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Syntheses and Characterizations of Two One-Dimensional Coordination Polymers Assembled by Dicarboxylate and N-Donor Coligands

  • Xiuling Zhang
  • Meifang Jin
  • Yu’e Qiu
  • Feng Guo
Article

Abstract

Two new coordination polymers [Mn(oba)(1,10-phen)] n (1) and [Zn(oba)(Pbim)2] n (2) [H2oba = 2-(3-carboxyphenoxy)benzoic acid, 1,10-phen = 1,10-phenanthro line and pbim = 2-(2-Pyridyl)benzimidazole] have been synthesized and structurally characterized by elemental analysis, IR and X-ray diffraction. Single-crystal X-ray analyses revealed that 2,3′-oba ligand act as a bridging ligand, exhibiting three coordination modes to link metal ion: bis-monodentate, bidentate chelating and monodentate modes. Compound 1 and 2 all demonstrate a 1D chain. There exist intermolecular hydrogen bonds which further connect the 1D structure into 2D supramolecular structure in compound 1 and 2. In addition, the luminescent property for compound 2 is also investigated in the solid state at room temperature.

Keywords

Coordination polymer Crystal structure 

Notes

Acknowledgments

The authors gratefully acknowledge financial support from the National Natural Science Foundation of China (20971018), the National Natural Science Foundation of Shandong Province (ZR2010BL010) and Science & Technology Program of Shandong Province (2010GWZ20251).

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  1. 1.Department of ChemistryDe Zhou UniversityShandongChina
  2. 2.Department of Chemical and Environment EngineeringAnyang Institute of TechnologyAnyangChina

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