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Direct Synthesis of Cd3OSO4 Nano-particles From a New Three-dimensional Cadmium(II) Coordination Polymer Precursor

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Abstract

A new three-dimensional Cd(II) coordination polymer, {[Cd3(3-pyc)4(NCS)2(H2O)4]·2H2O} n (1); 3-Hpyc = 3-pyridinecarboxylic acid, was prepared and characterized by elemental analyses and IR spectroscopy. Compound 1 was structurally characterized by single-crystal X-ray diffraction. The structural determination shows that the compound is a new 3D coordination polymer has different environments containing CdO5NS and CdO2N4 units. This polymeric precursor has been used in the preparation of Cd3OSO4 nanoparticles by thermolysis in oleic acid. The new nano-structure of Cd3OSO4 was characterized by scanning electron microscopy and X-ray powder diffraction. This study demonstrates that coordination polymers may be suitable precursors to the preparation of desirable nanoscale materials.

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Acknowledgment

This work was supported by Tabriz Azad University.

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Authors and Affiliations

  1. Department of Applied Chemistry, Research Laboratory, Islamic Azad University, Tabriz Branch, Tabriz, Iran

    Gholam Hossein Shahverdizadeh

  2. Department of Chemistry, Zanjan University, Zanjan, Iran

    Shahla Masoudian, Ali Akbar Soudi & Hassan Hosseini Monfared

  3. Department of Chemistry, Payame Noor University, Abhar, Iran

    Fahime Bigdeli

  4. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran

    Ali Morsali

  5. Department of Chemistry, Shahid Beheshti University, Evin, P.O. Box 19839-63113, Tehran, Iran

    Hamid Reza Khavasi

Authors
  1. Gholam Hossein Shahverdizadeh
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  2. Shahla Masoudian
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  3. Ali Akbar Soudi
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  4. Fahime Bigdeli
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  5. Hassan Hosseini Monfared
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  6. Ali Morsali
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  7. Hamid Reza Khavasi
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Correspondence to Gholam Hossein Shahverdizadeh or Ali Morsali.

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Shahverdizadeh, G.H., Masoudian, S., Soudi, A.A. et al. Direct Synthesis of Cd3OSO4 Nano-particles From a New Three-dimensional Cadmium(II) Coordination Polymer Precursor. J Inorg Organomet Polym 21, 171–174 (2011). https://doi.org/10.1007/s10904-010-9443-9

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  • DOI: https://doi.org/10.1007/s10904-010-9443-9

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