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Crystal Structures, Thermogravimetric and Magnetic Properties of Four Organodiamine Templated Vanadium Oxide Frameworks: Influences of Diaminoalkane Templates

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A series of four diaminoalkane templated vanadium oxide polymeric frameworks, [V IV2 O8V V2 O2](C2H10N2), [V IV2 O8V V2 O2](C3H12N2), [V IV4 O10V V2 O4](C4H14N2) and [V IV4 O10V V2 O4](C5H16N2), have been successfully prepared under hydrothermal conditions. The crystal structures are fully characterized revealing layered structures composed of common inorganic building units, namely {VIVO5} square pyramids and {VVO4} tetrahedra. The layer registries are different depending on the molecular structure of the diaminoalkanes, and can be accounted for by the organic-inorganic interface interactions. The analysis of hydrogen bonds indicates their important role in directing two- and three-dimensional structural architectures. The influences of different diaminoalkanes are also apparent in both thermogravimetric and complex magnetic behaviors, and are discussed in details.

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Acknowledgements

The authors thank the Thailand Research Fund (TRF) and the Commission for Higher Education (CHE) for financial support, the Department of Chemistry, Khon Kaen University for the access to the VSM magnetometer, and the Synchrotron Radiation Source, CCLRC Daresbury Laboratory for access to microcrystal diffraction facilities. Mr. Settheeworrarit additionally thanks the Development and Promotion of Science and Technology Talents Project (DPST), the Centre for Innovation in Chemistry: Postgraduate Education and Research Program in Chemistry (PERCH-CIC) and the Graduate School, Chiang Mai University for a graduate scholarship.

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Authors and Affiliations

  1. Inorganic Materials Research Unit, Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai, 50200, Thailand

    Thapanon Settheeworrarit & Apinpus Rujiwatra

  2. Department of Chemistry, University of Hull, Kingston upon Hull, HU6 7RX, UK

    Timothy J. Prior

  3. Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen, 40002, Thailand

    Santi Meansiri

  4. Department of Chemistry, Faculty of Science, Kasetsart University, Bangkok, 10900, Thailand

    Jumras Limtrakul

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  1. Thapanon Settheeworrarit
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  5. Apinpus Rujiwatra
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Correspondence to Apinpus Rujiwatra.

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Settheeworrarit, T., Prior, T.J., Meansiri, S. et al. Crystal Structures, Thermogravimetric and Magnetic Properties of Four Organodiamine Templated Vanadium Oxide Frameworks: Influences of Diaminoalkane Templates. J Inorg Organomet Polym 18, 253–263 (2008). https://doi.org/10.1007/s10904-007-9171-y

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  • DOI: https://doi.org/10.1007/s10904-007-9171-y

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