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Syntheses and Structural Characterization of Triorganotin Derivatives of 3-Mercapto-4-methyl-4H-1,2,4-triazol: X-ray Crystal Structures of One-dimensional Zigzag Polymeric chain of Me3Sn[SC3H4N3] and Ph3Sn[SC3H4N3]

  • Chunlin Ma
  • Guangru Tian
  • Rufen Zhang
Article

The triorganotin derivatives of 3-mercapto-4-methyl-4H-1,2,4-triazol, R3Sn[SC3H4N3] (R = Me 2, n-Bu 3, Ph 4, PhCH2 5), have been synthesized and characterized by IR and NMR spectroscopy. Among them, complexes 2 and 4 were also characterized by X-ray crystallography diffraction analyses, which revealed that both 2 and 4 show one-dimensional zigzag polymeric chain structure in which the geometries of tin atoms are both trigonal bipyramid with the axial positions occupied by sulfur and nitrogen atoms.

Keywords

Triorganotin derivatives 3-mercapto-4-methyl-4H-1,2,4-triazol crystal structures 

Notes

Acknowledgments

We thank the National Natural Science Foundation of China (20271025) for financial support.

References

  1. 1.
    M. S. Vratsanos in Polymeric materials encyclopedia, 9., J. C. Salmone, ed. (CRC Press, Boca Raton, 1996).Google Scholar
  2. 2.
    (a) J. A. Deiters and R. R. Holmes, J. Am. Chem. Soc. 109 1686 (1987). (b) K. C. Molloy, S. J. Blunden, and R. Hill, J. Chem. Soc., Dalton Trans. 1259 (1988). (c) S. Bhandari, M. F. Mahon, J. G. Mc Ginley, K. C. Molloy, and C. E. E. Roper, J. Chem. Soc., Dalton Trans. 3425 (1998).Google Scholar
  3. 3.
    (a) C. L. Ma, Q. Jiang, and R. F. Zhang, J. Organomet. Chem. 678, 148 (2003). (b) C. L. Ma and J. F. Sun, Polyhedron, 23 1547 (2004). (c) C. L. Ma, F. Li, Q. Jiang, and R. F. Zhang, J. Organomet. Chem. 689, 96 (2004).Google Scholar
  4. 4.
    (a) R. J. Deeth, K. C. Molloy, M. F. Mahon, and S. Whittaker, J. Organoment. Chem. 430, 25 (1992). (b) O. Jiménez-Sandoval, R. Cea-Olivares and S. Hernández-Ortega, Polyhedron 16, 4129 (1997).Google Scholar
  5. 5.
    Sisido K., Takeda Y., Kinugawa Z. (1961) J. Am. Chem. Soc. 83:538CrossRefGoogle Scholar
  6. 6.
    George T. A. (1971) J. Organomet. Chem. 31:233CrossRefGoogle Scholar
  7. 7.
    May J. R., Mc Whinnie W. R., Poller R. C. (1971) Spectrochim. Acta A 27:969CrossRefGoogle Scholar
  8. 8.
    C. Pettinari, F. Marchetti, R. Pettinari, D. Martini, A. Drozdov, and S. Troyanov, Inorganica Chimica Acta. 325, 103 (2001) and references thereinGoogle Scholar
  9. 9.
    (a) C. Pettinari, F. Marchetti, R. Pettinari, D. Martini, A. Drozdov, and S. Troyanov, J. Chem. Soc., Dalton Trans. 1790 (2001). (b) R. R. Holmes, C. G. Schmid, V. Chandrasekhar, R. O. Day, and J. M. Homels, J. Am. Chem. Soc. 109, 1408 (1987)Google Scholar
  10. 10.
    J. S. Casas, A. Castiñeiras, M. D. Couce, N. Playá, U. Russo, A. Sánchez, J. Sordo, and J. M. Varela, J. Chem. Soc., Dalton Trans. 1513 (1998)Google Scholar
  11. 11.
    Poller R. C. (1970) The Chemistry of Organotin Compounds. Logos Press, LondonGoogle Scholar
  12. 12.
    James B. D., Magee R. J., Patalinghug W. C., Skelton B. W., White A. H. (1994) J. Organomet. Chem. 467:51CrossRefGoogle Scholar
  13. 13.
    Casas J. S., Castineiras A., Martinez E. G., González A. S., Sánchez A., Sordo J. (1997) Polyhedron 16:795CrossRefGoogle Scholar
  14. 14.
    Vrabel V., Lokaj J., Kello E., Garaj J., Batsanov A. C., Struchkov Yu. T. (1992) Acta Crystallogr. C 48:633CrossRefGoogle Scholar
  15. 15.
    Allen F. H., Bellard S. A., Brice M. D., Cartwright B. A., Doubleday A., Higgs H., Hummelink T., Hummelink-Peters B. G., Kennard O., Motherwell W. D .S., Rogers J. R., Watson D. G. (1979) Acta Crystallogr. B 35:2331CrossRefGoogle Scholar
  16. 16.
    Huheey J. E., Keiter E. A., Keiter R. L. (1993) Principles and Applications of Inorganic Chemistry, 4th ed. Harper Collins, New YorkGoogle Scholar
  17. 17.
    Ma C. L., Zhang J. H., Tian G. R., Zhang R. F. (2005) J. Organomet. Chem. 690:519CrossRefGoogle Scholar
  18. 18.
    (a) G. F. de Sousa, V. M. Deflon, and E. Niquet, J. Mol. Struct. 687, 17 (2004); (b) N. Singh, S. Gupta, and G. Nath, Appl. Organomet. Chem.14, 484 (2000)Google Scholar
  19. 19.
    F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen, and R. Taylor, J. Chem. Soc., Perkintrans. II S1 (1987)Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  1. 1.Department of ChemistryLiaocheng UniversityLiaochengP.R. China
  2. 2.Department of ChemistryTaishan UniversityTaianP.R. China

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