Skip to main content
SpringerLink
Log in

A 3D 3d-4f Heterometallic Coordination Polymer: Synthesis, Crystal Structure and Properties

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

A three-dimensional heterometallic coordination polymer formulated as Sm2Zn2(BIPA)5(H2O)2 (1) (H2BIPA = 5-bromoisophthalic acid) was synthesized by hydrothermal reaction of H2BIPA with Sm2O3 and Zn(NO3)2. Complex 1 shows an 8-connected (36.418.53.6) topological network. The thermal analysis of complex 1 has been measured and discussed. Additionally, the photoluminescent property of complex 1 was investigated.

Graphical Abstract

An intriguing feature of complex 1 is a 3D eight-connected framework of 36.418.53.6 topology.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. (a) S.R. Batten, R. Robson, Angew. Chem. Int. Ed. 37, 1460 (1998); (b) M. Eddaoudi, D.B. Moler, H. Li, B. Chen, T.M. Reineke, M. O’Keeffe, O.M. Yaghi, Acc. Chem. Res. 34, 319 (2001); (c) G.S. Papaefstathiou, L.R. MacGillivray, Coord. Chem. Rev. 246, 169 (2003); (d) O.R. Evans, W. Lin, Acc. Chem. Res. 35, 511 (2002); (e) B. Moulton, M.J. Zaworotko, Chem. Rev. 101, 1629 (2001)

  2. (a) J.S. Seo, D. Whang, H. Lee, S.I. Jun, J. Oh, Y.J. Jeon, K. Kim, Nature 404, 982 (2000); (b) O.R. Evans, H.L. Ngo, W. Lin, J. Am. Chem. Soc. 123, 10395 (2001); (c) W. Lin, J. Solid State Chem. 178, 2486 (2005)

  3. (a) H. Li, M. Eddaoudi, M. O’Keeffe, O.M. Yaghi, Nature 402, 276 (1999); (b) M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O’Keeffe, O.M. Yaghi, Science 295, 469 (2002); (c) J.L.C. Rowsell, E.C. Spencer, J. Eckert, J.A.K. Howard, O.M. Yaghi, Science 309, 1350 (2005); (d) G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surblé, I. Margiolaki, Science 309, 2040 (2005)

  4. (a) A.J. Tasiopoulos, A. Vinslava, W. Wernsdorfer, K.A. Abboud, G. Christou, Angew. Chem. Int. Ed. 43, 2117 (2004); (b) M. Murugesu, M. Habrych, W. Wernsdorfer, K.A. Abboud, G. Christou, J. Am. Chem. Soc. 126, 4766 (2004); (c) G.J. Halder, C.J. Kepert, B. Moubaraki, K.S. Murray, J.D. Cashion, Science 298, 1762 (2002)

  5. G.B. Deacon, R. Philips, Coord. Chem. Rev. 88, 227 (1980)

    Article  Google Scholar 

  6. (a) H.K. Chae, M. Eddaoudi, J. Kim, S.I. Hauck, J.F. Hartwig, M. O’Keeffe, O.M. Yaghi, J. Am. Chem. Soc. 123, 11482 (2001); (b) J.L.C. Rowsell, A.R. Millward, K.S. Park, O.M. Yaghi, J. Am. Chem. Soc. 126, 5666 (2004); (c) J.L.C. Rowsell, O.M. Yaghi, J. Am. Chem. Soc. 128, 1304 (2006); (d) Q.B. Bo, Z.X. Sun, G.L. Song, G.X. Sun, J. Inorg. Organmet. Polym. Mater. 17, 615 (2007)

  7. (a) L.-Y. Zhang, G.-F. Liu, S.-L. Zheng, B.-H. Ye, X.-M. Zhang, X.-M. Chen, Eur. J. Inorg. Chem. 2965 (2003); (b) J. Tao, M.-L. Tong, J.-X. Shi, X.-M. Chen, S.W. Ng, Chem. Commun. 2043 (2000); (c) C.S. McCowan, T.L. Groy, M.T. Caudle, Inorg. Chem. 41, 1120 (2002)

  8. (a) N.W. Ockwig, O. Delgado-Friedrichs, M. O’Keeffe, O.M. Yaghi, Acc. Chem. Res. 38, 176 (2005); (b) I.A. Baburin, V.A. Blatov, L. Carlucci, G. Ciani, D.M. Proserpio, J. Solid State Chem. 178, 2452 (2005); (c) V.A. Blatov, L. Carlucci, G. Ciani, D.M. Proserpio, CrystEngComm 6, 377 (2004)

  9. (a) A.F. Wells, Three-Dimensional Nets and Polyhedra (Wiley-Interscience, New York, 1977); (b) I.A. Baburin, V.A. Blatov, Acta Cryst. B 63, 791 (2007); (c) V.A. Blatov, Acta Cryst. A 63, 329 (2007)

  10. (a) J. Ballato, J.S. Lewis, P. Holloway, Mater. Res. Soc. Bull. 24, 51 (1999); (b) A.J. Steckl, J.M. Zavada, Mater. Res. Soc. Bull. 24, 33 (1999); (c) M. Bredol, U. Kynast, C. Ronda, Adv. Mater. 3, 361 (1991)

  11. (a) Y.-Q. Sun, J. Zhang, Y.-M. Chen, G.-Y. Yang, Angew. Chem. Int. Ed. 44, 5814 (2005); (b) M.R. Bnrgstein, M.T. Gamer, P.W. Roesky, J. Am. Chem. Soc. 126, 5213 (2004); (c) T.M. Reineke, M. Eddaoudi, M. O’Keeffe, O.M. Yaghi, Angew. Chem. Int. Ed. 38, 2590 (1999)

  12. (a) M.B. Zhang, J. Zhang, S.T. Zheng, G.Y. Yang, Angew. Chem. Int. Ed. 44, 1385 (2005); (b) J.W. Cheng, J. Zhang, S.T. Zheng, M.B. Zhang, G.Y. Yang, Angew. Chem. Int. Ed. 45, 73 (2006); (c) J. Lisowski, P. Starynowicz, Inorg. Chem. 38, 1351 (1999)

  13. (a) B. Zhao, P. Cheng, Y. Dai, C. Cheng, D.Z. Liao, S·P. Yan, Z.H. Jiang, G.L. Wang, Angew. Chem. Int. Ed. 42, 934 (2003); (b) B. Zhao, P. Cheng, X.Y. Chen, C. Cheng, W. Shi, D.Z. Liao, S·P. Yan, Z.H. Jiang, J. Am. Chem. Soc. 126, 3012 (2004); (c) T. Sanada, T. Suzuki, T. Yoshida, S. Kaizaki, Inorg. Chem. 37, 4712 (1998)

  14. (a) Y.P. Ren, L.S. Long, B.W. Mao, Y.Z. Yuan, R.B. Huang, L.S. Zheng, Angew. Chem. Int. Ed. 42, 532 (2003); (b) Y.J. Zhang, B.Q. Ma, S. Gao, J.R. Li, Q.D. Liu, G.H. Wen, X.X. Zhang, J. Chem. Soc. Dalton Trans. 2249 (2000); (c) H. Maas, A. Currao, G. Calzaferri, Angew. Chem. Int. Ed. 41, 2495 (2002)

  15. (a) N. Sabatini, M. Guardigli, J.-M. Lehn, Coord. Chem. Rev. 123, 201 (1993); (b) M. Shibasaki, N. Yoshikawa, Chem. Rev. 102, 2187 (2002); (c) W. Su, R. Cao, M.C. Hong, J. Chen, J. Liu, Chem. Commun. 1389 (1998)

  16. (a) Y.C. Liang, M.C. Hong, W.P. Su, R. Cao, W.J. Zhang, Inorg. Chem. 40, 4574 (2001); (b) P. Mahata, G. Sankar, G. Madras, S. Natarajan, Chem. Commun. 5787 (2005); (c) B. Zhao, X.-Y. Chen, W.-Z. Wang, P. Cheng, B. Ding, D.-Z. Liao, S.-P. Yan, Z.-H. Jiang, Inorg. Chem. Commun. 8, 178 (2005); (d) J.-J. Zhang, T.-L. Sheng, S.-Q. Xia, G. Leibeling, F. Meyer, S.-M. Hu, R.-B. Fu, S.-C. Xiang, X.-T. Tao, Inorg. Chem. 43, 5472 (2004)

  17. (a) J.M. Boncella, R.A. Andersen, Inorg. Chem. 23, 432 (1984); (b) H. Deng, S.G. Shore, J. Am. Chem. Soc. 113, 8538 (1991); (c) H. Deng, S. Chun, P. Florian, P.J. Grandinetti, S.G. Sore, Inorg. Chem. 35, 3891 (1996); (d) F. He, M.-L. Tong, X.-M. Chen, Inorg. Chem. 44, 8285 (2005)

  18. (a) A. Loosli, M. Wermuth, H.-U. Güdel, S. Capelli, S. Hauser, H.-B. Bürgi, Inorg. Chem. 39, 2289 (2000); (b) A. Figuerola, C. Diaz, J. Ribas, V. Tangoulis, J. Granell, F. Lloret, Mahía, J.M. Maestro, Inorg. Chem. 42, 641 (2003); (c) J.-P. Costes, G. Novitchi, S. Shova, F. Dahan, B. Donnadieu, J.-P. Tuchagues, Inorg. Chem. 43, 7792 (2004)

  19. T. Higashi, ABSCOR: Program for Absorption Correction (Rigaku Corporation, Tokyo, Japan, 1995)

    Google Scholar 

  20. P.T. Beurskens, G. Admiraal, G. Beurskens, W.P. Bosman, R. De Gelder, R. Israel, J.M.M. Smits, DIRDIF-94: The DIRDIF-94 program system (Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands, 1994)

  21. TEXSAN: Crystal Structure Analysis Package (Molecular Structure Corporation, 1985 and 2004)

  22. (a) A. Thirumurugan, S. Natarajan, Inorg. Chem. Commun. 7, 395 (2004); (b) Z.H. Zhang, T. Okamura, Y. Hasegawa, H. Kawaguchi, L.Y. Kong, W.Y. Sun, N. Ueyama, Inorg. Chem. 44, 6219 (2005); (c) Y.L. Qu, Y.X. Ke, S.M. Lu, J. Fan, G.J. Pan, J.M. Li, J. Mol. Struct. 734, 7 (2005)

  23. S. Petoud, S.M. Cohen, J.C.G. Bünzli, K.N. Raymond, J. Am. Chem. Soc. 125, 13324 (2003)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (20731004) and the Natural Science Foundation of the Education Committee of Anhui Province, China (KJ2008B004).

Author information

Authors and Affiliations

  1. Anhui Key Laboratory of Functional Coordination Compounds, College of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246003, People’s Republic of China

    Guang-Xiang Liu, Yan Wang, Liang-Fang Huang, Xue-Jun Kong & Hong Chen

Authors
  1. Guang-Xiang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yan Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Liang-Fang Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xue-Jun Kong
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Hong Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Guang-Xiang Liu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liu, GX., Wang, Y., Huang, LF. et al. A 3D 3d-4f Heterometallic Coordination Polymer: Synthesis, Crystal Structure and Properties. J Inorg Organomet Polym 18, 358–363 (2008). https://doi.org/10.1007/s10904-008-9212-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-008-9212-1

Key Words

Search

Navigation