Identification of Commercial Oxo-Biodegradable Plastics: Study of UV Induced Degradation in an Effort to Combat Plastic Waste Accumulation


End of life single-use items such as carrier bags constitute a large proportion of the litter found in marine and terrestrial environments. The main objective of the current work was to investigate the response of an oxo-biodegradable commercial plastic film product to photo-degradation using accelerated weathering, verifying the claim of its biodegradability and suitability as an eco-friendly product. This study is also geared towards the appropriateness of such products to reduce plastic waste accumulation in urban environments. The film samples were exposed to weathering as a means to determine the impact of UV induced oxo-biodegradation. Haze (%), light transmission (%) and the total change in colour (ΔE) were measured as indicators to the degradation profile of the polymeric materials, in addition to tensile pull mechanical properties and thermal stability. The melting peak indicates the melting point (Tm) of the polymer and with exposure to weathering it showed a slight decrease from 105 to 102 °C indicating that biodegradation mechanisms were triggered to a certain extent. The reduction in strain at rupture was also indicative for a loss in crystalline structure, coupled with Young’s modulus increase throughout the weathering exposure tests. Therefore, the material studied could be a candidate to mitigate the accumulation of plastic waste in open environments based on the results of this study whilst regulating controlled substances.

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  1. 1.

    Plastics Europe (2018) Plastics-the facts 2017. Plastics Europe, Brussels

    Google Scholar 

  2. 2.

    UNEP (2018) Single-use plastics: a roadmap for sustainability. UN Environment Programme, Nairobi

    Google Scholar 

  3. 3.

    Napper I, Thompson R (2019) Environ Sci Tech 53:4783

    Article  CAS  Google Scholar 

  4. 4.

    Dumas D (2007) Ecologist 37:37

    Google Scholar 

  5. 5.

    Clapp J, Swanston L (2009) Environ Politic 18:315

    Article  Google Scholar 

  6. 6.

    Brems A, Baeyens J, Dewil R (2012) Therm Sci 16:669

    Article  Google Scholar 

  7. 7.

    Siotto M, Sezenna E, Saponaro S, Innocenti F, Tosin M, Bonomo L, Mezzanotte V (2012) J Environ Mange 93:31

    CAS  Article  Google Scholar 

  8. 8.

    Oxo-biodegradable plastics association (2008). Available at:

  9. 9.

    Al-Salem S, Al-Hazza'a A, Karam H, Al-Wadi M, Al-Dhafeeri A, Al-Rowaih A (2019) J Environ Manag 250:109475

    CAS  Article  Google Scholar 

  10. 10.

    Chinaglia S, Tosin M, Degli-Innocenti F (2018) Polym Degrad Stab 147:237

    CAS  Article  Google Scholar 

  11. 11.

    Anstey A, Muniyasamy S, Reddy M, Misra M, Mohanty A (2014) J Polym Environ 22:209

    CAS  Article  Google Scholar 

  12. 12.

    Burgos N, Valdés A, Jiménez A (2016) J Renew Mater 4:165

    CAS  Article  Google Scholar 

  13. 13.

    Harrison J, Boardman C, O'Callaghan K, Delort A, Song J (2018) Royal Soc Open Sci 5:171792

    Article  CAS  Google Scholar 

  14. 14.

    Nazareth M, Marques RC, Leite MCA, Castro IB (2019) J Hazard Mater 366:714

    CAS  PubMed  Article  Google Scholar 

  15. 15.

    Al-Salem SM (2009) Mater Des 30:1729

    CAS  Article  Google Scholar 

  16. 16.

    Al-Salem SM (2018) WIT Trans Ecol Environ 231:415

    Article  Google Scholar 

  17. 17.

    Al-Salem SM, Abraham G, Al-Qabandi OA, Dashti AM (2015) Polym Test 46:116

    CAS  Article  Google Scholar 

  18. 18.

    Vyazovkin S, Burnham AK, Criado JM, Pérez-Maqueda LA, Popescu C, Sbirrazzuoli N (2011) Thermochim Acta 520:1

    CAS  Article  Google Scholar 

  19. 19.

    Vyazovkin S, Chrissafis K, Di Lorenzo ML, Koga N, Pijolat M, Roduit B, Sbirrazzuoli N, Suñol JJ (2014) Thermochim Acta 590:1

    CAS  Article  Google Scholar 

  20. 20.

    Ojeda T, Freitas A, Birck K, Dalmolin E, Jacques R, Bento F, Camargo F (2011) Polym Degrad Stab 96:703

    CAS  Article  Google Scholar 

  21. 21.

    D’Amelia RP, Gentile S, Nirode WF, Huang L (2016) World J Chem Educ 4:25–31

    Google Scholar 

  22. 22.

    Abed RMM, Al Khaburi TMM, Al-Senafi F, Munam A, Mahmoud H (2020) Mar Pollut Bull 150:110639

    PubMed  Article  CAS  Google Scholar 

  23. 23.

    Nikolić MAL, Gauthier E, Colwell JM, Halley P, Bottle SE, Laycock B (2017) Rowan Truss. Polym Degrad Stab 145:102

    Article  CAS  Google Scholar 

  24. 24.

    Al-Salem SM, Al-Nasser AY, Behbehani MH, Sultan HH, Karam HJ, Al-Wadi MH, Al-Dhafeeri AT, Rasheed Z, Al-Foudaree M (2019) Int J Polym Sci 2019:15

    Article  CAS  Google Scholar 

  25. 25.

    Küpper L, Gulmine J, Janissek P, Heise H (2004) Vibration Spec 34:63

    Article  CAS  Google Scholar 

  26. 26.

    Davis G (2006) Mater Charac 57:314

    CAS  Article  Google Scholar 

  27. 27.

    Ojeda T, Dalmolin E, Forte M, Jacques R, Bento F, Camargo F (2009) Polym Degrad Stab 94:965

    CAS  Article  Google Scholar 

  28. 28.

    Ammala A, Bateman S, Dean K, Petinakis E, Sangwan P, Wong S, Yuan Q, Yu L, Patrick C, Leong K (2011) Prog Polym Sci 36:1015

    CAS  Article  Google Scholar 

  29. 29.

    European Parliament and Council Directive 94/62/EC (1994) on packaging and packaging waste

  30. 30.

    Contat-Rodrigo L (2013) Polym Degrad Stab 98:2117

    CAS  Article  Google Scholar 

  31. 31.

    Guadagno L, Naddeo C, Vittoria V, Camino G, Cagnani C (2001) Polym Degrad Stab 72:175

    CAS  Article  Google Scholar 

  32. 32.

    Corti A, Muniyasamy S, Vitali M, Imam S, Chiellini E (2010) Polym Degrad Stab 95:1106

    CAS  Article  Google Scholar 

  33. 33.

    Mendes LC, Rufino ES, de Paula FOC, Torres AC (2003) Polym Degrad Stab 79:371

    CAS  Article  Google Scholar 

  34. 34.

    Al-Salem S, Sultan H, Karam H, Al-Dhafeeri A (2019) J Polym Res 26:157

    Article  CAS  Google Scholar 

  35. 35.

    Bonhomme S, Cuer A, Delort A, Lemaire J, Sancelme M, Scott G (2003) Polym Degrad Stab 81:441

    CAS  Article  Google Scholar 

  36. 36.

    Sudhakar M, Doble M, Murthy PS, Venkatesan R (2008) Int Biodeterior Biodegrad 61:203

    CAS  Article  Google Scholar 

  37. 37.

    Hopewell J, Dvorak R, Kosior E (2009) Philos Trans R Soc B 364:2115

    CAS  Article  Google Scholar 

  38. 38.

    Barnes DKA, Galgani F (2009) Philos Trans R Soc B 364:1985

    CAS  Article  Google Scholar 

  39. 39.

    Scott G (2000) Polym Degrad Stab 68:1

    CAS  Article  Google Scholar 

  40. 40.

    Webb H, Arnott J, Crawford R, Ivanova E (2012) Polymers 5:1

    Article  CAS  Google Scholar 

  41. 41.

    Singh B, Sharma N (2008) Polym Degrad Stab 93:561

    CAS  Article  Google Scholar 

  42. 42.

    Musioł M, Rydz J, Janeczek H, Radeck I, Jiang G, Kowalczuk M (2017) Waste Manag 64:20

    PubMed  Article  CAS  Google Scholar 

  43. 43.

    Viera JSC, Marques MRC, Nazareth NC, Jimenez PC, Castro IB (2020) Enviorn Sci Policy 106:177

    Article  Google Scholar 

  44. 44.

    EC (2018) Report from the commission to the European parliament and the council on the impact of the use of oxo-degradable plastic, including oxo-degradable plastic carrier bags, on the environment. Brussels 16(1):2018

    Google Scholar 

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The authors are grateful to the support given to this research work by the Kuwait Institute for Scientific Research (KISR) and Kuwait University (KUniv).

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AA: Data Analysis and Original Draft Preparation; AC: Draft Review; AB: Draft Review, GM: Draft Review, RD: Draft Review, SA-S: Conceptualization, Data Analysis, Fund Acquisition, and Draft Review.

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Correspondence to S. M. Al-Salem.

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Antelava, A., Constantinou, A., Bumajdad, A. et al. Identification of Commercial Oxo-Biodegradable Plastics: Study of UV Induced Degradation in an Effort to Combat Plastic Waste Accumulation. J Polym Environ (2020).

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  • Plastic film
  • Oxo-biodegradable
  • Colour
  • Haze
  • TGA