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Hydrothermal Synthesis of Mn–Fe Nano Oxides and Their Composite for Removal of Zn2+, Ni2+ and Co2+ from Simulated Radioactive Waste

  • M. Khalil
  • Y. F. El-Aryan
  • I. M. Ali
Article

Abstract

A study on the sorption of Zn2+, Ni2+ and Co2+ onto mixed oxide of Mn and Fe obtained at different hydrothermal conditions and its organic hybrid film modified with polyacrylamide (Mn–Fe oxide/PAM) has been examined. The characterization of inorganic oxides and its composite samples were performed using XRD, SEM, FTIR, XRF and DTA-TGA techniques. The percent sorption of Zn2+, Ni2+ and Co2+ on Mn–Fe oxide at pH 4.5 was 97, 11.85 and 10 % respectively with selectivity order Zn2+ ≫ Ni2+ > Co2+. The sorption value of Zn2+ at pH 4.5 onto Fe–Mn oxide reached nearly the same value of Zn2+ onto its composite. So, the new compound of Fe–Mn oxide has promising uses for separation of zinc ions while its composite can be used for removal all of these cations.

Keywords

Hydrothermal synthesis Nano oxide Iron Manganese Polyacrylamide Radioactive waste 

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.Atomic Energy AuthorityHot Laboratory CenterCairoEgypt

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