994), vol. 105, p. 109.
Q. Kan, V. Fornés, and F. Rey, A. Corma, Mater. Chem. 10, 993 (2000).
T. Linssen, M. Barroudi, P. Cool, and E.F. Vansant, Zeolites and Mesoporous Materials at the Dawn of the 21st Century, Studies in Surface Science and Catalysis, edited by A. Galarneau, F. Di Renzo, F. Fajula, and J. Vedrine (Elsevier, Amsterdam, 2001), vol. 135, 06-P-15.
A. Sayari, Chem. Mater. 8, 1480 (1996).
R. Mokaya and W.J. Jones, Chem. Soc., Chem. Commun. 983 (1996).
A. Corma, M.S. Grande, V. Gonzales-Alfaro, and A.V. Orchilles, J. Catal. 159, 375 (1996).
T. Linssen, P. Cool, M. Baroudi, K. Cassiers, E.F. Vansant, O. Lebedev, and J. Van Landuyt, J. Phys. Chem. B 106, 4470 (2002).
T. Linssen, K. Cassiers, P. Cool, E.F. Vansant, and O. Lebedev, Chem. Mater. 15(25), 4863 (2003).
T. Linssen, F. Mees, K. Cassiers, P. Cool, A. Whittaker, and E.F. Vansant, J. Phys. Chem. B 107, 8599 (2003).
D. Zhao, C. Nie, Y. Zhou, S. Xia, L. Huang, and Q. Li, Catal. Today 68, 11 (2001).
H. Koch, U. Böhmer, A. Klemt, W. Reschetilowski, and M. Stöcker, J. Chem. Soc. Faraday Trans. 94(6), 817 (1998).
R. Mokaya, W. Jones, S. Moreno, and G. Poncelet, Catal. Letters 49, 87 (1997).
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Linssen, T., Cool, P., Vansant, E.F. et al. Octane Hydroisomerization Over Hexagonal Mesoporous Aluminosilicates Synthesized from Leached Saponite. J Porous Mater 12, 35–40 (2005). https://doi.org/10.1007/s10934-005-5231-2
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DOI: https://doi.org/10.1007/s10934-005-5231-2