Synthesis and Characterization of Nanostructure BPO4
Boron phosphate (BPO4) is a well known catalyst for a range of organic chemical reactions. In this paper, we report the preparations and characterizations of nano-sized BPO4 and nano-BPO4-based core-shell spheres. The samples were synthesized hydrothermally using H3BO3, H3PO4 and short chain n-alkylamines (n = 3, 4) as starting materials. The resulting products were characterized by powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scan electron microscopy (SEM) and transmission electron microscopy (TEM), respectively. A possible mechanism for the formation of the materials is also discussed.
KeywordsNano-sized BPO4 Core-shell BPO4 n-Alkylamine Hydrothermal synthesis
This work was supported by the Major Basic Research Programs of Shanghai (No. 07DJ14001) and State ‘973’ project (2007CB936704), the Hundred Talents Program from the Chinese Academy of Sciences and fund for Young Leading Researchers from Shanghai municipal government.
- 13.A. Tada, H. Suzuka, Y. Imizu, Chem. Lett. 423 (1987)Google Scholar
- 17.S. Imamura, T. Higashihara, H. Jindai, Chem. Lett. 22, 1667 (1993)Google Scholar
- 28.A. Baykal, M. Kizilyalli, M. Toprak, R. Kniep, Turk. J. Chem. 25, 425 (2001)Google Scholar