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Supramolecular Chemistry of Organoplatinum(IV) Complexes Bearing Ligands with Remote Carboxylic Acid Substituents

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Abstract

The oxidative addition of compounds RBr to [PtMe2(bpox)], 1, bpox = 2,5-bis(2-pyridyl)-1,3,4-oxadiazole gave the corresponding organoplatinum(IV) complexes [PtBrMe2(R)(bpox)], 2, R = CH2CO2H; 3, R = CH2-4-C6H4CO2H; 4, R = CH2-4-C6H4CH2CO2H, whereas the reaction with BrCH2CH2CO2H gave only the platinum(II) complex [PtBrMe(bpox)], 5. The organoplatinum(IV) complexes with carboxylic acid substituents form unusual supramolecular structures in the solid state through hydrogen bonding interactions, some of which are supramolecular polymers.

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References

  1. I. Haiduc, F.T. Edelmann, Supramolecular Organometallic Chemistry (Wiley-VCH, Weinheim, 1999)

    Book  Google Scholar 

  2. J.L. Atwood, J.W. Steed, Encyclopedia of Supramolecular Chemistry (Marcel Dekker, New York, 2004)

    Google Scholar 

  3. M. Oh, G.B. Carpenter, D.A. Sweigart, Acc. Chem. Res. 37, 1 (2004)

    Article  CAS  Google Scholar 

  4. S.U. Son, J.A. Reingold, G.B. Carpenter, P.T. Czech, D.A. Sweigart, Organometallics 25, 5276 (2006)

    Article  CAS  Google Scholar 

  5. R.J. Puddephatt, Chem. Soc. Rev. 37, 2012 (2008)

    Article  CAS  Google Scholar 

  6. T.J. Burchell, D.J. Eisler, M.C. Jennings, R.J. Puddephatt, Chem. Commun. 2228 (2003)

  7. T.J. Burchell, R.J. Puddephatt, Inorg. Chem. 44, 3718 (2005)

    Article  CAS  Google Scholar 

  8. G.A. Jeffrey, An Introduction to Hydrogen Bonding (Oxford University Press, New York, 1997)

    Google Scholar 

  9. E.R.T. Tiekink, J.J. Vittal, Frontiers of Crystal Engineering (Wiley, Chichester, 2006)

    Google Scholar 

  10. A.Y. Robin, K.M. Fromm, Coord. Chem. Rev. 250, 2127 (2006)

    Article  CAS  Google Scholar 

  11. E.S. Tabei, H. Samouei, M. Rashidi, Dalton Trans. 40, 1138 (2011)

    Article  Google Scholar 

  12. M.I. Djuran, S.U. Milinkovic, A. Habtemariam, S. Parsons, P.J. Sadler, J. Inorg. Biochem. 88, 268 (2002)

    Article  CAS  Google Scholar 

  13. N.C. Gianneschi, E.R.T. Tiekink, L.M. Rendina, J. Am. Chem. Soc. 122, 8474 (2000)

    Article  CAS  Google Scholar 

  14. R.H.W. Au, C.S.A. Fraser, D.J. Eisler, M.C. Jennings, R.J. Puddephatt, Organometallics 28, 1719 (2009)

    Article  CAS  Google Scholar 

  15. R.H.W. Au, M.C. Jennings, R.J. Puddephatt, Organometallics 28, 3734 (2009)

    Article  CAS  Google Scholar 

  16. C.S.A. Fraser, H.A. Jenkins, M.C. Jennings, R.J. Puddephatt, Organometallics 19, 1635 (2000)

    Article  CAS  Google Scholar 

  17. M. Safa, R.J. Puddephatt, J. Organomet. Chem. 724, 7 (2013)

    Article  CAS  Google Scholar 

  18. C.S.A. Fraser, M.C. Jennings, R.J. Puddephatt, J. Chem. Soc., Chem. Commun. 1310 (2001)

  19. C.S.A. Fraser, M.C. Jennings, R.J. Puddephatt, J. Chem. Soc., Chem. Commun. 1224 (2002)

  20. C.S.A. Fraser, D.J. Eisler, R.J. Puddephatt, Polyhedron 25, 266 (2005)

    Article  Google Scholar 

  21. R.H.W. Au, L.J. Findlay-Shirras, N.M. Woody, M.C. Jennings, R.J. Puddephatt, Can. J. Chem. 87, 904 (2009)

    Article  CAS  Google Scholar 

  22. M.A. Safa, A. Abo-Amer, A. Borecki, B.F.T. Cooper, R.J. Puddephatt, Organometallics 31, 2675 (2012)

    Article  CAS  Google Scholar 

  23. J.D. Scott, R.J. Puddephatt, Organometallics 2, 1643 (1983)

    Article  CAS  Google Scholar 

  24. P.K. Monaghan, R.J. Puddephatt, Organometallics 3, 444 (1984)

    Article  CAS  Google Scholar 

  25. A. Abo-Amer, M.S. McCready, F. Zhang, R.J. Puddephatt, Can. J. Chem. 90, 46 (2012)

    Article  CAS  Google Scholar 

  26. J.D. Scott, R.J. Puddephatt, Organometallics 5, 2522 (1986)

    Article  CAS  Google Scholar 

  27. APEX 2, Crystallography software package; Bruker AXS: Madison, WI, 2005

  28. G.M. Sheldrick, Acta Cryst. A64, 112 (2008)

    Article  Google Scholar 

  29. R.J. Puddephatt, Angew. Chem. Int. Ed. 41, 261 (2002)

    Article  CAS  Google Scholar 

  30. M.S. McCready, R.J. Puddephatt, Dalton Trans. 41, 12378 (2012)

    Article  CAS  Google Scholar 

  31. D.E. Janzen, K.R. Mann, J. Chem. Crystallogr. 43, 292 (2013)

    Article  CAS  Google Scholar 

  32. R.J. Puddephatt, K.A. Azam, R.H. Hill, M.P. Brown, C.D. Nelson, R.P. Moulding, K.R. Seddon, M.C. Grossel, J. Am. Chem. Soc. 105, 5642 (1983)

    Article  CAS  Google Scholar 

  33. G.R. Whittell, M.D. Hager, U.S. Schubert, I. Manners, Nat. Mater. 10, 176 (2011)

    Article  CAS  Google Scholar 

  34. C.-P. Li, Q. Yu, J. Chen, M. Du, Cryst. Growth Des. 10, 2650 (2010)

    Article  CAS  Google Scholar 

  35. K. Chen, X. Jin, L. Tang, Prog. Chem. 22, 1094 (2010)

    Google Scholar 

  36. J. Zhang, C.-Y. Su, Coord. Chem. Rev. 257, 1373 (2013)

    Article  CAS  Google Scholar 

  37. Z. Qin, M.C. Jennings, R.J. Puddephatt, Chem. Commun. 2676 (2001)

  38. W.J. Hunks, M.C. Jennings, R.J. Puddephatt, Inorg. Chem. 41, 4590 (2002)

    Article  CAS  Google Scholar 

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Acknowledgments

We thank the NSERC (Canada) for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Al al-Bayt University, Al-Mafraq, Jordan

    Anwar Abo-Amer

  2. Department of Chemistry, University of Western Ontario, London, ON, N6A 5B7, Canada

    Anwar Abo-Amer & Richard J. Puddephatt

Authors
  1. Anwar Abo-Amer
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  2. Richard J. Puddephatt
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Corresponding author

Correspondence to Richard J. Puddephatt.

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Dedicated to the memory of Dwight Sweigart, in recognition of his distinguished contributions to organometallic chemistry.

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Abo-Amer, A., Puddephatt, R.J. Supramolecular Chemistry of Organoplatinum(IV) Complexes Bearing Ligands with Remote Carboxylic Acid Substituents. J Inorg Organomet Polym 24, 114–120 (2014). https://doi.org/10.1007/s10904-013-9959-x

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