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Synthesis and Characterization of Chitosan/Polyvinylpyrrolidone/Zeolite Composite by Solution Blending Method

  • Erol Alver
  • Ayşegül Ü. Metin
  • Hakan Çiftçi
Article

Abstract

Polymer/clay composites have been studied for several decades; in the study, polymer/zeolite composite beads have been prepared by a simple solution blending method using chitosan, polyvinylpyrrolidone and zeolite particles as organic and inorganic components, respectively. Different techniques, such as SEM, FTIR spectroscopy, and thermogravimetry have been used to characterize the composite beads. Chitosan/polyvinylpyrrolidone/zeolite (CH/PVP/Z) beads are expected to have a potential as an adsorbent for wastewater treatment. To investigate its applicability, copper (II) was selected as a model compound. The results showed that the composite beads had effective loading capacity and it is a promising adsorbent for heavy metal removal.

Keywords

Chitosan Polyvinylpyrrolidone Blend Zeolite Composite 

References

  1. 1.
    W. Wang, J. Wang, Y. Kang, A. Wang, Compos. Pt. B-Eng. 42, 809 (2011)CrossRefGoogle Scholar
  2. 2.
    M.A. Tasdelen, W.V. Camp, E. Goethals, P. Dubois, F.D. Prez, Y. Yagci, Macromolecules 41, 6035 (2008)CrossRefGoogle Scholar
  3. 3.
    D. Wang, J. Zhu, Q. Yao, C.A. Wilkie, Chem. Mater. 14, 3837 (2002)CrossRefGoogle Scholar
  4. 4.
    R.Y. Lin, B.S. Chen, G.L. Chen, J.Y. Wu, H.C. Chiu, S.Y. Suen, J. Membrane Sci. 326, 117 (2009)CrossRefGoogle Scholar
  5. 5.
    M. Alexandre, P. Dubois, Mater. Sci. Eng. R 28, 1 (2000)CrossRefGoogle Scholar
  6. 6.
    B.H. Kim, J.H. Jung, S.H. Hong, J. Joo, Macromolecules 35, 1419 (2002)CrossRefGoogle Scholar
  7. 7.
    Y. Mansoori, S.V. Atghia, M.R. Zamanloo, G.H. Imanzadeh, M. Sirousazar, Eur. Polym. J. 46, 1844 (2010)CrossRefGoogle Scholar
  8. 8.
    U. Ulusoy, S. Simsek, O. Ceyhan, Adsorption 9, 165 (2003)CrossRefGoogle Scholar
  9. 9.
    M. Yoonessi, H. Toghiani, L.W. Kingery, C.U. Pittman, Macromolecules 37, 2511 (2004)CrossRefGoogle Scholar
  10. 10.
    S. Filippi, E. Mameli, C. Marazzato, P. Magagnini, Eur. Polym. J. 43, 1645 (2007)CrossRefGoogle Scholar
  11. 11.
    K.E. Strawhecker, E. Manias, Chem. Mater. 12, 2943 (2000)CrossRefGoogle Scholar
  12. 12.
    J. Billingham, C. Breen, J. Yarwood, Vibr Spectrosc. 14, 19 (1997)CrossRefGoogle Scholar
  13. 13.
    Z. Shen, G.P. Simon, Y.B. Cheng, Polymer 43, 4251 (2002)CrossRefGoogle Scholar
  14. 14.
    Y. Xie, A. Wang, J. Compos. Mater. 43, 2401 (2009)CrossRefGoogle Scholar
  15. 15.
    A.R. Nesić, S.J. Velićković, D.G. Antonovic, Compos. Pt. B-Eng. 53, 145 (2013)Google Scholar
  16. 16.
    M. Sahin, N. Koçak, G. Arslan, H.I. Ucan, J. Inorg. Organomed. Polym. 21, 69 (2011)CrossRefGoogle Scholar
  17. 17.
    A. Geçer, N. Yıldız, D. Kavak, A. Çalımlı, Polym. Composite. 30, 288 (2009)CrossRefGoogle Scholar
  18. 18.
    A. Aldana, A. González, M.C. Strumia, M. Martinelli, Mater. Chem. Phys. 134, 317 (2012)CrossRefGoogle Scholar
  19. 19.
    R. Nesic, S.V. Velickovic, D.G. Antonovic, J. Hazard. Mater. 209–210, 256 (2012)CrossRefGoogle Scholar
  20. 20.
    E.S. Dragan, M.V. Dinu, D. Timpu, Bioresour. Technol. 101, 812 (2010)CrossRefGoogle Scholar
  21. 21.
    M. Futalan, C.C. Kan, M.L. Dalida, K.J. Hsien, C. Pascua, M.W. Wan, Carbohydr. Polym. 83, 528 (2011)CrossRefGoogle Scholar
  22. 22.
    M. Darder, M. Colilla, E. Ruiz-Hitzky, Appl. Clay Sci. 28, 199 (2005)CrossRefGoogle Scholar
  23. 23.
    J.H. An, S. Dultz, Appl. Clay Sci. 36, 256 (2007)CrossRefGoogle Scholar
  24. 24.
    S. Hua, H. Yang, W. Wang, A. Wang, Appl. Clay Sci. 50, 112 (2010)CrossRefGoogle Scholar
  25. 25.
    K. Lewandowska, Thermochim. Acta 517, 90 (2011)CrossRefGoogle Scholar
  26. 26.
    M. Zeng, H. Xiao, X. Zhang, X. Sun, C. Qi, B. Wang, J. Macromol. Sci. Phys. 50, 1413 (2011)CrossRefGoogle Scholar
  27. 27.
    B. Smitha, S. Sridhar, A.A. Khan, J. Power Sources 159, 846 (2006)CrossRefGoogle Scholar
  28. 28.
    W.S.W. Ngah, L.C. Teong, C.S. Wong, M.A.K.M. Hanafiah, J. Appl. Polym. Sci. 125, 241 (2012)Google Scholar
  29. 29.
    G. Crini, Bioresour. Technol. 97, 1061 (2006)CrossRefGoogle Scholar
  30. 30.
    M. Qiu, C. Qian, J. Xu, J. Wu, G. Wang, Desalination 243, 286 (2009)CrossRefGoogle Scholar
  31. 31.
    S. Sen, B. Bardakcı, A.G. Yavuz, A.U. Gok, Eur. Polym. J. 44, 2708 (2008)CrossRefGoogle Scholar
  32. 32.
    N. Yener, C. Biçer, M. Önal, Y. Sarıkaya, Appl. Surf. Sci. 258, 2534 (2012)CrossRefGoogle Scholar
  33. 33.
    D. Archana, B.K. Singh, J. Dutta, P.K. Dutta, Carbohydr. Polym. 95, 530 (2013)CrossRefGoogle Scholar
  34. 34.
    L. Zhang, X. Bai, H. Tian, L. Zhong, C. Ma, Y. Zhou, S. Chen, D. Li, Carbohydr. Polym. 89, 1060 (2012)CrossRefGoogle Scholar
  35. 35.
    J.S. Jovaševic, S.I. Dimitrijevic, J.M. Filipovic, S.L. Tomic, M.M. Micic, E.H. Suljovrujic, Acta Phys. Pol. A 120, 6 (2011)Google Scholar
  36. 36.
    R.P. Chahal, S. Mahendıa, A.K. Tomar, S. Kumar, Dig. J. Nanomater. Bios. 6, 299 (2011)Google Scholar
  37. 37.
    J.C. Boulet, P. Williams, T. Doco, Carbohydr. Polym. 69, 79 (2007)CrossRefGoogle Scholar
  38. 38.
    V.N. Tirtom, A. Dinçer, S. Becerik, T. Aydemir, Chem. Eng. J. 197, 379 (2012)CrossRefGoogle Scholar
  39. 39.
    S. Mekahlia, B. Bouzid, Physics Procedia. 2, 1045 (2009)CrossRefGoogle Scholar
  40. 40.
    F. Brunel, N.E.E. Gueddari, B.M. Moerschbacher, Carbohydr. Polym. 92, 1348 (2013)CrossRefGoogle Scholar
  41. 41.
    D.A. Devi, B. Smitha, S. Sridhar, T.M. Aminabhavi, J. Membrane Sci. 280, 45 (2006)CrossRefGoogle Scholar
  42. 42.
    A.U. Metin, H. Çiftçi, E. Alver, Ind. Eng. Chem. Res. 52, 10569 (2013)CrossRefGoogle Scholar
  43. 43.
    H. Aydın, Y. Bulut, Ç. Yerlikaya, J. Environ. Manage. 87, 37 (2008)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Erol Alver
    • 1
  • Ayşegül Ü. Metin
    • 2
  • Hakan Çiftçi
    • 3
  1. 1.Department of Chemical Engineering, Faculty of EngineeringHitit UniversityÇorumTurkey
  2. 2.Department of Chemistry, Faculty of Arts and SciencesKirikkale UniversityYahşihanTurkey
  3. 3.Department of Chemistry and Chemical Processing Technologies, Kirikkale Vocational High SchoolKirikkale UniversityYahşihanTurkey

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