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Synthesis and Structures of Two Triorganotin(IV) Polymers R3Sn{O2CC6H4[N=C(H)}{C(CH3)CH(CH3)-3-OH]-p} n (R = Me and Ph) Containing a 4-[(2Z)-(3-Hydroxy-1-methyl-2-butenylidene)amino] benzoic Acid Framework

  • Tushar S. Basu Baul
  • Cheerfulman Masharing
  • Giuseppe Ruisi
  • Claudio Pettinari
  • Anthony Linden
Article

Abstract

Two new polymeric triorganotin(IV) complexes R3Sn{O2CC6H4[N=C(H)}{C(CH3)CH(CH3)-3-OH]-p} n ([Me3Sn(LH)] n : 1) and ([Ph3Sn(LH)] n : 2) containing a 4-[(2Z)-(3-hydroxy-1-methyl-2-butenylidene)amino]benzoate (LH) framework were prepared. Both compounds have been characterized by 1H, 13C, 119Sn NMR, IR and 119Sn Mössbauer spectroscopic techniques in combination with elemental analyses. The crystal structures of complexes 1 and 2 reveal that they exist as polymeric zig-zag chains in which the LH-bridged Sn-atoms adopt a trans-R3SnO2 trigonal bipyramidal configuration with R groups in the equatorial positions and the axial sites occupied by an oxygen atom from the carboxylate ligand and the alcoholic oxygen atom of the next carboxylate ligand in the chain. The carboxylate ligands coordinate in the zwitterionic form with the alcoholic proton moved to the nearby nitrogen atom.

Keywords

Organometallic polymers Triorganotin carboxylates 4-[(2Z)-(3-Hydroxy-1-methyl-2-butenylidene)amino]benzoate NMR Mössbauer Crystal structure 

Notes

Acknowledgments

The financial support of the Department of Science & Technology, New Delhi, India (Grant No. SR/S1/IC-03/2005, TSBB) and the University Grants Commission, New Delhi, India through SAP-DSA, Phase-III are gratefully acknowledged. GR is indebted to the Università di Palermo, Italy for financial support. Dr. David Wolstenholme, Dalhousie University, Canada is thanked for assistance with the crystal structure determination of compound 1.

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Tushar S. Basu Baul
    • 1
  • Cheerfulman Masharing
    • 1
  • Giuseppe Ruisi
    • 2
  • Claudio Pettinari
    • 3
  • Anthony Linden
    • 4
  1. 1.Department of ChemistryNorth-Eastern Hill UniversityShillongIndia
  2. 2.Dipartimento di Chimica Inorganica e Analitica “Stanislao Cannizzaro”Università di PalermoPalermoItaly
  3. 3.Dipartimento di Scienze ChimicheUniversità di CamerinoCamerinoItaly
  4. 4.Institute of Organic ChemistryUniversity of ZurichZurichSwitzerland

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