Fiber from DDGS and Corn Grain as Alternative Fillers in Polymer Composites with High Density Polyethylene from Bio-based and Petroleum Sources

Original Paper

Abstract

The steady increase in production of corn based ethanol fuel has dramatically increased the supply of its major co-product known as distiller’s dried grain with solubles (DDGS). Large amount of DDGS and corn flour are used as an animal feed. The elusieve process can separate DDGS or corn flour into two fractions: DDGS fraction with enhanced protein and oil content or corn flour fraction with high starch content, and hull fiber. This study investigated the feasibility of using fiber from DDGS and corn grain as alternative fillers to wood fiber in high density polyethylene (HDPE) composites made with two different sources of polymers. Two fiber loading rates of 30 and 50% were evaluated for fiber from DDGS, corn, and oak wood (control) to assess changes in various physical and mechanical properties of the composite materials. Two HDPE polymers, a bio-based HDPE made from sugarcane (Braskem), and a petroleum based HDPE (Marlex) were also compared as substrates. The biobased polymer composites with DDGS and corn fibers showed significantly lower water absorption than the Marlex composite samples. The Braskem composite with 30% DDGS fiber loading showed the highest impact resistance (80 J/m) among all the samples. The flexural properties showed no significant difference between the two HDPE composites.

Keywords

Biofillers Distillers dried grain with solubles Bio based high density polyethylene Dynamic mechanical analysis Flexural property 

Notes

Acknowledgements

The authors gratefully acknowledge North Dakota Corn Utilization Council for funding this research project (Grant No. FAR0021049). We would also like to acknowledge Sujal Bhattacharjee, a graduate student from NDSU for his help with sample preparations.

References

  1. 1.
    Klopfenstein TJ, Erickson GE, Berger LL (2013) Field Crop Res 153:5CrossRefGoogle Scholar
  2. 2.
    Dinneen B (2014) Renew Fuels Assoc http://www.ethanolrfa.org/. Accessed 15 Aug 2016
  3. 3.
    Belyea RL, Rausch KD, Tumbleson ME (2004) Bioresour Technol 94:293CrossRefGoogle Scholar
  4. 4.
    Cheesbrough V, Rosentrater KA, Visser J (2008) J Polym Environ 16:40CrossRefGoogle Scholar
  5. 5.
    Rosentrater KA, Muthukumarappan K (2006) Int Sugar J 108:645Google Scholar
  6. 6.
    Shurson GC (2002) The value and use of distiller’s dried grains with solubles (DDGS) in swine diets. Carolina Nutrition Conference, Raleigh, NCGoogle Scholar
  7. 7.
    Srinivasan R, Moreau RA, Rausch KD, Belyea RL, Tumbleson ME, Singh V (2005) Cereal Chem 82:528CrossRefGoogle Scholar
  8. 8.
    Srinivasan R, Yadav MP, Belyea RL, Rausch KD, Pruiett LE, Johnston DB, Tumbleson ME, Singh V (2008) Biol Eng 1:39CrossRefGoogle Scholar
  9. 9.
    Kim E, Parsons C, Singh V (2007) Poult Sci 86:397Google Scholar
  10. 10.
    Loar RE, Srinivisan R, Dozier WA III, Kidd MT, Corzo A (2008) Poult Sci 87:28Google Scholar
  11. 11.
    Gurunathan T, Mohanty S, Nayak SK (2015) Comp Part A 77:1CrossRefGoogle Scholar
  12. 12.
    Ahmad F, Choi HS, Park MK (2015) Macromol Mater Eng 300:10CrossRefGoogle Scholar
  13. 13.
    Thakur VK, Thakur MK, Gupta RK (2014) Int J Polym Anal Charact 19:256CrossRefGoogle Scholar
  14. 14.
    Xie Y, Hill CA, Xiao Z, Militz H, Mai C (2010) Compos Part A 41(7):806–819CrossRefGoogle Scholar
  15. 15.
    Thakur VK, Thakur MK, Gupta RK (2014) Carbohydr Polym 104:87–93CrossRefGoogle Scholar
  16. 16.
    Li X, Tabil LG, Panigrahi S (2007) J Polym Environ 15(1):25–33CrossRefGoogle Scholar
  17. 17.
    Adekunle KF (2015) Open J Polym Chem 5(03):41CrossRefGoogle Scholar
  18. 18.
    Li Y, Sun XS (2010) J Appl Polym Sci 121:589CrossRefGoogle Scholar
  19. 19.
    Muniyaswamy S, Reddy MM, Misra M, Mohanty A (2013) Ind Crops Prod 43:812CrossRefGoogle Scholar
  20. 20.
    Bajwa SG, Bajwa DS, Holt G, Coffelt T, Nakayama F (2011) Ind Crops Prod 33(3):747CrossRefGoogle Scholar
  21. 21.
    Liang G, Xu J, Bao S, Xu W (2004) J Appl Polym Sci 91:3974CrossRefGoogle Scholar
  22. 22.
    Sanadi AR, Caulfield DF, Jacobson RE, Rowell RM (1995) Ind Eng Chem Res 34:1889Google Scholar
  23. 23.
    Bismarck A, Askargorta IA, Springer J, Lampke T, Wielage B, Stamboulis A (2002) Polym Compos 23:872Google Scholar
  24. 24.
    Zabihzadeh SM (2010) Bio Resour 5:316CrossRefGoogle Scholar
  25. 25.
    Tisserat B, Reifschneider L, Kuru RHO, Finkenstadt VL (2013) Bio Resour 8:59CrossRefGoogle Scholar
  26. 26.
    Thwe MM, Liao K (2003) J Mater Sci Lett 38:363CrossRefGoogle Scholar
  27. 27.
    Singh S, Mohanty AK (2006) Compos Sci Technol 67:1753Google Scholar
  28. 28.
    Sewda K, Maiti SN (2009) J Appl Polym SciGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2017

Authors and Affiliations

  1. 1.Department of Agricultural & Biosystems EngineeringNorth Dakota State UniversityFargoUSA
  2. 2.Department of Mechanical EngineeringNorth Dakota State UniversityFargoUSA

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