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Four New Ag(I) Coordination Polymers: Synthesis, Crystal Structures and Thermal Stability

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Abstract

Four silver(I) coordination polymers of composition [Ag6(bptp)3(OOCCF2CF2COO)3]∞ (1), [Ag5(bptp)2(CF3SO3)5(CH3COCH3)2]∞ (2), [Ag(bmtm)(C10H7SO3)]∞ (3), and [Ag10(bpte)4(NO3)10]∞ (4) (bmtm = bis(methylthio)methane, bpte = 1,2-bis(phenylthio)ethane, bptp = 1,3-bis(phenylthio)propane) have been synthesized and structurally characterized. The 2D-coordination networks of both 1 and 2 consist of two meshed networks, (Ag-anion)∞ and (Ag-ligand)∞, which share their silver atoms. The 1D-coordination polymers of 3 are associated through weak van der Waals interactions into 2D network while polymer 4 forms a tubular structure. Relatively short Ag···Ag interactions are found in both 1 and 3. The stoichiometries of the obtained polymers were found to be independent of the starting materials metal-to-ligand ratio except for coordination polymer 4. Thermogravimetric analyses of 1 and 2 revealed that they decompose in a single step to metallic silver while 3 and 4 showed a two-step weight loss.

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Acknowledgments

This work was supported by the Centre d’Etude et de Recherche de Djibouti (M. O. A.) and the Natural Sciences and Engineering Research Council of Canada (F. B.).

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Authors and Affiliations

  1. Institut des Sciences de la Terre, Centre d’Etude et de Recherche de Djibouti (CERD), Route de l’aéroport, B.P. 486, Djibouti, Republic of Djibouti

    Mohamed Osman Awaleh

  2. Département de Chimie, Université de Montréal, C.P. 6128, Succursale Centre-ville, Montreal, QC, H3C 3J7, Canada

    Francois Brisse & Thierry Maris

  3. Institut des sciences de la mer de Rimouski, Université du Québec à Rimouski, 310 Allée des Ursulines, Rimouski, QC, G5L 3A1, Canada

    Youssouf Djibril Soubaneh

  4. Hôpital Général Peltier, Ministère de la Santé de la République de Djibouti, B.P. 1974, Djibouti, Republic of Djibouti

    Elias Said Dirieh

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  1. Mohamed Osman Awaleh
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  2. Francois Brisse
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  3. Youssouf Djibril Soubaneh
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Correspondence to Mohamed Osman Awaleh.

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Awaleh, M.O., Brisse, F., Soubaneh, Y.D. et al. Four New Ag(I) Coordination Polymers: Synthesis, Crystal Structures and Thermal Stability. J Inorg Organomet Polym 20, 816–824 (2010). https://doi.org/10.1007/s10904-010-9407-0

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  • DOI: https://doi.org/10.1007/s10904-010-9407-0

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