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Controlled Formation of Sm(III) Doping Polymer Thin Films Based on a New Macroligand with β-Diketonate

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Abstract

The macroligand of poly(vinyl ketone) has been synthesized. Chelation of polymeric ligands to Sm(III) ions produced metal-centered polymers, which were characterized by 1H-NMR, FT-IR, UV–Vis, elemental analysis, differential scanning calorimetry, fluorescence spectroscopy and gel permeation chromatography. A poly(vinyl ketone)/Sm(III) thin film was further prepared in situ. This method demonstrates easy processing relative to other methods of obtaining macroligands and Sm(III) complex films. The emission spectrum of the complex film excited by the 325.0 nm He–Cd line was measured at room temperature in the visible region and showed an efficient antenna effect to sensitize the poly(vinyl ketone)–Sm complex. Thus, the material may be used as a material for PLED devices.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No: 50025309, and No:90201016), the Project of Technology Promotion for Shan Xi province (No 20080321015), University’s Science and technology exploiture of Shanxi Province (20080320ZX) and Youthful Science Foundation of North University OF China. The authors are grateful for the financial support and express their thanks to Zhang Zhiyi for helpful discussions and Gao Jianfeng for IR measurements.

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Authors and Affiliations

  1. Research Center for Engineering Technology of Polymeric Composites of Shanxi Province, North University of China, Taiyuan, 030051, People’s Republic of China

    Youyi Sun, Binghua Yang, Guizhen Guo, Yaqing Liu & Guizhe Zhao

  2. Key Laboratory for Instrumentation Science & Dynamic Measurement, North University of China, Taiyuan, 030051, People’s Republic of China

    Youyi Sun

  3. National Key Laboratory for Electronic Measurement Technology, North University of China, Taiyuan, 030051, People’s Republic of China

    Youyi Sun

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  1. Youyi Sun
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  2. Binghua Yang
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  3. Guizhen Guo
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  4. Yaqing Liu
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  5. Guizhe Zhao
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Correspondence to Youyi Sun.

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Sun, Y., Yang, B., Guo, G. et al. Controlled Formation of Sm(III) Doping Polymer Thin Films Based on a New Macroligand with β-Diketonate. J Inorg Organomet Polym 21, 395–399 (2011). https://doi.org/10.1007/s10904-011-9502-x

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  • DOI: https://doi.org/10.1007/s10904-011-9502-x

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