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Synthesis, Thermal and Morphological Properties of Polyurethanes Containing Azomethine Linkage

  • Musa Kamacı
  • İsmet Kaya
Article

Abstract

This paper presents synthesis, photophysical, electrochemical, thermal and morphological properties of Schiff bases containing various side-group substitutions and polyurethanes (PUs) containing azomethine linkage. Morphological properties of PUs containing azomethine bonding were investigated by scanning electron microscopy (SEM). SEM images showed that PU containing azomethine consist of semi-crystalline particles. Thermal transitions in PUs containing azomethine units were studied using DSC. The obtained DSC curves showed that PUs containing azomethine are semi-crystalline materials due to they contain both crystallization and melting peaks. Electrochemical properties also investigated by using cyclic voltammetry (CV). According to the cyclic voltommagrams and CV data, PUs containing azomethine have below 2.0 eV electrochemical band gap.

Keywords

Semi-crystalline polymer Low-band gap polymers Electrochemical and morphological properties Thermal analysis 

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.Polymer Synthesis and Analysis Lab., Department of Chemistry, Faculty of Sciences and ArtsÇanakkale Onsekiz Mart UniversityÇanakkaleTurkey
  2. 2.Department of Chemistry, Faculty of Sciences and ArtsPiri Reis UniversityIstanbulTurkey

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