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Structure and Photocatalytic Property of a Novel Three-Dimensional Supramolecular Cu(ΙΙ) Coordination Polymer with pcu Topology Based on the Rigid Multifunctional Ligand

  • Xiaoshuo Wu Pengfei Wang
  • Siyuan Xu Pengpeng Lu
Communication
  • 214 Downloads

Abstract

A new copper coordination polymer, [Cu2L4(H2O)2]n (1), (HL = 3-(pyridine-2-yl)benzoic acid) has been solvothermally synthesized by using the HL and CuCl2⋅2H2O and characterized by IR spectra, elemental analysis, single-crystal and powder X-ray diffractions, and TGA. Compound 1 contains a well-known paddle-wheel unit [Cu2(COO)4], which is connected to a three-dimensional supramolecular structure with pcu topology through the hydrogen bond interactions. Compound 1 displays considerable thermal stability and exhibits selective absorption in the visible region, which is shown by thermogravimetric analysis and solid-state UV–Vis diffuse-reflectance spectra, respectively. In addition, compound 1 represents an example of visible light driven photocatalyst based on coordination polymer and shows good degradation ability over Rhodamine B (RhB).

Keywords

Coordination polymer Multifunctional ligand Photocatalytic activity 

Notes

Acknowledgments

This work was financially supported by the National Nature Science Foundation of China (No. 21101019), the Natural Science Foundation of Anhui Province University (No. gxyqZD2016371) and the Chizhou College (No.2015ZR001).

Supplementary material

10904_2016_404_MOESM1_ESM.doc (194 kb)
Supplementary material 1 (DOC 193 kb) CCDC-1476277 contains the supplementary crystallographic data for compound 1. These data also can be obtained free of charge from The Cambridge Crystalographic Data Centra via www.ccdc.ac.uk/data_request/cif. Supplementary data associated with this manuscript can be found in supporting information

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Xiaoshuo Wu Pengfei Wang
    • 1
  • Siyuan Xu Pengpeng Lu
    • 1
  1. 1.School of Chemistry and Material EngineeringChizhou CollegeChizhouPeople’s Republic of China

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