Abstract
We present the relativistic rotation–vibrational energy equation of a diatomic molecule which moves under the improved Tietz potential energy model in higher spatial dimensions. The nonrelativistic limits of the bound state solutions of the Klein–Gordon equation are the bound state solutions of the Schrödinger equation with the same potential energy function. Numerical analysis results show that there exists a critical point around which the solution behaviors bifurcate into two extreme cases. Below the critical point, the behavior of the relativistic vibrational energies for the ground electronic state of carbon monoxide in higher dimensions keeps similar to that of the three-dimensional system, while this symmetry phenomenon breaks and the Klein–Gordon equation has no stability solution upon the critical point.
Similar content being viewed by others
References
N. Saad, R.L. Hall, H. Ciftci, The Klein–Gordon equation with the Kratzer potential in d dimensions. Cent. Eur. J. Phys. 6, 717–729 (2008)
H. Hassanabadi, H. Rahimov, S. Zarrinkamar, Approximate solutions of Klein–Gordon equation with Kratzer potential. Adv. High Energy Phys. 2011, 458087 (2011)
S.M. Ikhdair, R. Sever, Relativistic solution in D-dimensions to a spin-zero particle for equal scalar and vector ring-shaped Kratzer potential. Cent. Eur. J. Phys. 6, 141–152 (2008)
T.T. Ibrahim, K.J. Oyewumi, S.M. Wyngaardt, Analytical solution of N-dimensional Klein–Gordon and Dirac equations with Rosen–Morse potential. Eur. Phys. J. Plus 127, 100 (2012)
H. Hassanabadi, E. Maghsoodi, S. Zarrinkamar, H. Rahimov, Approximate solutions of the Klein–Gordon equation for an Eckart and modified Hylleraas potential by SUSYQM. Eur. Phys. J. Plus 127, 143 (2012)
X.Y. Chen, T. Chen, C.S. Jia, Solutions of the Klein–Gordon equation with the improved Manning–Rosen potential energy model in D dimensions. Eur. Phys. J. Plus 129, 75 (2014)
M.S. Tan, S. He, C.S. Jia, Molecular spinless energies of the improved Rosen–Morse potential energy model in D dimensions. Eur. Phys. J. Plus 129, 264 (2014)
X.J. Xie, C.S. Jia, Soloutions of the Klein–Gordon equation with the Morse potential energy model in higher spatial dimensions. Phys. Scr. 90, 035207 (2015)
C.S. Jia, J.W. Dai, L.H. Zhang, J.Y. Liu, G.D. Zhang, Molecular spinless energies of the modified Rosen–Morse potential energy model in higher spatial dimensions. Chem. Phys. Lett. 619, 54–60 (2015)
C.S. Jia, Y.F. Diao, X.J. Liu, P.Q. Wang, J.Y. Liu, G.D. Zhang, Equivalence of the Wei potential model and Tietz potential model for diatomic molecules. J. Chem. Phys. 137, 014101 (2012)
T. Tietz, Potential-energy function for diatomic molecules. J. Chem. Phys. 38, 3036–3037 (1963)
M.L. Strekalov, An accurate closed-form expression for the partition function of Morse oscillators. Chem. Phys. Lett. 439, 209–212 (2007)
C.S. Jia, L.H. Zhang, C.W. Wang, Thermodynamic properties for the lithium dimer. Chem. Phys. Lett. 667, 211–215 (2017)
X.Q. Song, C.W. Wang, C.S. Jia, Thermodynamic properties for the sodium dimer. Chem. Phys. Lett. 673, 50–55 (2017)
C.S. Jia, C.W. Wang, L.H. Zhang, X.L. Peng, R. Zeng, X.T. You, Partition function of improved Tietz oscillators. Chem. Phys. Lett. 676, 150–153 (2017)
C.S. Jia, T. Chen, L.Z. Yi, S.R. Lin, Equivalence of the deformed Rosen–Morse potential energy model and Tietz potential energy model. J. Math. Chem. 51, 2165–2172 (2013)
G.D. Zhang, W. Zhou, J.Y. Liu, L.H. Zhang, C.S. Jia, D-dimensional energies for sodium dimer. Chem. Phys. 439, 79–84 (2014)
C.W. Li, J. Ciston, M.W. Kanan, Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper. Nature 508, 504–507 (2014)
C.L. Pekeris, The rotation–vibration coupling in diatomic molecules. Phys. Rev. 45, 98–103 (1934)
L.E. Gendenshtein, Derivation of exact spectra of the Schrödinger equation by means of supersymmetry. Sov. Phys. JETP Lett. 38, 356–359 (1983)
C.S. Jia, X.G. Wang, X.K. Yao, P.C. Chen, W. Xiao, A unified recurrence operator method for obtaining normalized explicit wavefunctions for shape-invariant potentials. J. Phys. A: Math. Gen. 31, 4763–4772 (1998)
C. Berkdemir, A. Berkdemir, R. Sever, Shape-invariance approach and Hamiltonian hierarchy method on the Woods–Saxon potential for ℓ ≠ 0 states. J. Math. Chem. 43, 944–954 (2008)
D. Mikulski, K. Eder, J. Konarski, The supersymmetric quantum mechanics theory and Darboux transformation for the Morse oscillator with an approximate rotational term. J. Math. Chem. 52, 1552–1562 (2014)
D. Mikulski, J. Konarski, K. Eder, M. Molski, S. Kabaciński, Exact solution of the Schrödinger equation with a new expansion of anharmonic potential with the use of the supersymmetric quantum mechanics and factorization method. J. Math. Chem. 53, 2018–2027 (2015)
M. Eshghi, H. Mehraban, M. Ghafoori, Non-relativistic Eigen spectra with q-deformed physical potentials by using the SUSY approach. Math. Methods Appl. Sci. 40, 1003–1018 (2016)
J.F. Du, P. Guo, C.S. Jia, D-dimensional energies for scandium monoiodide. J. Math. Chem. 52, 2559–2569 (2014)
F. Cooper, B. Freedman, Aspects of supersymmetric quantum mechanics. Ann. Phys. 146(2), 262–288 (1983)
P.G. Hajigeorgiou, An extend Lennard–Jones potential energy function for diatomic molecules: application to ground electronic states. J. Mol. Spectrosc. 263, 101–110 (2010)
G.F. Wei, S.H. Dong, Pseudospin symmetry for modified Rosen–Morse potential including a Pekeris-type approximation to the pseudo-centrifugal term. Eur. Phys. J. A 46, 207–212 (2010)
I. Tobias, R.J. Fallon, J.T. Vanderslice, Potential energy curve for CO. J. Chem. Phys. 33, 1638–1640 (1960)
J.F. Wang, X.L. Peng, L.H. Zhang, C.W. Wang, C.S. Jia, Entropy of gaseous boron monobromide. Chem. Phys. Lett. 686, 131–133 (2017)
C.S. Jia, C.W. Wang, L.H. Zhang, X.L. Peng, H.M. Tang, J.Y. Liu, Y. Xiong, R. Zeng, Predictions of entropy for diatomic molecules and gaseous substances. Chem. Phys. Lett. 692, 57–60 (2018)
C.S. Jia, C.W. Wang, L.H. Zhang, X.L. Peng, H.M. Tang, R. Zeng, Enthalpy of gaseous phosphorus dimer. Chem. Eng. Sci. 183, 26–29 (2018)
A. Demirkaya, M. Stanislavova, Conditional stability theorem for the one dimensional Klein–Gordon equation. J. Math. Phys. 52, 112703 (2011)
D. Chakraborty, J.H. Jung, Efficient determination of the critical parameters and the statistical quantities for Klein–Gordon and sine-Gordon equations with a singular potential using generalized polynomial chaos methods. J. Comput. Sci. 4, 46–61 (2013)
P.G. Hajigeorgiou, The number of bound vibrational levels in a diatomic molecule. J. Mol. Spectrosc. 286–287, 1–4 (2013)
P.G. Hajigeorgiou, The vibrational index at dissociation: an extended treatment. J. Mol. Spectrosc. 296, 17–23 (2014)
Acknowledgements
We would like to thank the kind referees for positive and invaluable suggestions which have greatly improved the manuscript. This work was supported by the Key Program of National Natural Science Foundation of China under Grant No. 51534006.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Liu, HB., Yi, LZ. & Jia, CS. Solutions of the Klein–Gordon equation with the improved Tietz potential energy model. J Math Chem 56, 2982–2994 (2018). https://doi.org/10.1007/s10910-018-0927-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10910-018-0927-0