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Two Novel Metal Phosphonate Compounds: Different One-Dimension Chain Structures Constructed by Imidazole and 1-Aminoethylidenediphosphonic Acid

  • Shuo-ping Chen
  • Ming Li
  • Qiao-lan Chen
  • Yan Guo
  • Si-min Wu
  • Liang-jie Yuan
  • Ju-tang Sun
Article

Abstract

Hydrothermal reactions of 1-aminoethylidenediphosphonic acid (AEDPH4), imidazole (Im) and divalent metal oxides afforded two novel phosphonate compounds: Zn2(AEDP)(Im)3·H2O (1), Cd3(AEDPH)2(Im)5·Im (2). Compounds 1 and 2 are both one-dimensional (1-D) coordination polymers that illustrate different chain motifs. Compound 1 features a zigzag double chain structure while compound 2 has a distorted square-chain structure. Both compounds are further extended to form three-dimensional (3-D) supramolecular structures via hydrogen bonds. The effect of degree of deprotonization of AEDPH4 on the structural types of the final products is also discussed.

Keywords

1-Aminoethylidenediphosphonic acid Coordination polymer Supramolecular structures Degree of deprotonization Coordination mode Hydrogen bonding 

Notes

Acknowledgements

This work was supported by grants of the National Nature Science Foundation of China (No. 20671074).

Supplementary material

10904_2007_9154_MOESM1_ESM.doc (184 kb)
MOESM 1: Schematic view of the unit cell linking of compound 1 by hydrogen bonds. Dashed lines represent hydrogen bonds. (DOC 185 kb)
10904_2007_9154_MOESM2_ESM.doc (220 kb)
MOESM 2: Schematic view of the unit cell linking of compound 2 by hydrogen bonds. Dashed lines represent hydrogen bonds. (DOC 221 kb)

References

  1. 1.
    (a) E. Stein, A. Clearfield, and M.A. Subramanian, Solid State Ionics, 83, 113 (1996); (b) G. Alberti and U. Costantino, in Comprehensive Supramolecular Chemistry, ed. By J.-M. Lehn, (Pergamon-Elsevier Science Ltd., London, 1996, p. 1); (c) A Clearfield, Curr. Opin. Solid State Mater. Sci. 1, 268 (1996); (d) A. Clearfield, in Metal phosphonate chemistry in Progress in Inorganic Chemistry, vol 47, ed. by K.D. Karlin (John Wiley & Sons, New York, 1998), pp. 371–510, and references thereinGoogle Scholar
  2. 2.
    For example (a) J.G. Mao, Z.K. Wang, and A. Clearfield, J. Chem. Soc., Dalton Trans. 23, 4457 (2002); (b) J.L. Song, J.G. Mao, Y.Q. Sun, Z.C. Dong, Eur. J. Inorg. Chem. 23, 4218 (2003); (c) Y. Gong, W. Tang, W.B. Hou, Z.Y. Zha, and C.W. Hu, Inorg. Chem. 45, 4987 (2006); (d) H.H. Song, L.M. Zheng, C.H. Lin, S.L. Wang, X.Q. Xin, S. Gao, Chem. Mater. 11, 2382 (1999); (e) H.H. Song, L.M. Zheng, Z.M. Wang, C.H. Yan, X.Q. Xin, Inorg. Chem. 40, 5024 (2001)Google Scholar
  3. 3.
    For example; (a) J.G. Mao, Z.K. Wang, A. Clearfield, J. Chem. Soc., Dalton Trans. 23, 4457 (2002); (b) F. Fredoueil, M. Evain, D. Massiot, M. Bujoli, P. Janvier, A. Clearfield, B. Bujoli, J. Chem. Soc., Dalton Trans. 23, 1508 (2002); (c) Z.M. Sun, J.G. Mao, Y.Q. Sun, H.Y. Zeng, A. Clearfield, New J. Chem. 27, 1326 (2003); (d) C.V. Krishnamohan Sharma, C.C. Chusuei, R. Clérac, T. Mǒller, K.R. Dunbar, A. Clearfield, Inorg. Chem. 42, 8300 (2003); (e) D. Grohol, F. Gingl, A. Clearfield, Inorg. Chem. 38, 751 (1999)Google Scholar
  4. 4.
    For example; (a) J.G. Mao, Z.K. Wang, A. Clearfield, New J. Chem. 26, 1010 (2002); (b) D. Kong, Y. Li, J.H. Ross Jr, A. Clearfield, Chem. Commun. 14, 1720 (2003); (c) J.G. Mao, Z.K. Wang, A. Clearfield, Inorg. Chem. 41, 3713 (2002); (d) C.V. Krishnamohan Sharma, C.C. Chusuei, R. Clérac, T. Mǒller, K.R. Dunbar, A. Clearfield, Inorg. Chem. 42, 8300 (2003); (e) D.K. Cao, Y.Z. Li, Y. Song, L.M. Zheng, Inorg. Chem. 44, 3599 (2004)Google Scholar
  5. 5.
    (a) P. Yin, X.C. Wang, S. Gao, L.M. Zheng, J. Solid State Chem. 178, 1049 (2000); (b) D.G. Ding, M.C. Yin, H.J. Lu, Y.T. Fan, H.W. Hou, Y.T. Wang. J. Solid State Chem. 179, 747 (2006); (c) M. Li, S.P. Chen, J.F. Xiang, H.J. He, L.J. Yuan, J.T. Sun, Cryst. Growth Des. 6, 1250 (2006); (d) M. Li, J.F. Xiang, S.M. Wu, S.P. Chen, L.J. Yuan, H. Li, H.J. He, J.T. Sun, J. Molecu. Struc. (In press); (e) M. Li, J.F. Xiang, S.P. Chen, S.M. Wu, L.J. Yuan, H. Li, H.J. He, J.T. Sun, J. Coord. Chem. (In press)Google Scholar
  6. 6.
    B.J. Chai, W. Covina, F.D. Muggee, Anaheim, U.S. Patent 4239695 Google Scholar
  7. 7.
    G.M. Sheldrick, SHEXTL(Xprep, SADABS, XS, XL) Crystallographic Software Package, Version 5.1; Bruker-AXS: Madison, WI, 1998Google Scholar
  8. 8.
    T.K. Prasad, M.V. Rajasekharan, Inorg. Chem. Commun. 8, 1116 (2005)CrossRefGoogle Scholar
  9. 9.
    D. Kong, A. Clearfield, J. Zoń, Cryst. Growth Des. 5, 1767 (2005)CrossRefGoogle Scholar
  10. 10.
    A. Cabeza, M.A.G. Aranda, S. Bruque, D.M. Poojary, A. Clearfiled, J. Sanz, Inorg. Chem. 37, 4148 (1998)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Shuo-ping Chen
    • 1
  • Ming Li
    • 1
  • Qiao-lan Chen
    • 1
  • Yan Guo
    • 1
  • Si-min Wu
    • 1
  • Liang-jie Yuan
    • 1
  • Ju-tang Sun
    • 1
  1. 1.College of Chemistry and Molecular SciencesWuhan UniversityWuhanP.R. China

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