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Hydrothermal Synthesis of Mn–Fe Nano Oxides and Their Composite for Removal of Zn2+, Ni2+ and Co2+ from Simulated Radioactive Waste

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Abstract

A study on the sorption of Zn2+, Ni2+ and Co2+ onto mixed oxide of Mn and Fe obtained at different hydrothermal conditions and its organic hybrid film modified with polyacrylamide (Mn–Fe oxide/PAM) has been examined. The characterization of inorganic oxides and its composite samples were performed using XRD, SEM, FTIR, XRF and DTA-TGA techniques. The percent sorption of Zn2+, Ni2+ and Co2+ on Mn–Fe oxide at pH 4.5 was 97, 11.85 and 10 % respectively with selectivity order Zn2+ ≫ Ni2+ > Co2+. The sorption value of Zn2+ at pH 4.5 onto Fe–Mn oxide reached nearly the same value of Zn2+ onto its composite. So, the new compound of Fe–Mn oxide has promising uses for separation of zinc ions while its composite can be used for removal all of these cations.

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Authors and Affiliations

  1. Atomic Energy Authority, Hot Laboratory Center, P. No. 13759, Cairo, Egypt

    M. Khalil, Y. F. El-Aryan & I. M. Ali

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  1. M. Khalil
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  2. Y. F. El-Aryan
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  3. I. M. Ali
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Correspondence to M. Khalil.

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Khalil, M., El-Aryan, Y.F. & Ali, I.M. Hydrothermal Synthesis of Mn–Fe Nano Oxides and Their Composite for Removal of Zn2+, Ni2+ and Co2+ from Simulated Radioactive Waste. J Inorg Organomet Polym 26, 359–369 (2016). https://doi.org/10.1007/s10904-015-0318-y

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  • DOI: https://doi.org/10.1007/s10904-015-0318-y

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