Supramolecular Architectures in Three Metal(II) Coordination Polymers with 2,5-Dichloroterephthalate and Flexible Bis(Benzimidazole) Ligands



Three supramolecular coordination polymers, namely [Ni(L1)(DCTP)(H2O)] n (1), [Cu(L2)(DCTP)] n (2), [Co(L3)(DCTP)] n (3) (L1 = 1,5-bis(5,6-dimethylbenzimidazole)pentane, L2 = 1,4-bis(5,6-dimethylbenzimidazole)butane, L3 = 1,4-bis(benzimidazole)-2-butylene) have been hydrothermally synthesized and characterized by single crystal X-ray structure determination, FT-IR, elemental analysis, X-ray powder diffraction (XPD), and thermogravimetric analysis (TGA). CP 1 exhibits 2D 63 honeycombed network structure, which is further extended into a 3D Moganite (mog) supramolecular framework by classical O–H⋯O hydrogen-bonding interaction. CPs 2 –3 present 2D (4,4) layers, and 3D supramolecular frameworks that are formed by ππ stacking interactions. Furthermore, the catalytic activities of CPs 1–3 for the degradation of methyl orange in a Fenton-like process has been investigated, and CPs 1–3 show strong photoluminescence properties at room temperature in solid state.


Catalytic activity Flexible bis(benzimidazole) Photoluminescence property Supramolecular framework 



The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation – Steel and Iron Foundation of Hebei Province (B2015209299).

Supplementary material

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  1. 1.College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic MaterialsNorth China University of Science and TechnologyTangshanPeople’s Republic of China

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