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Journal of Polymers and the Environment

, Volume 13, Issue 3, pp 293–300 | Cite as

Role of Amino Acids on In Situ Photografting of Jute Yarn with 3-(Trimethoxysilyl) Propylmethacrylate

  • M. Masudul Hassan
  • M. Rabiul Islam
  • Laurence T. Drzal
  • Mubarak A. Khan
Article

To improve the mechanical performance of natural lignocellulosic jute yarn, grafting with [3-(trimethoxysilyl) propylmethacrylate] (TMSPM) monomer has been performed on in situ UV radiation and optimized the monomer concentration (30%) and irradiation time (30 min). Effect of various amino acids (1%) as additives in TMSPM with photografted jute yarn at optimized system has been studied. The polymer loading (PL) and tensile properties like tensile strength (TS) and elongation at break (Eb) of treated samples were enhanced by incorporation of amino acids and the highest properties (TS = 300% and Eb = 386%) achieved by the sample treated with l-Arginine (Arg) with 32.5% PL value. Weak acid like 3% acetic acid and inorganic acid like 1% sulfuric acid were also incorporated in the optimized system of TMSPM grafting and compared their effect on the tensile properties with amino acid treated samples. Water absorption and weathering resistance of treated and untreated samples were also performed and treated sample showed lesser water uptake as well as less weight loss and mechanical properties as compared to untreated samples.

Key words

Jute photografting UV radiation natural fiber biodegradable 

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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • M. Masudul Hassan
    • 1
  • M. Rabiul Islam
    • 2
  • Laurence T. Drzal
    • 3
  • Mubarak A. Khan
    • 4
  1. 1.Department of ChemistryM C CollegeSylhetBangladesh
  2. 2.Department of ChemistryJahangirnagar UniversityDhakaBangladesh
  3. 3.Composite Materials and Structures CenterMichigan State UniversityEast LansingUSA
  4. 4.Radiation and Polymer Chemistry Laboratory, Institute of Nuclear Science and TechnologyBangladesh Atomic Energy CommissionDhakaBangladesh

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