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Preparation of Cadmium Sulfide/Polystyrene Nanocomposites Films Using Gamma Irradiation

  • H. A. Youssef
  • Z. I. Ali
  • T. A. Afify
  • M. Bekhit
Article
  • 120 Downloads

Abstract

In the present study we have synthesized Cadmium Sulfide/Cetyltrimethylammonium bromide (CdS/CTAB) nanoparticles + by the gamma ray irradiation method and then embedded in polystyrene polymer with different concentration (2, 5 and 10 wt%) forming CdS/PS nanocomposites using solution casting method. The as-prepared CdS/CTAB nanoparticles and CdS/PS nanocomposites were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscope (FTIR), Ultraviolet/Visible (UV/Vis) absorption, high resolution scanning electron microscopy (HRSEM) and thermogravimetric analysis (TGA). The XRD results indicated the formation of CdS nanoparticles with hexagonal phase. FTIR data suggesting interaction of the alkyl ammonium head group of CTAB with the CdS nanoparticle surface. UV–Vis spectroscopy revealed that the CdS/PS nanocomposites films showed quantum confinement effect. The TGA results showed incorporation of CdS nanoparticles significantly enhance the thermal properties of PS matrix. The photoluminescence spectra of CdS/PS nanocomposites films show two emission bands arising from the presence of CdS nanoparticles.

Keywords

Nanocomposites CdS nanoparticles CTAB Gamma radiation Photoluminces 

Notes

Acknowledgements

This work was funded by the Science & Technology Development Fund (STDF) in Egypt under the Grant Number (6370). The authors would like to thank the STDF for their fund.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • H. A. Youssef
    • 1
  • Z. I. Ali
    • 1
  • T. A. Afify
    • 1
  • M. Bekhit
    • 1
  1. 1.Radiation Chemistry Department, National Center for Radiation Research and TechnologyEgyptian Atomic Energy Authority (EAEA)Nasr City, CairoEgypt

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