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Journal of Polymers and the Environment

, Volume 26, Issue 7, pp 3040–3050 | Cite as

Urea Formaldehyde and Cellulose Nanocrystals Adhesive: Studies Applied to Sugarcane Bagasse Particleboards

  • Ricardo Gabriel de Almeida Mesquita
  • Lourival Marin Mendes
  • Anand Ramesh Sanadi
  • Alfredo Rodrigues de Sena Neto
  • Pedro Ivo Cunha Claro
  • Ana Carolina Corrêa
  • José Manoel Marconcini
Original Paper
  • 238 Downloads

Abstract

The aim of this research was to investigate the behavior of urea formaldehyde (UF) adhesive based particleboards using sugarcane bagasse (SCB), with and without the addition of cellulose nanocrystals (NCC). In the first step of this research study, the interaction between UF and the NCC was evaluated. The NCC were dispersed in the UF, in different proportions (0, 0.5, 1, 2, 3 and 5%). Subsequent to this, the mixtures were dried, milled, and put in molds, to produce flexural specimens. The second step involved evaluation of the interaction between the NCC, UF, and SCB. After sonication, the NCC and UF were applied on the SCB particles to produce particleboards. They were evaluated according to the modulus of elasticity and rupture, water absorption (WA), and thickness swelling. The viscosity of the mixture of NCC and UF increased according to the NCC increase load. At 5% of NCC load, the viscosity increased greatly, which prevented adhesive dispersion in the particleboard. The thermogravimetric analysis of UF showed that better conditions of processing were at 160 °C for 8 min, so these parameters were used to produce the specimens. SCB is a promising raw material for particleboard, and its potential to produce SCB particleboards with relatively good performance was demonstrated. For the particleboards specimens, the best performance was observed with 1% of NCC. Particleboards did not show improvement compared with UF specimens, probably because bond links were not sufficient. Addition of NCC in UF increased the liquid suspension viscosity, and the specimens showed a better mechanical performance.

Keywords

Natural fiber Amino resin Chipboards Thermosetting Nanotechnology 

Notes

Acknowledgements

The authors are grateful for the support of Coordenação de Aperfeiçoamento de pessoal de Nível Superior (CAPES), Fundação de Amparo à Pesquisa do Estado de Minas Gerais (Fapemig), Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq), RELIGAR, Embrapa Instrumentação, Federal University of Lavras (UFLA), and University of Copenhagen.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Ricardo Gabriel de Almeida Mesquita
    • 1
  • Lourival Marin Mendes
    • 2
  • Anand Ramesh Sanadi
    • 3
  • Alfredo Rodrigues de Sena Neto
    • 4
  • Pedro Ivo Cunha Claro
    • 5
  • Ana Carolina Corrêa
    • 6
  • José Manoel Marconcini
    • 6
  1. 1.Department of Forestry SciencesRural Federal University of the Amazonia (UFRA)Capitão PoçoBrazil
  2. 2.Department of Forestry SciencesFederal University of LavrasLavrasBrazil
  3. 3.Department of Geosciences and Natural Resource ManagementUniversity of Copenhagen Faculty of ScienceFrederiksberg CDenmark
  4. 4.Department of EngineeringFederal University of LavrasLavrasBrazil
  5. 5.Federal University of São CarlosSão CarlosBrazil
  6. 6.LNNA, Brazilian Agricultural Research Corporation (EMBRAPA Instrumentação)São CarlosBrazil

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