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Synthesis, Structures, and Catalytic Properties of Three New Metal–Organic Coordination Polymers Constructed from Flexible Benzimidazole-Based and cis-1,2-Cyclohexanedicarboxylate Synthons

  • Chun-Lun Ming
  • Zeng-Chuan Hao
  • Bao-Yi Yu
  • Kristof Van Hecke
  • Guang-Hua Cui
Article

Abstract

Three metal–organic coordination polymers {[Co(pbmb)(chadc)]·2H2O} n (1), {[Zn(pbmb)(chadc)]·2H2O} n (2), and [Ag(pbmb)(chadc)] n (3) (pbmb = 1,1′-(1,3-propanediyl)bis(2-methylbenzimidazole), chadc = cis-1,2-cyclohexanedicarboxylate anion), have been hydrothermally synthesized by self-assembly of a flexible bis(2-methylbenzimidazole) ligand and one dicarboxylate anion with three kinds of metal salts. All the compounds were characterized by single-crystal X-ray diffraction and physico-chemical spectroscopic methods. Complexes 1 and 2 possess a 1D sequence of fused rings and 3 shows a 1D helical chain structure, which are bridged by pbmb and chadc ligands. Complex 2 and 3 are further packed into 2D and 3D supramolecular architectures by diverse ππ interactions, respectively. The investigation as heterogeneous catalyst in a Fenton-like process for 13 reveals different performances. In addition, the fluorescence properties of 13 have been investigated in the solid state.

Keywords

Bis(2-methylbenzimidazole) ligand Fluorescence and catalytic properties Supramolecular interactions 

Supplementary material

10904_2014_117_MOESM1_ESM.doc (143 kb)
Supplementary material 1 (DOC 143 kb)

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Chun-Lun Ming
    • 1
  • Zeng-Chuan Hao
    • 1
  • Bao-Yi Yu
    • 2
  • Kristof Van Hecke
    • 2
  • Guang-Hua Cui
    • 1
  1. 1.College of Chemical EngineeringHebei United UniversityTangshanPeople’s Republic of China
  2. 2.Department of Inorganic and Physical ChemistryGhent UniversityGhentBelgium

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