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Two Novel Metal Phosphonate Compounds: Different One-Dimension Chain Structures Constructed by Imidazole and 1-Aminoethylidenediphosphonic Acid

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Abstract

Hydrothermal reactions of 1-aminoethylidenediphosphonic acid (AEDPH4), imidazole (Im) and divalent metal oxides afforded two novel phosphonate compounds: Zn2(AEDP)(Im)3·H2O (1), Cd3(AEDPH)2(Im)5·Im (2). Compounds 1 and 2 are both one-dimensional (1-D) coordination polymers that illustrate different chain motifs. Compound 1 features a zigzag double chain structure while compound 2 has a distorted square-chain structure. Both compounds are further extended to form three-dimensional (3-D) supramolecular structures via hydrogen bonds. The effect of degree of deprotonization of AEDPH4 on the structural types of the final products is also discussed.

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Acknowledgements

This work was supported by grants of the National Nature Science Foundation of China (No. 20671074).

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Authors and Affiliations

  1. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, P.R. China

    Shuo-ping Chen, Ming Li, Qiao-lan Chen, Yan Guo, Si-min Wu, Liang-jie Yuan & Ju-tang Sun

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  1. Shuo-ping Chen
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  2. Ming Li
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Correspondence to Liang-jie Yuan.

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10904_2007_9154_MOESM1_ESM.doc

MOESM 1: Schematic view of the unit cell linking of compound 1 by hydrogen bonds. Dashed lines represent hydrogen bonds. (DOC 185 kb)

10904_2007_9154_MOESM2_ESM.doc

MOESM 2: Schematic view of the unit cell linking of compound 2 by hydrogen bonds. Dashed lines represent hydrogen bonds. (DOC 221 kb)

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Chen, Sp., Li, M., Chen, Ql. et al. Two Novel Metal Phosphonate Compounds: Different One-Dimension Chain Structures Constructed by Imidazole and 1-Aminoethylidenediphosphonic Acid. J Inorg Organomet Polym 17, 665–672 (2007). https://doi.org/10.1007/s10904-007-9154-z

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  • DOI: https://doi.org/10.1007/s10904-007-9154-z

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