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Sonochemical Synthesis of New Nano-Belt One-Dimensional Double-Chain Lead(II) Coordination Polymer; As Precursor for Preparation of PbBr(OH) Nano-Structure

  • Mohammad Jaafar Soltanian Fard
  • Ali Morsali
Article

Abstract

Nano-structure of a new 1D double-chain Pb(II) coordination polymer, [Pb(μ-HPDC)(μ-Br)(H2O)]n (1), {H2PDC = 2,3-pyrazinedicarboxylic acid} was synthesized by a sonochemical method. The new nano-structure was characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses. The structure of compound 1 was determined by single crystal X-ray diffraction and consists of 1D double-chain polymeric units. The coordination number in compound 1 is six and each lead atom is coordinated by two oxygen atoms of HPDC, two nitrogen atoms of HPDC ligands, one bromide atom and one oxygen of H2O molecule. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses. Calcination of the nano-belts of compound 1 at 500 °C under air atmospheres yielded nano-sized particles of PbBr(OH) that characterized by scanning electron microscopy and X-ray powder diffraction.

Keywords

Nano-structure Coordination polymer Lead(II) Crystal structure 

Notes

Acknowledgements

This work was supported by the Science and Research Campus of Islamic Azad and Tarbiat Modares University.

Supplementary material

10904_2010_9392_MOESM1_ESM.docx (59 kb)
Supplementary material 1 (DOCX 59 kb)

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  1. 1.Science and Research BranchIslamic Azad UniversityTehranIran
  2. 2.Department of Chemistry, Faculty of SciencesTarbiat Modares UniversityTehranIran

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