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Synthesis, Characterization and Crystal Structure of Zn(II) and Cd(II) One- and Two-Dimensional Coordination Polymers Derived from Pyridine Based Schiff Base ligand

  • Ali Akbar Khandar
  • Farhad Akbari Afkhami
  • Seyed Abolfazl Hosseini-Yazdi
  • Janusz Lipkowski
  • William. G. Dougherty
  • W. Scott Kassel
  • Héctor Rodríguez Prieto
  • Santiago García-Granda
Article

Abstract

Four coordination polymers with the formulas [Zn(L)(NO3)]n (1), {[Zn(L)(NO2)]·CH3OH}n (2), [Cd(L)(NO2)]n (3) and [Cd(L)(NO3)]n (4) {HL=2-benzolypyridine-isonicotinoylhydrazone (HBPIH)} have been synthesized and characterized by elemental analyses, FT-IR spectroscopy, 1H and 13C NMR and single crystal X-ray data diffraction. The L ligand acts as a negatively charged tetradentae N3O-donor in 13 and pentadentate ligand in 4. The Schiff base ligand coordinates to a metal center as N2O-donor and coordinates to adjacent metal center via its Para-Nitrogen of pyridlyl group in 13 leading to formation of one-dimensional, 1D, coordination polymer. The oxygen atom of the ligand L also coordinates to the third metal center as a bridging atom in 4 and forms a two-dimensional, 2D, coordination polymer. Metal centers are six coordinated with distorted octahedral geometry in 13 and seven coordinated with pentagonal bipyramid geometry in 4. The nitrate and nitrite groups act as asymmetric bidentate ligands in all complexes.

Keywords

Zinc(II) complex Cadmium(II) complex Coordination polymer Pyridine based ligand Crystal Structure 

Notes

Acknowledgments

We are grateful to the University of Tabriz for the generous financial support of this research. Single crystal X-ray diffraction experiments were performed at Villanova University and Cardinal Stefan Wyszynski University in Warsaw and Universidad de Oviedo. We thank them all for their helpful collaboration.

Supplementary material

10904_2015_175_MOESM1_ESM.docx (2.5 mb)
Supplementary material 1 (DOCX 2552 kb)

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Ali Akbar Khandar
    • 1
  • Farhad Akbari Afkhami
    • 1
  • Seyed Abolfazl Hosseini-Yazdi
    • 1
  • Janusz Lipkowski
    • 2
  • William. G. Dougherty
    • 3
  • W. Scott Kassel
    • 3
  • Héctor Rodríguez Prieto
    • 4
  • Santiago García-Granda
    • 4
  1. 1.Department of Inorganic Chemistry, Faculty of ChemistryUniversity of TabrizTabrizIran
  2. 2.Faculty of Mathematics and Natural SciencesCardinal Stefan Wyszynski University in WarsawWarsawPoland
  3. 3.Department of ChemistryVillanova UniversityVillanovaUSA
  4. 4.Departamento de Química Física y Analítica, Facultad de QuímicaUniversidad de Oviedo–CINNOviedoSpain

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