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Novel Benzidine and o-Phenylenediamine Copolymer–Matrix Microcomposites

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Abstract

Poly(benzidine-co-o-phenylenediamine)/bentonite composites were fabricated utilizing several bentonite percentages by a facile oxidative copolymerization. The composites were clarified by means of FT-IR and UV–Vis absorption spectra of both poly(benzidine-co-o-phenylenediamine) emeraldine base, and poly(benzidine-co-o-phenylenediamine)/bentonite composite. The conjunction of o-phenylenediamine monomer with polybenzidine skeleton in the existence of bentonite was proven. TGA analyses under non-oxidative condition were studied. Moreover, at different magnifications, SEM of bentonite composite was examined having micrometric particle sizes in the range of 0.24–0.80 μm. A comparison of XRD patterns of the synthesized polymer and composite was discussed.

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  1. Chemistry Department, Faculty of Science, Port Said University, 23 December Street, Port Said, 42521, Egypt

    Ayman S. Al-Hussaini

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Al-Hussaini, A.S. Novel Benzidine and o-Phenylenediamine Copolymer–Matrix Microcomposites. J Inorg Organomet Polym 28, 871–879 (2018). https://doi.org/10.1007/s10904-017-0777-4

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