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Synthesis of Molybdenum Oxide Nanohybrids as Efficient Catalysts in Oxidation of Alcohols

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Abstract

Novel layered materials based on molybdenum oxide have been synthesized using three amino-carboxylate ligands; terephetalic acid, p-aminobezoic acid and diaminobenzene. On the basis of X-ray diffraction, scanning electron microscopy, thermogravimetry, and infrared results, the insertion of organic ligands into the interlayer space of molybdenum oxide has been proposed. Moreover, the influence of organic guests on the oxide structure and also their catalytic performance are discussed. Furthermore, fabrication of the nanostructured molybdenum oxide is achieved by calcinations of these hybrid materials at 600 °C. Somewhat oriented nanoplatelets are viewed with different catalytic activity.

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Acknowledgments

Support of this investigation by Tarbiat Modares University is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Tarbiat Modares University, Alleahmad Ave, 14155-4838, Tehran, Iran

    Maryam Afsharpour & Alireza Mahjoub

  2. Department of Chemistry, Shahid Beheshti University, G.C., 1983963113, Tehran, Iran

    Mostafa M. Amini

Authors
  1. Maryam Afsharpour
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  2. Alireza Mahjoub
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  3. Mostafa M. Amini
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Correspondence to Alireza Mahjoub.

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Afsharpour, M., Mahjoub, A. & Amini, M.M. Synthesis of Molybdenum Oxide Nanohybrids as Efficient Catalysts in Oxidation of Alcohols. J Inorg Organomet Polym 19, 298–305 (2009). https://doi.org/10.1007/s10904-009-9285-5

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