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A Water Stable Metal–Organic Framework Based on Eu Clusters as Highly Selective Luminescent Sensor Towards MnO4−

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Abstract

A novel water stable Eu-MOF, namely [Eu(H2O)2(CPBDA)]n, was solvothermally synthesized by rigid ligand 3-(6-carboxypyridin-3-yl)benzene-1,4-dioic acid (H3CPBDA) and Eu(III) ion. The resultant sample was studied in detail by single X-ray diffraction, powder X-ray diffraction, elemental analysis (C, H and N), thermogravimetric analysis and luminescence. Due to its water stability and luminescence properties, the resultant sample can be used as a luminescent sensor for MnO4− in water. Furthermore, it also can be reused at least four times without any change.

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  1. Chongqing Key Laboratory of Inorganic Special Functional Materials, School of Chemistry and Chemical Engineering, Yangtze Normal University, Fuling, Chongqing, 408100, China

    Feng Guo, Qianya Yang & Xiaoyan Li

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  1. Feng Guo
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  2. Qianya Yang
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  3. Xiaoyan Li
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Correspondence to Feng Guo.

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Guo, F., Yang, Q. & Li, X. A Water Stable Metal–Organic Framework Based on Eu Clusters as Highly Selective Luminescent Sensor Towards MnO4−. J Inorg Organomet Polym 29, 159–164 (2019). https://doi.org/10.1007/s10904-018-0975-8

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