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Journal of Low Temperature Physics

, Volume 157, Issue 3–4, pp 221–251 | Cite as

Quantum Size Effects in the Growth, Coarsening, and Properties of Ultra-thin Metal Films and Related Nanostructures

  • Mustafa M. Özer
  • Cai-Zhuang Wang
  • Zhenyu Zhang
  • Hanno H. Weitering
Article

Abstract

This review addresses the quantum mechanical nature of the formation and stability of ultrathin metal films. The competition between quantum confinement, charge spilling effects, and Friedel oscillations determines whether an atomically smooth metal film will be marginally, critically, or magically stable or totally unstable against roughening. Pb(111) films represent a special case, not only because of strong quantum oscillations in the stability of two-dimensional thin films but also because of the exceptionally fast coarsening of Pb nanoclusters. The latter appears to be due to the combined effects of size quantization and the existence of a unique mass exchange medium in the form of an unusually dense and highly dynamic wetting layer. The consequences of size quantization on the physical and chemical properties of the films are profound, some of which will be highlighted in this review.

Keywords

Metal films Metal islands Quantum size effects Electronic growth Stability Coarsening Superconductivity Work function Reactivity Catalysis 

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References

  1. 1.
    D.C. Tsui, H.L. Stormer, A.C. Gossard, Phys. Rev. Lett. 48, 1559 (1982) CrossRefADSGoogle Scholar
  2. 2.
    M.N. Baibich, J.M. Broto, A. Fert, F. Nguyen Van Dau, F. Petroff, Phys. Rev. Lett. 61, 2472 (1988) CrossRefADSGoogle Scholar
  3. 3.
    A.R. Smith, K.-J. Chao, Q. Niu, C.-K. Shih, Science 273, 226 (1996) CrossRefADSGoogle Scholar
  4. 4.
    Z.Y. Zhang, Q. Niu, C.K. Shih, Phys. Rev. Lett. 80, 5381 (1998) CrossRefADSGoogle Scholar
  5. 5.
    V. Yeh, L. Berbil-Bautista, C.Z. Wang, K.M. Ho, M.C. Tringides, Phys. Rev. Lett. 85, 5158 (2000) CrossRefADSGoogle Scholar
  6. 6.
    C.M. Wei, M.Y. Chou, Phys. Rev. B 66, 233408 (2002) CrossRefADSGoogle Scholar
  7. 7.
    M.H. Upton, C.M. Wei, M.Y. Chou, T. Miller, T.C. Chiang, Phys. Rev. Lett. 93, 026802 (2004) CrossRefADSGoogle Scholar
  8. 8.
    M.M. Özer, Y. Jia, B. Wu, Z.Y. Zhang, H.H. Weitering, Phys. Rev. B 72, 113409 (2005) CrossRefADSGoogle Scholar
  9. 9.
    Y. Jia, B. Wu, H.H. Weitering, Z.Y. Zhang, Phys. Rev. B 74, 035433 (2006) CrossRefADSGoogle Scholar
  10. 10.
    L. Aballe, A. Barinov, A. Locatelli, S. Heun, M. Kiskinova, Phys. Rev. Lett. 93, 196103 (2004) CrossRefADSGoogle Scholar
  11. 11.
    A.G. Danese, F.G. Curti, R.A. Bartynski, Phys. Rev. B 70, 165420 (2004) CrossRefADSGoogle Scholar
  12. 12.
    Y. Guo, Y.F. Zhang, X.Y. Bao, T.Z. Han, Z. Tang, L.X. Zhang, W.G. Zhu, E.G. Wang, Q. Niu, Z.Q. Qiu, J.F. Jia, Z.X. Zhao, Q.K. Xue, Science 306, 1915 (2004) CrossRefADSGoogle Scholar
  13. 13.
    D. Eom, S. Qin, M.Y. Chou, C.K. Shih, Phys. Rev. Lett. 96, 027005 (2006) CrossRefADSGoogle Scholar
  14. 14.
    M.M. Özer, J.R. Thompson, H.H. Weitering, Nature Phys. 2, 173 (2006) CrossRefADSGoogle Scholar
  15. 15.
    M.M. Özer, J.R. Thompson, H.H. Weitering, Phys. Rev. B 74, 235427 (2006) CrossRefADSGoogle Scholar
  16. 16.
    Z.G. Suo, Z.Y. Zhang, Phys. Rev. B 58, 5116 (1998) CrossRefADSGoogle Scholar
  17. 17.
    A. Zangwill, Physics at Surfaces (Cambridge University Press, Cambridge, 1998) Google Scholar
  18. 18.
    M. Hupalo, V. Yeh, L. Berbil-Bautista, S. Kremmer, E. Abram, M.C. Tringides, Phys. Rev. B 64, 155307 (2001) CrossRefADSGoogle Scholar
  19. 19.
    H.W. Hong, C.M. Wei, M.Y. Chou, Z. Wu, L. Basile, H. Chen, M. Holt, T.C. Chiang, Phys. Rev. Lett. 90, 076104 (2003) CrossRefADSGoogle Scholar
  20. 20.
    W.B. Su, S.H. Chang, W.B. Jian, C.S. Chang, L.J. Chen, T.T. Tsong, Phys. Rev. Lett. 86, 5116 (2001) CrossRefADSGoogle Scholar
  21. 21.
    M. Hupalo, S. Kremmer, V. Yeh, L. Berbil-Bautista, E. Abram, M.C. Tringides, Surf. Sci. 493, 526 (2001) CrossRefADSGoogle Scholar
  22. 22.
    H.H. Weitering, D.R. Heslinga, T. Hibma, Phys. Rev. B 45, 5991 (1992) CrossRefADSGoogle Scholar
  23. 23.
    A. Mans, J.H. Dil, A.R.H.F. Ettema, H.H. Weitering, Phys. Rev. B 66, 195410 (2002) CrossRefADSGoogle Scholar
  24. 24.
    K.L. Man, M.C. Tringides, M.M.T. Loy, M.S. Altman, Phys. Rev. Lett. 101, 226102 (2008) CrossRefADSGoogle Scholar
  25. 25.
    B.A. Wu, Z. Zhang, Phys. Rev. B 77, 035410 (2008) CrossRefADSGoogle Scholar
  26. 26.
    P. Czoschke, H. Hong, L. Basile, T.-C. Chiang, Phys. Rev. B 72, 075402 (2005) CrossRefADSGoogle Scholar
  27. 27.
    F.K. Schulte, Surf. Sci. 55, 427 (1976) CrossRefADSGoogle Scholar
  28. 28.
    M.M. Özer, Y. Jia, Z.Y. Zhang, J.R. Thompson, H.H. Weitering, Science 316, 1594 (2007) CrossRefADSGoogle Scholar
  29. 29.
    Y. Qi, X. Ma, P. Jiang, S.H. Ji, Y.S. Fu, J.F. Jia, Q.K. Xue, S.B. Zhang, Appl. Phys. Lett. 90, 013109 (2007) CrossRefADSGoogle Scholar
  30. 30.
    A. Mans, J.H. Dil, A.H.R.F. Ettema, H.H. Weitering, Phys. Rev. B 72, 155442 (2005) CrossRefADSGoogle Scholar
  31. 31.
    P. Czoschke, H.W. Hong, L. Basile, T.C. Chiang, Phys. Rev. Lett. 91, 226801 (2003) CrossRefADSGoogle Scholar
  32. 32.
    X. Ma, P. Jiang, Y. Qi, S. Ji, Y. Fu, J. Jia, Y. Yang, W. Duan, W. Li, X. Bao, S.B. Zhang, Q.-K. Xue, Proc. Nat. Acad. Sci. 104, 9204 (2007) CrossRefADSGoogle Scholar
  33. 33.
    B.J. Hinch, C. Koziol, J.P. Toennies, G. Zhang, Europhys. Lett. 10, 341 (1989) CrossRefADSGoogle Scholar
  34. 34.
    J. Braun, J.P. Toennies, Surf. Sci. 384, L858 (1997) CrossRefGoogle Scholar
  35. 35.
    Y. Jia, B. Wu, H.H. Weitering, T. Einstein, Z.Y. Zhang, Phys. Rev. Lett. (submitted) Google Scholar
  36. 36.
    I.B. Altfeder, V. Narayanamurti, D.M. Chen, Phys. Rev. Lett. 88, 206801 (2002) CrossRefADSGoogle Scholar
  37. 37.
    R. Otero, A.L. Vásquez de Parga, R. Miranda, Phys. Rev. B 66, 115401 (2002) CrossRefADSGoogle Scholar
  38. 38.
    J.C. Heyraud, J.J. Metois, Surf. Sci. 128, 334 (1983) CrossRefADSGoogle Scholar
  39. 39.
    P. Czoschke, H.W. Hong, L. Basile, T.C. Chiang, Phys. Rev. Lett. 93, 036103 (2004) CrossRefADSGoogle Scholar
  40. 40.
    H.J. Schulz, J. Phys. 46, 257 (1985) Google Scholar
  41. 41.
    M. Zinke-Allmang, L.C. Feldman, M.H. Grabow, Surf. Sci. Rep. 16, 377 (1992) CrossRefADSGoogle Scholar
  42. 42.
    K. Morgenstern, Phys. Stat. Sol. 242, 773 (2005); and references therein CrossRefADSGoogle Scholar
  43. 43.
    C.V. Thompson, Acta Met. 36, 2929 (1988) CrossRefGoogle Scholar
  44. 44.
    C.A. Jeffrey, E.H. Conrad, R. Feng, M. Hupalo, C. Kim, P.J. Ryan, P.F. Miceli, M.C. Tringides, Phys. Rev. Lett. 96, 106105 (2006) CrossRefADSGoogle Scholar
  45. 45.
    M. Li, J.W. Evans, C.Z. Wang, M. Hupalo, M.C. Tringides, T.-L. Chan, K.M. Ho, Surf. Sci. Lett. 601(23), L140–L144 (2007) CrossRefADSGoogle Scholar
  46. 46.
    M. Nowicki, C. Bombis, A. Emundts, H.P. Bonzel, Phys. Rev. B 67, 075405 (2003) CrossRefADSGoogle Scholar
  47. 47.
    J.G. McLean, B. Krishnamachari, D.R. Peale, E. Chason, J.P. Sethna, B.H. Cooper, Phys. Rev. B 55, 1811 (1997) CrossRefADSGoogle Scholar
  48. 48.
    M. Hupalo, M.C. Tringides, Phys. Rev. B 75, 235443 (2007) CrossRefADSGoogle Scholar
  49. 49.
    M. Li, C.Z. Wang, J.W. Evans, M. Hupalo, M.C. Tringides, K.M. Ho, Phys. Rev. B 79, 113404 (2009) CrossRefADSGoogle Scholar
  50. 50.
    Y. Han, J.Y. Zhu, F. Liu, S.-C. Li, J.-F. Jia, Y.-F. Zhang, Q.-K. Xue, Phys. Rev. Lett. 93, 106102 (2004) CrossRefADSGoogle Scholar
  51. 51.
    J.H.I. Cho, Z.Y. Zhang, E.W. Plummer, Phys. Rev. B 59, 1677 (1999) CrossRefADSGoogle Scholar
  52. 52.
    A. Crottini, D. Cvetko, L. Floreano, R. Gotter, A. Morgante, F. Tommasini, Phys. Rev. Lett. 79, 1527 (1997) CrossRefADSGoogle Scholar
  53. 53.
    L. Floreano, D. Cvetko, F. Bruno, G. Bavdek, A. Cossaro, R. Gotter, A. Verdini, A. Morgante, Prog. Surf. Sci. 72, 135 (2003) CrossRefGoogle Scholar
  54. 54.
    T.C. Chiang, Private communication Google Scholar
  55. 55.
    R. Wiesendanger, Scanning Probe Microscopy (Cambridge University Press, Cambridge, 1994) Google Scholar
  56. 56.
    J. Kosterlitz, D. Thouless, J. Phys. C 6, 1181 (1973) CrossRefADSGoogle Scholar
  57. 57.
    D.B. Haviland, Y. Liu, A.M. Goldman, Phys. Rev. Lett. 62, 2180 (1989) CrossRefADSGoogle Scholar
  58. 58.
    I. Vilfan, M. Henzler, O. Pfennigstorf, H. Pfnür, Phys. Rev. B 66, 241306 (2002) CrossRefADSGoogle Scholar
  59. 59.
    I. Vilfan, H. Pfnür, Eur. Phys. J. B 36, 281 (2003) CrossRefADSGoogle Scholar
  60. 60.
    J. Simonin, Phys. Rev. B 33, 7830 (1986) CrossRefADSGoogle Scholar
  61. 61.
    R.C. Dynes, J.M. Rowell, Phys. Rev. B 11, 1884 (1975) CrossRefADSGoogle Scholar
  62. 62.
    S. Qin, J. Kim, Q. Niu, C.K. Shih, Science (2008). doi: 10.1126/science.1170775 Google Scholar
  63. 63.
    G.J. Dolan, J. Silcox, Phys. Rev. Lett. 30, 603 (1973) CrossRefADSGoogle Scholar
  64. 64.
    M. Valden, X. Lai, D.W. Goodman, Science 281, 1647 (1998) CrossRefADSGoogle Scholar
  65. 65.
    M.S. Chen, D. Kumar, C.-W. Yi, D.W. Goodman, Science 310, 291 (2005) CrossRefADSGoogle Scholar
  66. 66.
    M.S. Chen, Y. Cai, Z. Yan, D.W. Goodman, J. Am. Chem. Soc. 128, 6341 (2006) CrossRefGoogle Scholar
  67. 67.
    M.S. Chen, D.W. Goodman, Catal. Today 111, 22 (2006) CrossRefGoogle Scholar
  68. 68.
    N. Binggeli, M. Altarelli, Phys. Rev. Lett. 96, 036805 (2006) CrossRefADSGoogle Scholar
  69. 69.
    J.K. Nørskov, Rep. Prog. Phys. 53, 1253 (1990) CrossRefADSGoogle Scholar
  70. 70.
    Z.Q. Qiu, N.V. Smith, J. Phys. Condens. Matter 14, R169 (2002) CrossRefADSGoogle Scholar
  71. 71.
    E.J. Moon, M.M. Özer, J.R. Thompson, H.H. Weitering, submitted Google Scholar
  72. 72.
    A. Khajetoorians, W.G. Zhu, J.S. Kim, S. Qin, H. Eisele, Z.Y. Zhang, C.-K. Shih, submitted Google Scholar
  73. 73.
    M.M. Özer, E.J. Moon, A.G. Eguiluz, H.H. Weitering, unpublished Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Mustafa M. Özer
    • 1
  • Cai-Zhuang Wang
    • 2
  • Zhenyu Zhang
    • 1
    • 3
  • Hanno H. Weitering
    • 1
    • 3
  1. 1.Materials Science and Technology DivisionOak Ridge National LaboratoryOak RidgeUSA
  2. 2.Ames Laboratory USDOE, Department of Physics and AstronomyIowa State UniversityAmesUSA
  3. 3.Department of Physics and AstronomyThe University of TennesseeKnoxvilleUSA

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