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Arenetricarbonylchromium Complexes in Polymerization Transformations by Radical Initiation of Vinyl Polymerization

  • Lyudmila Semenycheva
  • Alexander Artemov
  • Natalia Valetova
  • Julia Matkivskaja
  • Alexei Moykin
Review Paper
  • 118 Downloads

Abstract

The article is devoted to the systematization of investigations of arenetricarbonylchromium complexes in radical polymerization transformation at the initiation of vinyl polymerization. The presented data are shown that these compounds are promising and interesting model systems for the study of the phenomenon of the metal atom action on the reactivity of the monomer π-bond. The correlation between the structure of metal-containing monomers and polymerization parameters, as well as the molecular mass properties of the resulting polymers, are discussed.

Keywords

Arenetricarbonylchromium complexes (Co)polymerization Radical initiation Stable radical A weak inhibition Reversible inhibition 

Notes

Acknowledgments

The work was supported by the Ministry of Education and Science of Russian Federation (task №2014/134, the agreement of 27 August 2013 year № 02.В.49.21.0003) using equipment of the center “New materials and resource-saving technologies” (project RFMEFI59414X0005).

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Lyudmila Semenycheva
    • 1
  • Alexander Artemov
    • 1
  • Natalia Valetova
    • 1
  • Julia Matkivskaja
    • 1
  • Alexei Moykin
    • 1
  1. 1.N.I. Lobachevsky State University of Nizhni Novgorod – National Research UniversityNizhny NovgorodRussia

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