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Synthesis, Crystal Structure, Physical Properties and Theoretical Calculations of a New One-Dimensional Ni(II) Coordination Polymer Constructed by 1,10-Phenanthroline Derivative Ligand and Sulfate

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Abstract

A new Ni(II) coordination polymer constructed by 1,10-phenanthroline derivative 2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1, 10]phenanthroline (L) and inorganic sulfate anion, namely, [Ni(L)(SO4)(H2O)2]n (1), has been successfully synthesized under hydrothermal condition. In compound 1, each sulfate functions in bidentate bridging coordination mode and links two Ni(II) atoms to generate a one-dimensional chain structure. The adjacent chains are joined together by aromatic π–π interactions between L ligands to yield a two-dimensional supramolecular layer. The O–H···O and N–H···O hydrogen bonding interactions between sulfate oxygen atoms, coordination water molecules and nitrogen atoms of L ligands further stabilize the two-dimensional supramolecular architecture of 1. Moreover, the magnetic property of 1 was investigated. In addition, natural bond orbital analysis was performed by the B3LYP/LANL2DZ method in Gaussian 09 Program. The calculation results show the obvious covalent interaction between the coordinated atoms and Ni(II) ion.

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Acknowledgments

This work was supported by the Science and Technology Research Projects of the Education Committee of Jilin Province (No. 2013206).

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Authors and Affiliations

  1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, College of Chemistry, Jilin Normal University, Siping, 136000, People’s Republic of China

    Zhi-Guo Kong, Wei Wang, Si-Qi Zhang, Fang-Wei Zhao & Xiu-Yan Wang

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  1. Zhi-Guo Kong
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  2. Wei Wang
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  3. Si-Qi Zhang
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  4. Fang-Wei Zhao
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  5. Xiu-Yan Wang
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Correspondence to Xiu-Yan Wang.

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Kong, ZG., Wang, W., Zhang, SQ. et al. Synthesis, Crystal Structure, Physical Properties and Theoretical Calculations of a New One-Dimensional Ni(II) Coordination Polymer Constructed by 1,10-Phenanthroline Derivative Ligand and Sulfate. J Inorg Organomet Polym 25, 1441–1447 (2015). https://doi.org/10.1007/s10904-015-0257-7

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