Advertisement

Silver(I) Polymer of Tripodal Amine: Synthesis, Structure and Photoluminescence

  • Joydev Dinda
  • Lakshmikanta Maity
  • Chen-Shiang Lee
  • Wen-Shu Hwang
  • Salem S. Al-Deyab
Article
  • 177 Downloads

Abstract

Starting from tripodal ligand tris-(methyl-imidazole) amine (1) the colourless complex tris-(methyl-imidazole)aminesilver(I)perchlorate (2) has been synthesized, characterized by IR, UV/Vis and 1HNMR spectroscopic studies and finally solid state structure has been established by single crystal X-ray diffraction studies. A single crystal X-ray structure determination revealed the formation of coordination polymer. The crystal structure possesses weak d10–d10 ‘argentophilic’ interactions with Ag–Ag separation (3.348 Å). The weak luminance at 375 nm may be this Ag–Ag weak interaction. The molecule possesses weak H-bonding with C2 and C4H of imidazole with oxygen of ClO4.

Keywords

Tripodal amine Imidazole Silver complex Luminescence XRD studies 

Notes

Acknowledgments

JD thankful to Hon’ble Vice Chancellor, Registrar and Chairman PG Council of Utkal University-Bhubaneswar for constant encouragement. SA extends sincere appreciation to the deanship of scientific research at King Saud University for its funding through Prolific Research group PRG-1436-03. JD is also thankful to Prof. Valerio Bertolasi for help regarding XRD.

Supplementary material

10904_2016_406_MOESM1_ESM.docx (24 kb)
Supplementary material 1 (DOCX 23 kb)

References

  1. 1.
    X. Hu, I.C. Rodriguez, K. Meyer, J. Am. Chem. Soc. 126, 13464 (2004)CrossRefGoogle Scholar
  2. 2.
    M.J.F.- Trujillo, M.G. Basallote, P. Valerga, M.C. Puerta, Dalton Trans. 5, 926 (1993)Google Scholar
  3. 3.
    Y.P. Cai, C.Y. Su, C.L. Chen, Y.M. Li, B.S. Kang, A.S.C. Chan, W. Kaim, Inorg. Chem. 42, 163 (2003)CrossRefGoogle Scholar
  4. 4.
    C.-Y. Su, B.-S. Kang, C.-X. Du, Q.-C. Yang, T.C.W. Mak, Inorg. Chem. 39, 4843 (2000)CrossRefGoogle Scholar
  5. 5.
    J.A.R. Hartman, R.W. Vachet, J.H. Callahan, Inorg. Chim. Acta 297, 79 (2000)CrossRefGoogle Scholar
  6. 6.
    T. Tuntulani, V. Ruangpornvisuti, N. Tantikunwatthana, O. Ngampaiboonsombut, R.S.M.Z. Asfari, J. Vicens, Tetrahedron Lett. 38, 3985 (1997)CrossRefGoogle Scholar
  7. 7.
    W.-Z. Lee, T.-L. Wang, H.-S. Tsang, C.-Y. Liu, C.-T. Chen, T.-S. Kuo, Organometallics 28, 652 (2009)CrossRefGoogle Scholar
  8. 8.
    S.N. Bhattacharya, C.V. Senoff, Inorg. Chem. 22, 1607 (1983)CrossRefGoogle Scholar
  9. 9.
    R. Wietzke, M. Mazzanti, J.-M. Latour, J. P´ecaut, Chem. Commun. 2, 209 (1999)CrossRefGoogle Scholar
  10. 10.
    M.J. Hardie, C.A. Kilner, M.A. Halcrow, Cryst. Struct. Commun. 60, 177 (2004)CrossRefGoogle Scholar
  11. 11.
    Q.P.B. Nguyen, T.N. Le, T.H. Kim, Bull. Korean Chem. Soc. 30, 1743 (2009)CrossRefGoogle Scholar
  12. 12.
    K.J. Oberhausen, R.J. O’brien, J.F. Richardson, R.M. Buchanan, Inorg. Chim. Acta. 173, 145–180 (1990)CrossRefGoogle Scholar
  13. 13.
    H. Nakamura, Y. Sunatsuki, M. Kojima, N. Matsumoto, Inorg. Chem. 46, 8170 (2007)CrossRefGoogle Scholar
  14. 14.
    S. Wang, L. Wang, X. Wang, Q. Luo, Inorg. Chim. Acta 254, 71 (1997)CrossRefGoogle Scholar
  15. 15.
    V.J. Catalano, M.A. Malwitz, A.O. Etogo, Inorg. Chem. 43, 5714 (2004)CrossRefGoogle Scholar
  16. 16.
    P.W. Alley, J. Org. Chem. 40, 1837 (1975)CrossRefGoogle Scholar
  17. 17.
    G.M. Sheldrick, SHELXS97 and SHELXL97: Programs for Crystal Structure Solution and Refinement University of Göttingen, Germany, 1997Google Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Joydev Dinda
    • 1
  • Lakshmikanta Maity
    • 1
  • Chen-Shiang Lee
    • 2
  • Wen-Shu Hwang
    • 2
  • Salem S. Al-Deyab
    • 3
  1. 1.Department of ChemistryUtkal UniversityBhubaneswarIndia
  2. 2.Department of ChemistryNational Dong -Hwa UniversityHoulianTaiwan
  3. 3.Chemistry Department, College of ScienceKing Saud UniversityRiyadhSaudi Arabia

Personalised recommendations