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Journal of Polymers and the Environment

, Volume 26, Issue 7, pp 2825–2844 | Cite as

Reuse of Selected Lignocellulosic and Processed Biomasses as Sustainable Sources for the Fabrication of Nanocellulose via Ni(II)-Catalyzed Hydrolysis Approach: A Comparative Study

  • Mazlita Yahya
  • You Wei Chen
  • Hwei Voon Lee
  • Wan Hasamudin Wan Hassan
Original Paper

Abstract

This study investigates for the first time the feasibility of isolating nanocellulose from several selected feedstocks via a novel Ni(II)-hydrolysis process, including lignocellulosic biomasses (oil palm trunk, banana peel and coconut husk) and processed biomasses (newspaper, tissue paper and cotton linter), with an obtained gravimetric yield ranging from 59.6 to 86.2%. The isolation of nanocellulose products from these selected feedstocks was verified by the successive removal of most of their non-cellulosic components (lignin and hemicellulose) and cellulose amorphous regions, the increase in the crystallinity index and the nanoscale of the individual crystals. Most importantly, the resultant nanocellulose products rendered better thermal stability than that of corresponding original sources, which are highly potential to be utilized as the new renewable sources of reinforcement materials with potential applications in bio-nanocomposites and thermoplastics. Therefore, this work proves the viability of direct production of nanocellulose from a variety of cellulosic sources by using Ni(II)-based transition metal salt catalyst. The results suggested that the concept of waste to wealth could be well executed from the obtained nanocellulose, which are greatly potential for various industrial applications.

Keywords

Lignocellulosic biomass Transition metal salt catalyst Cellulose nanocrystals Processed waste Thermal characterization 

Notes

Acknowledgements

The authors are grateful for the financial support from SATU Joint Research Scheme (ST015-2017) and University of Malaya, Postgraduate Research Grant Scheme PPP (PG063-2015A, PG079-2014B). We are also acknowledged for cordial support from Malaysian Palm Oil Board (MPOB). The authors would like to gratefully acknowledge the expert guidance and support from late Professor Sharifah Bee Abd Hamid throughout the study.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • Mazlita Yahya
    • 1
  • You Wei Chen
    • 1
  • Hwei Voon Lee
    • 1
  • Wan Hasamudin Wan Hassan
    • 2
  1. 1.Nanotechnology & Catalysis Research Centre (NANOCAT), Institute of Postgraduate StudiesUniversity of MalayaKuala LumpurMalaysia
  2. 2.Malaysian Palm Oil Board (MPOB)Persiaran Institusi Bandar Baru BangiKajangMalaysia

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