Abstract
The objective of this work is to study the feasibility of reinforcing polymer composites by utilizing the biofibers from the agricultural residue of Moringa oleifera pod husks (MOPH). The chemical and physical properties of the fibers were comprehensively investigated to evaluate their potential as a filler in gelatin-based films. The effect of MOPH fiber concentrations of 0, 5, 10, and 15 wt% on the water vapor permeability (WVP), and mechanical and thermal properties of the gelatin-based films was studied. By incorporation of 10 wt% of the MOPH fibers in gelatin, the highest tensile strength and Young’s modulus, and the lowest WVP properties were obtained. Scanning electron microscopy (SEM) photographs indicated good interfacial adhesion between the fibers and the gelatin matrix. TGA of the biocomposites revealed an improvement of thermal stability. Moreover, under accelerated weathering, the gelatin-MOPH-10% biocomposite degraded more slowly than the gelatin control. These results indicate that the MOPH fibers are a good reinforcing filler and may be useful for biocomposite applications.
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Nur Hanani ZA, Roos YH, Kerry JP (2014) Int J Biol Macromol 71:94
Núnez-Flores R, Giménez B, Fernández-Martín F, López-Caballero ME, Montero MP, Gómez-Guillén MC (2012) Food Hydrocolloids 27:60
Zadeh E M, Yu A, Fu L, Dehghan M, Sbarski I, Harding I (2014) Polym Compos 35:2043
Bergo P, Sobral PJA (2007) Food Hydrocolloids 21:1285
Wang W, Wang Z, Liu Y, Li N, Wang W, Gao J (2012) Mater Res Bull 47:2245
Farahnaky A, Dadfar SMM, Shahbazi M (2014) J Food Eng 122:78
Panzavolta S, Bracci B, Gualandi C, Focarete ML, Treossi E, Kouroupis-Agalou K, Rubini K, Bosia F, Brely L, Pugno NM, Palermo V, Bigi A (2014) Carbon 78:566
Yu G, Jialiang W, Zixing S, Jie Y (2012) J Mater Chem 22:19
Ran J, Hu J, Chen L, Shen X, Tong H (2015) Polym Compos. doi:10.1002/pc.23725.
Choi HY, Han SO, Lee JS (2008) Appl Surf Sci 255:2466
Chiellini E, Cinelli P, Fernandes EG, Kenawy ERS, Lazzeri A (2001) Biomacromolecules 2:806
Takinami PYI, Shimazaki K, Colombo MA, de Moura EAB, del Mastro NL (2010) Rev Mater 15:303
Inamura PY, Kraide FH, Drumond WS, de Lima NB, Moura EAB, del Mastro NL (2013) Radiat Phys Chem 84:66
Zheng X, Liu J, Pei Y, Li J, Tang K (2012) Compos Part A 43:45
Borugadda VB, Goud VV (2012) Renew Sustain Energy Rev 16:4763
Hernández E, García A, López M, Puls J, Paraja JC, Martín C (2013) Ind Crops Prod 44:227
Akhtar M, Hasany SM, Bhanger MI, Iqbal S (2007) J Hard Mater 141:546
Kumar MA, Reddy GR, Rao HR, Reddy KH, Reddy BHN (2012) Int J Polym Mater 61:759
Ge L, Li X, Zhang R, Yang T, Ye X, Li D (2015) Food Hydrocolloids 51:129
Chiou B-S, Avena-Bustillos RJ, Bechtel PJ, Jafri H, Narayan R, Imam SH, Glenn GM, Orts WJ (2008) Eur Polym J 44:3748
Kwon H-J, Sunthornvarabhas J, Park J-W, Lee J-H, Kim H-J, Piyachomkwan K, Sriroth K, Cho D (2014) Compos Part B 56:232
Segal L, Creely JJ, Martin AE, Conrad CM (1959) Text Res J 29(10):786
Updegraff DM (1969) Anal Biochem 32:420
Technical Association of the Pulp and Paper Industry (2012) Test method T222 om-11
Wise L E, Murphy M, D’Addieco A (1946) Pap Trade J 122:35
ShikuY, Hamaguchi PY, BenjakulS, Visessanguan W, Tanaka M (2004) Food Chem 86:493
McHugh TH, Bustillos RA, Krochta JM (1993) J MJ Food Sci 58:899
Torres-Huerta AM, Palma-Ramírez D, Domínguez-Crespo MA, Angel-López DD, de la Fuente D (2014) Eur Polym J 61285
Karimi S, Tahir PM, Karimi A, Dufresne A, Abdulkhani A (2014) Carbohydr Polym 101:878
Xiang LY, Mohammed MAP, Baharuddin AS (2016) Carbohydr Polym 148:11
Reddy KO, Maheswari CU, Shukla M, Song JI, Rajulu AV (2013) Compos Part B 44:433
d’Almeida JRM, Aquino RCMP, Monteiro SN (2006) Compos Part A 37:1473
Johara N, Ahmada I, Dufresne A (2012) Ind Crops Prod 37:93
Greco A, Gennaro R, Timo A, Bonfantini F, Maffezzoli A (2013) J Polym Environ 21:910
Reddy KO, Maheswari CU, Reddy DJP, Rajulu AV (2009) Mater lett 63:2390
Ridzuan MJM, Abdul Majid MS, Afendi M, Aqmariah Kanafiah SN, Zahri JM, Gibson AG (2016) Mater Des 89:839
Nguyen T, Zavarin E, Barral EM, (1981) J Macromol Sci-Rev Macromo Chem C 20:1
Methacanon P, Weerawatsophon U, Sumransin N, Prahsarn C, Bergado DT (2010) Carbohydr Polym 82:1090
Azwa ZN, Yousif BF, Manalo AC, Karunasena W (2013) Mater Des 47:424
Kompella MK, Lambros J (2002) Polym Test 21(5):523
Panthapulakkal S, Zereshkian A, Sain M (2006) Bioresour Technol 97:265
Pickering KL, Beckermann GW, Alam SN, Foreman NJ (2007) Compos Part A 38:461
Muensri P, Kunanopparat T, Menut P, Siriwattanayotin S (2011) Compos Part A 42:173
Norul Izani MA, Paridah MT, Anwar UMK, Mohd Nor MY, H’ng PS (2013) Compos Part B Eng 45(1):1251
Wang H, Yao X, Sui G, Yin L, Wang L (2015) J Mater Sci Technol 31(2):164
Huang L, Mu B, Yi X, Li S, Wang Q (2016) J Polym Environ. doi:10.1007/s10924-016-0917-x.
Tserki V, Zafeiropoulos NE, Simon F, Panayiotou C (2005) Compos Part A 36(8):1110
Halal SLME, Colussi R, Deon GV, Pinto VZ, Villanova FA, Carreño NLV, Dias ARG, Zavareze ER (2015) Carbohydr Polym 133:644
Mutje P, Lopez A, Vallejos ME, Lopez J, Vilaseca F (2007) Compos Part A 38:369
Salehudina MH, Salleh E, Mamat SNH, Muhamad II (2014) Procedia Chem 9:23
Montaño-Leyva B, Silva GGD, Gastaldi E, Torres-Chávez P, Gontard N, Angellier-Couss H (2013) Ind Crops Prod 43:545
Santos T M, Souza Filho MDSM, Caceres CA, Rosa MF, Morais JPS, Pinto AMB, Azeredo HMC (2014) Food Hydrocolloids 41:113
Kunanopparat T, Menut P, Morel M-H, Guilbert S (2008) Compos Part A 39:777
Berthet M-A, Angellier-Coussy H, Guillard V, Gontard N (2015) J Appl Polym Sci. doi:10.1002/app.42528
Famá L, Gerschenson L, Goyanes S (2009) Carbohydr Polym 75:230
Babaee M, Jonoobi M, Hamzeh Y, Ashori A (2015) Carbohydr Polym 132:1
Shankar S, Reddy JP, Rhim JW (2015) Int J Biol Macromol 81:267
Guo J, Ge L, Li X, Ma C, Li D (2014) Food Hydrocolloids 39:243
Mu C, Guo J, Li X, Lin W, Li D (2012) Food Hydrocolloids 27:22
Ibrahima H, Farag M, Megahed H, Mehanny S (2014) Carbohydr Polym 101:11
Zainuddin SYZ, Ahmad I, Kargarzadeh H, Abdullah I, Dufresn A (2013) Carbohydr Polym 92:2299
Wang XY, Su JF (2014) Mater Sci Technol 30:534
Acknowledgements
This work was supported by the budget revenue of Prince of Songkla University, Contract Number SCI590389S. We also acknowledge Mr. Thomas Coyne for his kind assistance in editing the English.
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Lehman, N., Phengthai, R. & Chinpa, W. Effect of Moringa oleifera Pod Husk Fibers on the Properties of Gelatin-Based Biocomposite. J Polym Environ 26, 1405–1414 (2018). https://doi.org/10.1007/s10924-017-1042-1
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DOI: https://doi.org/10.1007/s10924-017-1042-1