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Solvothermal Synthesis, Crystal Structure and Magnetic Properties of a Novel 3D 2-Fold Interpenetrated Coordination Polymer [Co2(hfipbb)2(dps) (H2O)]n

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Abstract

A novel 3D two-fold interpenetrated coordination polymer, [Co2(hfipbb)2(dps)(H2O)]n (1) [H2hfipbb = 4,4′-(hexafluoroisopropylidene) bis(benzoic acid), dps = 4,4′-dipyridylsulfide], has been synthesized by solvothermal reaction of Co(OAc)2·4H2O, dps and H2hfipbb in the presence of KOH, and characterized by elemental analysis, IR spectra, PXRD, and single-crystal X-ray diffraction. The structure determination reveals that 1 exhibits a 3D two-fold interpenetrated (3, 4)-connected network with (83)2(85·10) topology. In addition, the thermogravimetric analysis and magnetic behavior of 1 were also studied.

Graphical Abstract

A novel 3D two-fold interpenetrated coordination polymer, [Co2(hfipbb)2(dps) (H2O)]n (1) has been synthesized and characterized by elemental analysis, IR spectra, PXRD, and single-crystal X-ray diffraction. Furthermore, thermogravimetric analysis and the magnetic properties of complex 1 were also studied.

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Acknowledgments

This work was financially supported by the Natural Scientific Research Foundation of Shaanxi Provincial Education Office of China (2010JK903, 2010JK905).

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an, 716000, Shaanxi, People’s Republic of China

    Ya-Pan Wu, Feng Fu, Long Tang, Xiang-Yang Hou & Zhu-Lian Zhang

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  1. Ya-Pan Wu
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  2. Feng Fu
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  3. Long Tang
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  4. Xiang-Yang Hou
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  5. Zhu-Lian Zhang
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Correspondence to Feng Fu.

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Wu, YP., Fu, F., Tang, L. et al. Solvothermal Synthesis, Crystal Structure and Magnetic Properties of a Novel 3D 2-Fold Interpenetrated Coordination Polymer [Co2(hfipbb)2(dps) (H2O)]n . J Inorg Organomet Polym 21, 595–601 (2011). https://doi.org/10.1007/s10904-011-9493-7

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