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Four Flexible Bis(Thiabendazole)-Based Cd(II) Coordination Polymers with Various Aromatic Carboxylates: Syntheses, Structures and Properties

  • Xu Zhang
  • Yong-Guang Liu
  • Zeng-Chuan Hao
  • Guang-Hua Cui
Article
  • 145 Downloads

Abstract

Four Cd(II) coordination polymers (CPs) including [Cd(btbb)0.5(L1)] n (1), [Cd(btbb)(L2)·(H2O)1.5] n (2), [Cd(btbb)(L3)] n (3), and [Cd(btbb)(HL4)] n (4) (btbb = 1,4-bis(thiabendazole)butane, H2L1 = 5-hydroxyisophthalic acid, H2L2 = 4,4′-biphenyldicarboxylic acid, H2L3 = tetrabromoterephthalic acid, H3L4 = 5-nitro-1,2,3-benzenetricarboxylic acid) were prepared under hydrothermal conditions based on flexible bis(thiabendazole) ligand and different co-carboxylates. Their structures have been determined by single-crystal X-ray diffraction analyses, elemental analyses, IR spectra, X-ray powder diffraction, and thermogravimetric analyses. CP 1 exhibits a 3D 2-nodal (3,4)-connected framework with the 3,4T10 topology. CP 2 and 3 feature typical hcb layer structure, and 3 is further combined into a 3D supramolecular architecture through C–H⋯O hydrogen bonds. CP 4 possesses an infinite chain and further extended into 2D supramolecular network by O–H⋯O hydrogen-bonding interactions. The effects of the aromatic polycarboxylate co-ligands on the CPs framework have been discussed and the catalytic activities of CPs 14 for degradation of methyl orange in Fenton-like process are also investigated.

Keywords

Bis(thiabendazole) ligand Catalytic property Cd(II) coordination polymer Crystal structure 

Notes

Acknowledgments

The project was supported by the National Natural Science Foundation of China (51474086) and Natural Science Foundation-Steel and Iron Foundation of Hebei Province (B2015209299).

Supplementary material

10904_2016_440_MOESM1_ESM.doc (493 kb)
Supplementary material 1 (DOC 493 KB)

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Xu Zhang
    • 1
  • Yong-Guang Liu
    • 1
  • Zeng-Chuan Hao
    • 1
  • Guang-Hua Cui
    • 1
  1. 1.Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, College of Chemical EngineeringNorth China University of Science and TechnologyTangshanChina

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