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Sonochemical Synthesis of One-Dimensional Nano-structure of Three-Dimensional Cadmium(II) Coordination Polymer

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Abstract

Nano-wires and nano-rods of a new three-dimensional cadmium(II) coordination polymer, {[Cd3(3-pyc)4(NCS)2(H2O)4]·2H2O} n (1); 3-Hpyc = 3-pyridinecarboxilic acid, were synthesized by a sonochemical method in two different concetrations. The morphology of the nano-structures depend strongly on reactants’ concentration. The new nano-structures were characterized by scanning electron microscopy, X-ray powder diffraction, elemental analyses and IR spectroscopy. Compound 1 was structurally characterized by single-crystal X-ray diffraction and is a three-dimensional polymer with two types of Cd(II) coordination environments.

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References

  1. A. Morsali, M.Y. Masoomi, Coord. Chem. Rev. 253, 1882–1905 (2009)

    Article  CAS  Google Scholar 

  2. K.-T. Wong, J.-M. Lehn, S.-M. Peng, G.-H. Lee, Chem. Commun. 22, 2259–2261 (2000)

    Article  Google Scholar 

  3. A.G. Bunn, P.J. Carroll, B.B. Wayland, Inorg. Chem. 31, 1297–1298 (1992)

    Article  CAS  Google Scholar 

  4. M.A.M. Abu-Youssef, A. Escuer, D. Gatteschi, M.A.S. Goher, F.A. Mautner, R. Vicente, Inorg. Chem. 38, 5716–5719 (1999)

    Article  CAS  Google Scholar 

  5. M. Aoyagi, K. Biradha, M. Fujita, J. Am. Chem. Soc. 121, 7457–7458 (1999)

    Article  CAS  Google Scholar 

  6. M. Fujita, Y.J. Kwon, S. Washizu, K.J. Ogura, J. Am. Chem. Soc. 116, 1151–1152 (1994)

    Article  CAS  Google Scholar 

  7. D.S. Chowdhuri, A. Rana, M. Bera, E. Zangrando, S. Dalai, Polyhedron 28, 2131–2136 (2009)

    Article  CAS  Google Scholar 

  8. R.L. Davidovich, V. Stavila, D.V. Marinin, E.I. Voit, K.H. Whitmire, Coord. Chem. Rev. 253, 1316–1352 (2009)

    Article  CAS  Google Scholar 

  9. A. Morsali, J. Abedini, Inorg. Chem. Commun. 8, 460–462 (2005)

    Article  CAS  Google Scholar 

  10. A.A. Soudi, F. Marandi, A. Ramazani, E. Ahmadi, A. Morsali, C. R. Chimie 8, 157–168 (2005)

    Article  CAS  Google Scholar 

  11. U. Englert, Coord. Chem. Rev. 254, 537–554 (2010)

    Article  CAS  Google Scholar 

  12. A. Morsali, A.R. Mahjoub, M.J. Soltanian, S.J. Darzi, Z. Anorg, Allg. Chem. 629, 2596–2599 (2003)

    Article  CAS  Google Scholar 

  13. A. Morsali, A.R. Mahjoub, J. Coord. Chem. 56, 779–785 (2003)

    Article  Google Scholar 

  14. W.-J. Shi, L. Hou, D. Li, Y.-G. Yin, Inorg. Chim. Acta 360, 588–598 (2007)

    Article  CAS  Google Scholar 

  15. A. Morsali, L.-G. Zhu, Inorg. Chem. Commun. 7, 1184–1187 (2004)

    Article  CAS  Google Scholar 

  16. N. Le Narvor, L. Toupet, C. Lapinte, J. Am. Chem. Soc. 117, 7129–7138 (1995)

    Article  CAS  Google Scholar 

  17. A. Caneschi, D. Gatteschi, N. Lalioti, C. Sangregorio, R. Sessoli, G. Venturi, A. Vindigni, A. Rettori, M.G. Pini, M.A. Novak, Angew. Chem. Int. Ed. 40, 1760–1763 (2001)

    Article  CAS  Google Scholar 

  18. M.C. Suen, J.C. Wang, J. Coord. Chem. 60, 257–268 (2007)

    Article  CAS  Google Scholar 

  19. M.C. Suen, J.C. Wang, J. Coord. Chem. 60, 2197–2205 (2007)

    Article  CAS  Google Scholar 

  20. B. Notash, N. Safari, A. Abedi, V. Amani, H. Reza Khavasi, J. Coord. Chem. 62, 1638–1649 (2009)

    Article  CAS  Google Scholar 

  21. S. Banerjee, M.G.B. Drew, A. Ghosh, Polyhedron 22, 2933–2941 (2003)

    Article  CAS  Google Scholar 

  22. K.M. Blake, G.A. Farnum, L.L. Johnston, R.L. LaDuca, Inorg. Chim. Acta 363, 88–96 (2010)

    Article  CAS  Google Scholar 

  23. E. Shyu, M.A. Braverman, R.M. Supkowski, R.L. LaDuca, Inorg. Chim. Acta 362, 2283–2292 (2009)

    Article  CAS  Google Scholar 

  24. S.-Q. Xia, S.-M. Hu, J.-C. Dai, X.-T. Wu, Z.-Y. Fu, J.-J. Zhang, W.-X. Du, Polyhedron 23, 1003–1009 (2004)

    Article  CAS  Google Scholar 

  25. L.-F. Chen, Z.-J. Li, Y.-Y. Qin, J.-K. Cheng, Y.-G. Yao, J. Mol. Struct. 892, 278–282 (2008)

    Article  CAS  Google Scholar 

  26. J. Ding, X. Liu, B. Li, L. Wang, Y. Zhang, Inorg. Chem. Commun. 11, 1079–1081 (2008)

    Article  CAS  Google Scholar 

  27. M.A. Braverman, R.M. Supkowski, R.L. LaDuca, J. Solid State Chem. 180, 1852–1862 (2007)

    Article  CAS  Google Scholar 

  28. S. Hazra, B. Sarkar, S. Naiya, M.G.B. Drew, A. Frontera, D. Escudero, A. Ghosh, Cryst. Growth Des. 10, 1677–1687 (2010)

    Article  CAS  Google Scholar 

  29. H.T. Shi, L.M. Qi, J.M. Ma, H.M. Cheng, J. Am. Chem. Soc. 125, 3450–3451 (2003)

    Article  CAS  Google Scholar 

  30. H. Zhang, D.R. Yang, D.S. Li, X.Y. Ma, S.Z. Li, D.L. Que, Cryst. Growth Des. 5, 547–550 (2005)

    Article  CAS  Google Scholar 

  31. D.B. Kuang, A.W. Xu, Y.P. Fang, H.Q. Liu, C. Frommen, D. Fenske, Adv. Mater 15, 1747–1750 (2003)

    Article  CAS  Google Scholar 

  32. F. Kim, S. Connor, H. Song, T. Kuykendall, P.D. Yang, Angew. Chem. Int. Ed. 43, 3673–3677 (2004)

    Article  CAS  Google Scholar 

  33. Mercury 1.4.1, Copyright Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK, 2001–2005

  34. L. J. Farrugia: Ortep-3 for Windows J. Appl. Cryst 30 565–565 (1997)

    Google Scholar 

  35. K.S. Suslick, S.B. Choe, A.A. Cichowlas, M.W. Grinstaff, Nature 353, 414–416 (1991)

    Article  CAS  Google Scholar 

  36. M. Sugimoto, J. Magn, Chem. Mater 133, 460–466 (1994)

    CAS  Google Scholar 

  37. G. Mahmoudi, A. Morsali, A.D. Hunter, M. Zeller, CrystEngComm. 9, 704–713 (2007)

    Article  CAS  Google Scholar 

  38. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th edn. (John Wiley and Sons, New York, 1997)

    Google Scholar 

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Acknowledgment

This work was supported by the Tabriz Azad University.

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Authors and Affiliations

  1. Research Laboratory, Department of Applied Chemistry, Islamic Azad Univrsity, Tabriz Branch, Tabriz, Iran

    Gholam Hossein Shahverdizadeh

  2. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Islamic Republic of Iran

    Ali Morsali

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  1. Gholam Hossein Shahverdizadeh
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  2. Ali Morsali
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Correspondence to Gholam Hossein Shahverdizadeh or Ali Morsali.

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Shahverdizadeh, G.H., Morsali, A. Sonochemical Synthesis of One-Dimensional Nano-structure of Three-Dimensional Cadmium(II) Coordination Polymer. J Inorg Organomet Polym 21, 694–699 (2011). https://doi.org/10.1007/s10904-011-9468-8

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  • DOI: https://doi.org/10.1007/s10904-011-9468-8

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