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New Approaches to Hybrid Polymers that Contain Phosphazene Rings

  • Harry R. Allcock
Article

Abstract

New methods are described for the incorporation of cyclophosphazene rings into macromolecules. These include polynorbornenes with cyclophosphazene side units produced by ROMP reactions, polystyrenes linked to phosphazene rings by azide coupling processes, and cyclolinear polymers by ADMET and Heck coupling reactions. These last species are wavelength-emission tailored electroluminescent materials.

Keywords

Cyclophosphazene hybrid polymers electroluminescence ROMP ADMET 

Notes

Acknowledgments

We thank the Federal Aviation Authority, NASA Glen Research Center, The National Science Foundation, and the Dow Chemical Co. for support of this work.

References

  1. 1.
    Neuse E. W., Rosenberg H. J. (1970) Macromol. Sci. – Revs. Macromol. Chem. C4:1Google Scholar
  2. 2.
    Patterson W. J., McManus S. P., Pittman C. U. (1974) J. Polym. Sci. 12:837Google Scholar
  3. 3.
    Carraher C. E., Sheats J. E., Pittman C. U. (eds.) (1978) Organometallic Polymers. Academic Press, New YorkGoogle Scholar
  4. 4.
    C. U. Pittman, Organometallic Polymers. Academic Press, New York (1978)Google Scholar
  5. 5.
    G. F. Hayes, M. H. George, Organometallic Polymers. Academic Press, New York (1978)Google Scholar
  6. 6.
    Hayes G. F., George M. H. (1975) J. Polym. Sci Polym Ed. ed. 13:1049Google Scholar
  7. 7.
    Pittman C. U., Roundsefell T. D. (1976) Macromolecules 9:936CrossRefGoogle Scholar
  8. 8.
    Nuyken O, Burkhardt V, Hubsch C. (1997) Macromol Chem. Phys. 198:3353CrossRefGoogle Scholar
  9. 9.
    Filippova V. G., Nemetkin N. S., Durgayan S. G. (1966) Russ. Chem. B+ 15:1670CrossRefGoogle Scholar
  10. 10.
    Topchiev A. V., Nametkin N. S., Hsiao-pei C., Durgaryan S. G., Zavyalov V. I. (1963) Russ. Chem. B+ 12:244–249CrossRefGoogle Scholar
  11. 11.
    Allcock H. R., Kugel R. L. (1963) J. Polymer Sci. A 1:3627Google Scholar
  12. 12.
    L. Cong and C. W. Allen. Phosphorus, Sulfur, and Silicon (Proc. 10th Int. Symposium on Inorganic Ring Systems), Allen C. W. ed., 179, 961 (2004)Google Scholar
  13. 13.
    Allen C. W., Shaw J. C. (1987) Phosphorus Sulfur 30:97Google Scholar
  14. 14.
    Allen C. W., Bahadur M. (1993) Phosphorus Sulfur Silicon. 76:203Google Scholar
  15. 15.
    Allen C. W., Brown D. E., Carter K. R. (1989) Phosphorus Sulfur Silicon 41:311Google Scholar
  16. 16.
    Allen C. W., DuPont J. F. (1979) Ind Eng. Chem. Prod. Res. Dev. 18:80CrossRefGoogle Scholar
  17. 17.
    Allen C. W. (1983) J. Polym. Sci. Polym. Symp. 70:79CrossRefGoogle Scholar
  18. 18.
    Allen C. W., Bright R. P. (1986) Macromolecules 19:571CrossRefGoogle Scholar
  19. 19.
    Allen C. W., Shaw J. C. (1987) Phosphorus, Sulfur & Silicon 30:97Google Scholar
  20. 20.
    Allen C. W. (1988) ACS Symp. Ser. 360:290CrossRefGoogle Scholar
  21. 21.
    DuPont J. G., Allen C. W. (1979) Macromolecules 12:169CrossRefGoogle Scholar
  22. 22.
    Allen C. W., Shaw J. C., Brown D. E. (1988) Macromolecules 21:2653CrossRefGoogle Scholar
  23. 23.
    Allen C. W. (1994) Coord. Chem. Rev. 130:173CrossRefGoogle Scholar
  24. 24.
    Allen C. W., Brown D. E., Hayes R. F., Tooze R., Poyser L. (1994) ACS Symp Ser 572:389Google Scholar
  25. 25.
    Allen C. W., Ramachandran K., Brown D. E. (1989) Inorg. Synth. 25:74CrossRefGoogle Scholar
  26. 26.
    C. W. Allen. The Chemistry of Inorganic Ring Systems (R. Steudel, ed.), (Elsevier Science Publ, 1992). 14 Chap. 10, p.171Google Scholar
  27. 27.
    Allen C. W., Bahadur M. (1998) J. Inorg. Orgmet. Polym. 8:23–31CrossRefGoogle Scholar
  28. 28.
    Inoue K., Nakano M., Takagi M., Tanigaki T. (1989) Macromolecules 22:1530CrossRefGoogle Scholar
  29. 29.
    Inoue K., Kinoshita K., Nakahara H., Tanigaki T. (1990) Macromolecules 23:1227CrossRefGoogle Scholar
  30. 30.
    Bosscher G., de Vries G. P., van de Grampel J. C. (1994) Phosphorus, Sulfur Silicon 93–94:419Google Scholar
  31. 31.
    Bosscher G., van de Grampel J. C. (1995) J. Inorg. Organomet. Polym. 5:209CrossRefGoogle Scholar
  32. 32.
    Bosscher G., Jekel A. P., van de Grampel J. C. (1997) J. Inorg. Organomet Polym. 7:19CrossRefGoogle Scholar
  33. 33.
    Bosscher G., Wieninga R. H., Jekel A. P., van de Grampel J.C. (1996) J. Inorg Organomtl. Polym. 6:255CrossRefGoogle Scholar
  34. 34.
    Dez I., De Jaeger R. (1997) Macromolecules 30:8262CrossRefGoogle Scholar
  35. 35.
    Allcock H. R., Laredo W. R., de Denus C. R., Taylor J. P. (1999) Macromolecules 32:7719–7725CrossRefGoogle Scholar
  36. 36.
    Allcock H. R., Laredo W. R., Kellam E. C., Morford R. V. (2001) Macromolecules 34:787–794CrossRefGoogle Scholar
  37. 37.
    Allcock H. R., Laredo W. R., Morford R. V. (2001) Solid. State. Ionics 139:27–36CrossRefGoogle Scholar
  38. 38.
    Allcock H. R., de Denus C. R., Prange R., Laredo W. R. (2001) Macromolecules 34:2757CrossRefGoogle Scholar
  39. 39.
    Stone D. A., Welna D. T., Allcock H. R. (2004) Polym. Preprints 45:696Google Scholar
  40. 40.
    Allcock H. R., Welna D. T., Stone D. A. Powell E. S., Wood R., Kwak G. (2005) Polym. Preprints 93:782Google Scholar
  41. 41.
    Welna D. T., Stone D. A., Allcock H. R. (2005) Polym. Preprints 46(2):1055Google Scholar
  42. 42.
    Allcock H. R., Welna D. T., Stone D. A. (2005) Macromolecules 38:10406CrossRefGoogle Scholar
  43. 43.
    D. T. Welna, D. A. Stone, H. R. Allcock, Chemistry of Materials (2006), in pressGoogle Scholar
  44. 44.
    Stone D. A., Allcock H. R. (2006) Macromolecules 39:4935CrossRefGoogle Scholar
  45. 45.
    Allcock H. R., Welna D. T., Stone D. A. (2005) Macromolecules 38:10406CrossRefGoogle Scholar
  46. 46.
    Hartle T. J., Sunderland N. J., McUntosh M. B., Allcock H. R. (2000) Macromolecules 33:4307CrossRefGoogle Scholar
  47. 47.
    Allcock H. R., Hartle T. J., Taylor J. R., Sunderland N. J. (2001) Macromolecules 34:3896CrossRefGoogle Scholar
  48. 48.
    Allcock H. R., McIntosh M. B, Hartle T. J. (1999) Inorg. Chem. 38:5535CrossRefGoogle Scholar
  49. 49.
    Allcock H. R., Kellam E. C., Hofmann M. A. (2001) Macromolecules 34:5140CrossRefGoogle Scholar
  50. 50.
    Allcock H. R., Kellam E. C. (2002) Macromolecules 35:40CrossRefGoogle Scholar
  51. 51.
    Stone D. A., Chang Y., Allcock H. R. (2006) J Polymer Sci Part A 44:69CrossRefGoogle Scholar
  52. 52.
    Allcock H. R. (2003) Chemistry and Applications of Polyphosphazenes. Wiley-Interscience, Hoboken NJGoogle Scholar
  53. 53.
    D. A. Stone, D. T. Welna, and H. R. Allock, Chemistry of Material, in press (2007)Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  1. 1.Department of ChemistryThe Pennsylvania State UniversityUniversity ParkUSA

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