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Poly(2-Hydroxyethyl Methacrylate-Bis[Trimethoxysilylpropyl]Amine) Hybrid Networks

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Abstract

In this paper, our goal is to improve the understanding of structural control of hybrid materials synthesized by using acid-catalyzed sol–gel reactions of bis-[trimethoxysilylpropyl]amine (BisSi) and 2-hydroxyethyl methacrylate (HEMA) via free radical in a common solvent. Polymer networks compositions were determined by FTIR and 1H-NMR spectroscopy. The thermal properties of the P(HEMA-BisSi) hybrids with different silica content (e.g. 10, 15 and 25 wt%) were determined by thermogravimetric analysis and differential scanning calorimetry. Glass transition temperatures (Tg´s) of P(HEMA-BisSi) networks were also compared with Tg of PHEMA homopolymer. The Tg´ of PHEMA homopolymer was found as 103.74 °C. The thermal stability of these networks was increased with the BisSi content. Scanning electron microscopy images showed that an increase in acid content caused a decrease in the pore size and pore volume as well as in the surface area of the xerogel.

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Acknowledgments

This study was supported by DGEST-4416.11-P. The authors wish to express their sincere thanks to the BUAP-CUV for their guidance and support.

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Authors and Affiliations

  1. División de Estudios de Posgrado e Investigación y Departamento de Ingeniería Química y Bioquímica del Instituto Tecnológico de Zacatepec, Instituto Tecnológico de Zacatepec, Zacatepec de Hidalgo, Mexico

    R. Salgado-Delgado, L. A. Bustos-Figueroa, E. García-Hernández, Z. Vargas-Galarza, A. M. Salgado-Delgado & A. Olarte-Paredes

  2. División de Estudios de Posgrado, Facultad de Ingeniería, Universidad Autónoma de Querétaro, Querétaro, Mexico

    T. López-Lara & J. B. Hernández-Zaragoza

  3. Centro de Fisica Aplicada y Tecnologia Avanzada, Universidad Nacional Autónoma de México, Boulevard Juriquilla 3001, 76230, Querétaro, Qro, Mexico

    V. M. Castaño

Authors
  1. R. Salgado-Delgado
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  2. L. A. Bustos-Figueroa
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  3. E. García-Hernández
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  4. Z. Vargas-Galarza
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  5. A. M. Salgado-Delgado
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  6. A. Olarte-Paredes
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  7. T. López-Lara
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  8. J. B. Hernández-Zaragoza
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  9. V. M. Castaño
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Corresponding authors

Correspondence to R. Salgado-Delgado or V. M. Castaño.

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Salgado-Delgado, R., Bustos-Figueroa, L.A., García-Hernández, E. et al. Poly(2-Hydroxyethyl Methacrylate-Bis[Trimethoxysilylpropyl]Amine) Hybrid Networks. J Inorg Organomet Polym 26, 756–763 (2016). https://doi.org/10.1007/s10904-016-0391-x

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  • DOI: https://doi.org/10.1007/s10904-016-0391-x

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