Controllable Synthesis of NiSe2 Nanostructures via Hydrothermal Process for Photocatalytic and Solar Cell Applications

  • Majid Aliabadi


This paper reports on the synthesis of rice-like NiSe2 nanoparticles via a simple hydrothermal method by employing [bis(2-hydoxyacetophenato)nickle(II)], [Ni(HAP)2], as a novel nickel precursor. Effect of nickel source on morphology and size of nanostructures was also investigated. Moreover, the as-synthesized NiSe2 nanostructures were utilized as the photocatalyst for the degradation of methylene blue (MB) and as the counter electrode in dye-sensitized solar cells. The results showed that structures size and morphology have salient effect on solar cells and using rice-like NiSe2 nanoparticles leads to an increase in DSSCs efficiency compared to agglomerated sphere-like particles from 6.04 to 8.99 % (~49 % improvement).


NiSe2 Rice-like nanoparticle Counter electrode DSSC Methylene blue 



This work was supported by the Chemistry Research Center at Birjand Branch, Islamic Azad University, Birjand, Iran.


  1. 1.
    I.A. Ji, H.M. Choi, J.H. Bang, Mater. Lett. 123, 51 (2014)CrossRefGoogle Scholar
  2. 2.
    H. Fan, M. Zhang, X. Zhang, Y. Qian, J. Cryst. Growth 311, 4530 (2009)CrossRefGoogle Scholar
  3. 3.
    A. Sobhani, M. Salavati-Niasari, Superlattices Microst. 65, 79 (2014)CrossRefGoogle Scholar
  4. 4.
    A. Sobhani, M. Salavati-Niasari, F. Davar, Polyhedron 31, 210 (2012)CrossRefGoogle Scholar
  5. 5.
    M.Z. Xue, Z.W. Fu, Electrochem. Commun. 8, 1855 (2006)CrossRefGoogle Scholar
  6. 6.
    M. Mousavi-Kamazani, M. Salavati-Niasari, M. Goudarzi, A. Gharehbaii, J. Inorg. Organomet. Polym. 26, 259 (2016)CrossRefGoogle Scholar
  7. 7.
    W. Du, X. Qian, X. Niu, Q. Gong, Cryst. Growth Des. 7, 2733 (2007)CrossRefGoogle Scholar
  8. 8.
    Z. Pu, Y. Luo, A.M. Asiri, X. Sun, ACS Appl. Mater. Interfaces 8, 4718 (2016)CrossRefGoogle Scholar
  9. 9.
    J. Li, Z. Jin, T. Liu, J. Wang, X. Zheng, J. Lai, Cryst. Eng. Comm. 16, 6819 (2014)CrossRefGoogle Scholar
  10. 10.
    N. Moloto, M.J. Moloto, N.J. Coville, S.S. Ray, J. Cryst. Growth 311, 3924 (2009)CrossRefGoogle Scholar
  11. 11.
    A. Sobhani, F. Davar, M. Salavati-Niasari, Appl. Surf. Sci. 257, 7982 (2011)CrossRefGoogle Scholar
  12. 12.
    A. Sobhani, M. Salavati-Niasari, Opt. Mater. 35, 904 (2013)CrossRefGoogle Scholar
  13. 13.
    A. Sobhani M. Salavati-Niasari, Superlattices Microst. 59, 1 (2013)CrossRefGoogle Scholar
  14. 14.
    A. Sobhani, M. Salavati-Niasari, Mater. Res. Bull. 47, 1905 (2012)CrossRefGoogle Scholar
  15. 15.
    Y.C. Wang, D.Y. Wang, Y.T. Jiang, H.A. Chen, C.C. Chen, C. HoK et al., Angew. Chem. Int. Ed. 52, 6694 (2013)CrossRefGoogle Scholar
  16. 16.
    L. Guo-ran, W. Feng, J. Qi-wei, G. Xue-ping, S. Pan-wen, Angew Chem. Int. Ed. 49, 3653 (2010)CrossRefGoogle Scholar
  17. 17.
    M. Wu, X. Lin, Y. Wang, L. Wang, W. Guo, D. Qi, X. Peng, A. Hagfeldt, M. Gratzel, T. Ma, J. Am. Chem. Soc. 134, 3419 (2012)CrossRefGoogle Scholar
  18. 18.
    J. Han, H. Kim, D.Y. Kim, S.M. Jo, S.Y. Jang, ACS Nano 4, 3503 (2010)CrossRefGoogle Scholar
  19. 19.
    F. Gong, H. Wang, X. Xu, G. Zhou, Z.S. Wang, J. Am. Chem. Soc. 134, 10953 (2012)CrossRefGoogle Scholar
  20. 20.
    J. Guo, Y. Shi, C. Zhu, L. Wang, N. Wang, T. Ma, J. Mater. Chem. A 1, 11874 (2013)CrossRefGoogle Scholar
  21. 21.
    M. Panahi-Kalamueia, M. Mousavi-Kamazani, M. Salavati-Niasari, Mater. Lett. 136, 218 (2014)CrossRefGoogle Scholar
  22. 22.
    M. Mousavi–Kamazani, M. Salavati–Niasari, H. Emadi, Mater. Res. Bull. 47, 3983 (2012)CrossRefGoogle Scholar
  23. 23.
    M. Mousavi-Kamazani, M. Salavati-Niasari, M. Sadeghinia, Superlattice Microst. 63, 248 (2013)CrossRefGoogle Scholar
  24. 24.
    F. Mohandes, M. Salavati-Niasari, Ultrason. Sonochem. 20, 354 (2013)CrossRefGoogle Scholar
  25. 25.
    Z. Zarghami, M. Ramezani, M. Maddahfar, J. Mater. Sci. Mater. Electron. 26, 5884 (2015)CrossRefGoogle Scholar
  26. 26.
    Z. Peng, Y. Liu, Y. Zhao, K. Chen, Y. Cheng, W. Chen, Electrochim. Acta 135, 276 (2014)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.Department of Chemical Engineering, Birjand BranchIslamic Azad UniversityBirjandIran

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