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Supramolecular Coordination Assemblies Using 2-Aminodiacetic Terephthalic Acid Ligands: K[NiII(Hadta)(H2O)2]·H2O and K[Cu 1.5 II (adta)(H2O)1.5]·H2O

  • David P. Walsh
  • Lei Zhang
  • Paul E. Kruger
  • Wolfgang Schmitt
Article

Abstract

Two new network structures, K[NiII(Hadta)(H2O)2]·H2O (1) and K[Cu 1.5 II (adta)(H2O)1.5]·H2O (2) which are stabilized by 2-aminodiacetic terephthalic acid ligands have been synthesized and structurally characterized. Supplemental analyses include infrared spectroscopy and CHN analysis. 1 contains mononuclear secondary building units that are linked through potassium counterions and H-bonds to form a 3D network structure. 2 contains a 1D coordination polymer containing CuII ions with two different coordination environments. Potassium counterions further network these 1D chain structures.

Keywords

Coordination polymer Metal–organic frameworks Copper Nickel Crystal structure 

Notes

Acknowledgment

The authors thank the Science Foundation Ireland (SFI; 08/IN.1/I2047) and IRCSET (postdoctoral fellowship for L.Z.) for financial support.

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • David P. Walsh
    • 1
  • Lei Zhang
    • 1
  • Paul E. Kruger
    • 2
  • Wolfgang Schmitt
    • 1
  1. 1.School of Chemistry & CRANN, Trinity CollegeThe University of DublinDublin 2Ireland
  2. 2.Department of ChemistryUniversity of Canterbury, Te Whare Wananga WaitahaChristchurchNew Zealand

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