Abstract
The heteronuclear complex, {[Cu(4(5)-Meim)4][Ni(CN)4] · H2O}n (1), (4(5)-Meim = 4(5)-methylimidazole) was synthesized and characterized by FT-IR spectroscopy, single crystal X-ray diffraction, thermal analysis and elemental analysis. The Cu(II) ion has a distorted square planar geometry, extended to (4 + 2) weak coordination by two nitrogen atoms of the cyano group. The coordination sphere around the Ni(II) ion should be described as a 4 + 2 geometry with the four cyano groups and the axial coordination site is located at the imidazole ring though a weak Ni···π interaction. The coordination bond is much stronger than the Ni···π interactions and it is expected that the formation of the coordination bond will affect more significantly the position of the absorption bands associated with the vibrations of the ligand. In addition, the out-of-plane modes of 4(5)-Meim are shifted to higher frequencies relative to free ligand. We propose that these shifts are indicative of the weak CH∙∙∙π and Ni∙∙∙π interactions, according to the crystallographic and spectroscopic data.
Similar content being viewed by others
References
J. Cernak, M. Orendac, I. Potocnak, J. Chomic, A. Orendacova, J. Skorsepa, A. Feher, Coord. Chem. Rev. 224, 51 (2002)
Z. Smekal, I. Cisarova, J. Mrozinski, Polyhedron 20, 3301 (2001)
Z. Smekal, H. Strnadova, Z. Sindelar, M. Pavlicek, J. Walla, Chem. Pap. 59(2), 89 (2005)
P.S. Mukherjeee, T.K. Maji, T. Mallah, E. Zangrando, L. Randaccio, N.R. Chaudhuri, Inorg. Chim. Acta 315, 249 (2001)
D. Ghoshal, T.K. Maji, G. Rosair, G. Mostafa, Acta Crystallogr. C60, 212 (2004)
T. Iwamoto, J. Incl. Phenom. 24, 61 (1996)
J.H. Rayner, H.M. Powell, J. Chem. Soc. 319, 28 (1952)
S. Akyüz, A.B. Dempster, R.L. Morehouse, S. Suzuki, J. Mol. Struct. 17, 105 (1973)
G.S. Kürkçüoğlu, T. Hökelek, O.Z. Yeşilel, S. Aksay, Struct. Chem. 19, 493 (2008)
G.S. Kürkçüoğlu, O.Z. Yesilel, İ. Kavlak, O. Büyükgüngör, Z. Anorg, Allg. Chem. 635, 175 (2009)
G.S. Kürkçüoğlu, O.Z. Yesilel, İ. Kavlak, O. Büyükgüngör, Struct. Chem. 19, 879 (2008)
H. Yuge, C.H. Kim, T. Iwamoto, T. Kitazawa, Inorg. Chim. Acta 257, 217 (1997)
M. Şenyel, Bull. Pure Appl. Sci. 20, 61 (2001)
A.B. Dempster, H. Uslu, Spectrochim. Acta 34A, 71 (1978)
M. Şenyel, G.S. Kürkçüoğlu, J. Appl. Spect. 68, 862 (2001)
J.T. Edsall, G. Felsenfeld, D.S. Goodman, F.R.N. Gurd, J Am. Chem. Soc. 76, 3034 (1954)
Y. Nozaki, F.R.N. Gurd, R.H. Chen, J.T. Edsall, Ibid 79, 2123 (1957)
G. Iwarsson, Acta Chem. Scand. 27, 3523 (1973)
B. Lenarcik, K. Kurdziel, Pol. J. Chem. 55, 737 (1982)
H. Imai, H. Tamura, Bull. Chem. Soc. Jpn. 64, 2077 (1991)
C.C. Su, J.H. Chen, K.Y. Hwang, S.J. Liu, S.W. Wang, S.L. Wang, S.N. Liu, Inorg. Chim. Acta 196, 231 (1992)
A. Turek, M. Olczak-Kobza, J. Thermal Anal. 54, 133 (1998)
Y.-Q. Zheng, J.-L. Liu, E.-B. Ying, Z. Anorg, Allg. Chem. 629, 673 (2003)
G.M. Sheldrick, SHELXS–97 and SHELXL–97. Program for Refinement of Crystal Structures (University of Göttingen, Germany, 1997)
Stoe & Cie (2002), X–Area (Version 1.18) and X–Red32 (Version 1.04), (Stoe&Cie, Darmstadt, Germany, 2001)
L.J. Farrugia, ORTEP–III. Program for molecular drawing. J. Appl. Crystallogr. 30, 565 (1997)
L.J. Farrugia, WinGX suite for single crystal small molecule crystallography. J. Appl. Crystallogr. 32, 837 (1999)
A.-M. Bellocq, C. Garrigou-Lagrange, J. Chim. Phys. Physico-Chim. Biol. 66, 1511 (1969)
D.A. Carter, J.E. Pemberton, J. Raman Spect. 28, 939 (1997)
D. Lin-vien, N.B. Colthup, W.G. Fateley, J.G. Grasselli, in The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules. (Academic Press, Boston, 1991)
R.D. Hill, G.D. Meakins, J. Chem. Soc. 760 (1958)
J.B. Hodgson, G.C. Percy, D.A. Thornton, J. Mol. Struc. 66, 81 (1980)
Y. Tufan, N. Karacan, J.E.D. Davies, Vibr. Spect. 23, 51 (2000)
Y. Tufan, J. Incl. Phenom. 48, 131 (2004)
R.L. Mc Cullough, L.H. Jones, G.A. Crosby, Spectrochim. Acta 16, 929 (1960)
S. Akyüz, A.B. Dempster, R.L. Morehouse, Spectrochim. Acta 30A, 1989 (1974)
S. Akyüz, J. Mol. Struct. 68, 41 (1980)
J. Cernak, J. Skorsepa, K.A. Abboud, M.W. Meisel, M. Orendac, A. Orendacova, A. Feher, Inorg. Chim. Acta 326, 3 (2001)
S.G. Baca, S.T. Malinovskii, P. Franz, C. Ambrus, H.S. Evans, N. Gerbeleu, S. Decurtins, J. Solid State Chem. 177, 2841 (2004)
P.X. Rojas-Gonzalez, D. Choquesillo-Lazarte, J.M. Gonzalez-Perez, S.A. Ruiz-Garcia, R. Carballo, A. Castineiras, J. Niclos-Gutierrez, Polyhedron 22, 1027 (2003)
A. Erdönmez, Ş. Işık, O. Büyükgüngör, S. Akyüz, G. Nardın, Spectr. Lett. 31, 1325 (1998)
J. Lokaj, K. Gyerova, A. Sopkova, J. Sıvy, V. Kettmann, V. Vrabel, Acta Crystallogr. C47, 2447 (1991)
T. Hökelek, D. Ülkü, Acta Crystallogr. C44, 832 (1988)
Acknowledgment
This work was supported by the Research Fund of Eskişehir Osmangazi University, project number: 200719025.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kürkçüoğlu, G.S., Yeşilel, O.Z., Kavlak, İ. et al. Synthesis, Characterization and Crystal Structure of a Novel Three-Dimensional Supramolecular Framework Containing Ni···π Interaction Heteronuclear Complex: {[Cu(4(5)-Meim)4][Ni(CN)4] · H2O}n . J Inorg Organomet Polym 19, 314–321 (2009). https://doi.org/10.1007/s10904-009-9277-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10904-009-9277-5