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New Zn/Cd Coordination Polymers Constructed from Mixed Ligands: Crystal Structures and Photocatalytic Performances Toward Organic Dyes Degradation

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Abstract

Two coordination polymers (CPs), Cd(bpp)(H2O)L (BUC-18) and Zn(bpp)L (BUC-19), (H2L = cis-1,3-dibenzyl-2-imidazolidone-4,5-dicarboxylic acid, bpp = 1,3-bis(4-pyridyl)propane), have been synthesized under hydrothermal conditions, and characterized by single crystal X-ray analysis, Fourier transform infrared spectra (FTIR), thermogravimetric analyses (TGA), CNH element analysis and UV–Vis diffuse reflectance spectra (UV–Vis DRS). Upon the UV light irradiation, BUC-19 exhibited excellent photocatalytic performances toward methylene blue (initial concentration 10 mg L−1), methyl orange (initial concentration 10 mg L−1) and reactive red X-3B (initial concentration 50 mg L−1) with degradation efficiency of 93, 80 and 92%, respectively. The possible mechanism was proposed, which was further confirmed by trapping experiments.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (51578034), Great Wall Scholars Training Program Project of Beijing Municipality Universities (CIT&TCD20180323), Project of Construction of Innovation Teams and Teacher Career Development for Universities and Colleges Under Beijing Municipality (IDHT20170508) and Beijing Talent Project (2017A38).

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  1. Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation, Beijing University of Civil Engineering and Architecture, Beijing, 100044, China

    Fu-Xue Wang, Xi Chen, Peng Wang & Chong-Chen Wang

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  1. Fu-Xue Wang
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  2. Xi Chen
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Correspondence to Chong-Chen Wang.

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Wang, FX., Chen, X., Wang, P. et al. New Zn/Cd Coordination Polymers Constructed from Mixed Ligands: Crystal Structures and Photocatalytic Performances Toward Organic Dyes Degradation. J Inorg Organomet Polym 28, 1565–1573 (2018). https://doi.org/10.1007/s10904-018-0804-0

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