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Hydrothermal Synthesis and Crystal Structure of a Novel 2-Fold Interpenetrated Framework Based on Tetranuclear Homometallic Cluster

  • Rong-Yi Huang
  • Xue-Jun Kong
  • Guang-Xiang Liu
Article

Abstract

A novel 2-fold parallel interpenetrated polymer, Zn2(OH)(pheno)(p-BDC)1.5 · H2O (1) (pheno = phenanthrene-9,10-dione; p-BDC = 1,4-benzenedicarboxylate) was prepared by hydrothermal synthesis and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. Complex 1 crystallizes in the orthorhombic space group Pbca and affords a three-dimensional (3D) six-connected α-Po network.

Graphical Abstract

Hydrothermal Synthesis and Crystal Structure of a Novel 2-Fold Interpenetrated Framework Based on Tetranuclear Homometallic Cluster

Rong-Yi Huang, Xue-Jun Kong and Guang-Xiang Liu

A intriguing feature of complex 1 is a pair of identical 3D single nets is interlocked with each other, thus directly leading to the formation of a 2-fold interpenetrated 3D → 3D architecture.

Keywords

Carboxylate ligand Homometallic complex α-Po 

Notes

Acknowledgments

This work was supported by the National Natural Science Foundation of China (20731004) and the Natural Science Foundation of the Education Committee of Anhui Province, China (KJ2008B004).

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© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  1. 1.Anhui Key Laboratory of Functional Coordination Compounds, College of Chemistry and Chemical EngineeringAnqing Normal UniversityAnqingP.R. China

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