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Two New Nickel, Cobalt Coordination Polymers Based on Flexible 1,3-bis((1H-imidazolyl)-methyl)benzene Ligand: Syntheses, Structures and Magnetic Properties

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Abstract

Two new coordination polymers, namely, [Ni(HIP)(m-bix)(H2O)]n (1), {[Co2(oba)2(m-bix)2]·H2O}n (2) (m-bix = 1,3-bis(1H-imidazolyl)-methyl)benzene, H2HIP = 5-hydroxyisophthalic acid, oba = 4,4-oxybisbenzoic acid), were synthesized under hydrothermal conditions by reactions of transition metal salts of Ni(OAc)2 and Co(OAc)2 with the N-heterocyclic m-bix. There structures were characterized by techniques of single-crystal X-ray diffraction analysis, elemental analysis, infrared spectra (IR) and thermogravimetric analysis (TGA). Complex 1 and 2 both exhibit a 2D 4-connected sql network with the topology symbol of (44·62) and are further extending into a 3D architecture via O–H⋅⋅⋅O hydrogen bonds. Moreover, the solid state magnetic properties of complex 1 and 2 have been investigated.

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References

  1. W.X. Li, H.X. Li, H.Y. Li, M.M. Chen, Y.X. Shi, J.P. Lang, Cryst. Growth Des. 17, 3948 (2017)

    Article  CAS  Google Scholar 

  2. X. Feng, Y.Q. Feng, N. Guo, Y.L. Sun, T. Zhang, L.F. Ma, L.Y. Wang, Inorg. Chem. 56, 1713 (2017)

    Article  CAS  Google Scholar 

  3. T. Tahier, C.L. Oliver, Cryst. Eng. Commun. 19, 3607 (2017)

    Article  CAS  Google Scholar 

  4. D.M. Chen, N.N. Zhang, C.S. Liu, Z.H. Jiang, X.D. Wang, M. Du, Inorg. Chem. 56, 2379 (2017)

    Article  CAS  Google Scholar 

  5. K. Adil, Y. Belmabkhout, R.S. Pillai, A. Cadiau, P.M. Bhatt, A.H. Assen, G. Maurinb, M. Eddaoudi, Chem. Soc. Rev. 46, 3402 (2017)

    Article  CAS  Google Scholar 

  6. S.B. Zhou, X.F. Wang, C.C. Du, D.Z. Wang, D.Z. Jia, Cryst Eng Commun. 19, 3124 (2017)

    Article  CAS  Google Scholar 

  7. G. Xiong, B. Yu, J. Dong, Y. Shi, B. Zhao, L.N. He, Chem. Commun. 53, 6013 (2017)

    Article  CAS  Google Scholar 

  8. L. Zhu, X.Q. Liu, H.L. Jiang, L.B. Sun, Chem. Rev. 117, 8129 (2017)

    Article  CAS  Google Scholar 

  9. D. Xie, X. Liu, B. Ling, B. Zheng, Z.X. Pi, H. Chen, W.J. Zhu, Y. Xue, J.H. Bi, H.Z. Dong, J. Inorg. Organomet. Polym. 27, 658 (2017)

    Article  CAS  Google Scholar 

  10. J.P. Li, B.J. Li, M.T. Pan, B. Liu, J.J. Cheng, R.Y. Li, X.L. Gao, S.M. Wang, H.W. Hou, Z.Y. Liu, Cryst. Growth Des. 17, 2975 (2017)

    Article  CAS  Google Scholar 

  11. A.K. Bar, C. Pichon, J.P. Sutter, Coord, Chem. Rev. 308, 346 (2016)

    Article  CAS  Google Scholar 

  12. I. Castro, W.P. Barros, M.L. Calatayud, F. Lloret, N. Marino, G.D. Munno, H.O. Stumpf, R.R. García, M.J. Coord, Chem. Rev. 315, 135 (2016)

    CAS  Google Scholar 

  13. H.Y. Dai, C.J. Wang, Y.Y. Tang, Y. Tong, K.L. Mao, Z.B. Zhang, X.L. Zhou, J. Inorg. Organomet. Polym. 27, 80 (2017)

    Article  CAS  Google Scholar 

  14. S. Keskin, S. Kızılel, Ind. Eng. Chem. Res. 50, 1799 (2011)

    Article  CAS  Google Scholar 

  15. X.S. Zeng, Y. Chen, X.F. Deng, X. Li, H.L. Xu, Q. Yang, G.B. Hua, H.J. Qiu, D.R. Xiao, Inorg. Chem. Commun. 72, 65 (2016)

    Article  CAS  Google Scholar 

  16. H. Wang, J.J. Guo, X.L. Xu, P.F. Yao, Y.M. Jiang, Transit. Met. Chem. 42, 293 (2017)

    Article  CAS  Google Scholar 

  17. X.H. Zhou, Q.Q. Chen, B.L. Liu, L. Li, T. Yang, W. Huang, Dalton Trans. 46, 430 (2017)

    Article  CAS  Google Scholar 

  18. X.F. Wang, C.C. Du, S.B. Zhou, D.Z. Wang, J. Mol. Struct. 1128, 103 (2017)

    Article  CAS  Google Scholar 

  19. H.Y. Li, L.H. Cao, Y.L. Wei, H. Xu, S.Q. Zang, Cryst .Eng. Commun. 17, 6297 (2015)

    Article  CAS  Google Scholar 

  20. L. Zhou, Y.S. Xue, Y. Xu, J. Zhang, H.B. Du, Cryst. Eng. Commun. 15, 7315 (2013)

    Article  CAS  Google Scholar 

  21. T.T. Fan, J.J. Li, X.L. Qu, H.L. Han, X. Li, Cryst. Eng. Commun. 17, 9443 (2015)

    Article  CAS  Google Scholar 

  22. C.M. Nagaraja, B. Ugale, A. Chanthapally, Cryst. Eng. Commun. 16, 4805 (2014)

    Article  CAS  Google Scholar 

  23. W. Wang, W.Q. Kan, J. Yang, J.F. Ma, Cryst. Eng. Commun. 15, 3824 (2013)

    Article  CAS  Google Scholar 

  24. S. Tripathi, S.K. Sachan, G. Anantharaman, Polyhedron 119, 55 (2016)

    Article  CAS  Google Scholar 

  25. Z.Q. Shi, Y.Z. Li, Z.J. Guo, H.G. Zheng, Cryst. Growth Des. 13, 3078 (2013)

    Article  CAS  Google Scholar 

  26. X.M. Guo, Y.N. Yan, H.D. Guo, Y.J. Qi, C.M. Liu, Cryst. Eng. Commun. 18, 2546 (2016)

    Article  CAS  Google Scholar 

  27. Y. Liang, W.G. Yuan, S.F. Zhang, Z. He, J.R. Xue, X. Zhang, L.H. Jing, D.B. Qin, Dalton Trans. 45, 1382 (2016)

    Article  CAS  Google Scholar 

  28. P.K. Yadav, N. Kumari, P. Pachfule, R. Banerjee, L. Mishra, Cryst. Growth Des. 12, 5311 (2012)

    Article  CAS  Google Scholar 

  29. W. Wang, Z.Y. Xiao, H. Lin, R.M. Wang, L.L. Zhang, D.F. Sun, RSC Adv. 6, 16575 (2016)

    Article  CAS  Google Scholar 

  30. Z.G. Gu, Y.T. Liu, X.J. Hong, Q.G. Zhan, Z.P. Zheng, S.R. Zheng, W.S. Li, S.J. Hu, Y.P. Cai, Cryst. Growth Des. 12, 2178 (2012)

    Article  CAS  Google Scholar 

  31. J.T. Li, J. Li, L.M. Song, X.H. Ji, Inorg. Chem. Commun. 83, 88 (2017)

    Article  CAS  Google Scholar 

  32. D.J. Qiang, X.G. Yang, X.B. Deng, H.L. Sun, CrystEngComm 18, 8159 (2016)

    Article  CAS  Google Scholar 

  33. C.L. Zhang, L. Qin, Z.Z. Shi, H.G. Zheng, Dalton Trans. 44, 4238 (2015)

    Article  CAS  Google Scholar 

  34. N.N. Huang, X.D. Wang, Y.H. Yu, J.S. Gao, G.F. Hou, Chin. J. Struct. Chem. 34, 292 (2015)

    CAS  Google Scholar 

  35. C.M. Liu, S. Gao, H.M. Hu, X. Jin, H.Z. Kou, Dalton Trans. 598 (2002)

  36. L. Zhang, L. Liu, C. Huang, X. Han, L. Guo, H. Xu, H. Hou, Y. Fan, Cryst. Growth Des. 15, 3426 (2015)

    Article  CAS  Google Scholar 

  37. X.L. Wang, F.F. Sui, H.Y. Lin, J.W. Zhang, G.C. Liu, Cryst. Growth Des. 14, 3438 (2014)

    Article  CAS  Google Scholar 

  38. C.I. Yang, P.H. Chuang, G.H. Lee, S.M. Peng, K.L. Lu, Inorg. Chem. 51, 757 (2012)

    Article  CAS  Google Scholar 

  39. K.C. Mondal, G.E. Kostakis, Y. Lan, C.E. Anson, A.K. Powell, Inorg. Chem. 48, 9205 (2009)

    Article  CAS  Google Scholar 

  40. X.Y. Wang, S.C. Sevov, Inorg. Chem. 47, 1037 (2008)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was financially supported by the Scientific Research Foundation for the Introduced Talents of Kunming University of Science and Technology (No. KKSY201507026), the Analysis Testing Fund of Kunming University of Science and Technology (No. 2017T20040109, No. 2017M20152111048), the Joint Fund of National Natural Science Foundation of China and Yunnan (Grant No. U1502273), and the State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming 650093 (Grant No. CNMRCUKF1606).

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Authors and Affiliations

  1. Faculty of Science, Kunming University of Science and Technology, Kunming, 650500, China

    Xiaofei Xue, Yuqi Liu, Yubo Xing, Xinying Wang & Wei Li

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  1. Xiaofei Xue
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  2. Yuqi Liu
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  3. Yubo Xing
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  4. Xinying Wang
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  5. Wei Li
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Correspondence to Yuqi Liu or Wei Li.

Electronic supplementary material

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10904_2017_742_MOESM1_ESM.cif

Appendix A. Supplementary material CCDC 1564090 and 1564092 contain the supplementary crystallographic data for complexes 1 and 2. The data can be obtained free of charge viahttp://www.ccdc.cam.ac.uk/data_request /cif. (CIF 205 KB)

Supplementary material 2 (CIF 35 KB)

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Xue, X., Liu, Y., Xing, Y. et al. Two New Nickel, Cobalt Coordination Polymers Based on Flexible 1,3-bis((1H-imidazolyl)-methyl)benzene Ligand: Syntheses, Structures and Magnetic Properties. J Inorg Organomet Polym 28, 820–828 (2018). https://doi.org/10.1007/s10904-017-0742-2

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  • DOI: https://doi.org/10.1007/s10904-017-0742-2

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