Synthesis and Properties of Novel Selenium containing Polyimides with Various Dianhydrides

  • Süleyman Köytepe
  • Turgay Seçkin
  • Engin Çetinkaya
  • Yetkin Gök


Novel selenium-containing polyimides were prepared from bis(1,3-di-p-dimethylaminobenzylpyrimidine- 2-selenon) and bis(1,3-di-p-dimethylaminobenzyldiazepane-2-selenon) and with various aromatic dianhydrides in a one-stage polycondensation at high temperature in N-methyl-2-pyrrolidone. The polyimides have inherent viscosities that range from 1.55 to 2.05 dL/g in NMP at 30°C. These polymers showed glass transition temperatures between 188 and 268°C, and an initial decomposition temperature from 421 to 502°C with a 10% mass loss occurring from 480 to 547°C in air.


Polyimides functional polymers metal containing polymers selenium 


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  1. 1.
    Mittal, K. L. 1984Polyimides: Synthesis, Characterization and Applications Vols. 1 & 2PlenumNew YorkGoogle Scholar
  2. 2.
    Bessonov, M. T., Koton, M. M., Kudryavtsev, V. V., Laius, L. A. 1987Polyimides: Thermally Stable PolymersConsultants BureauNew YorkGoogle Scholar
  3. 3.
    Wilson, D., Stenzenberger, H. D., Hergenrother, P. M. 1990PolyimidesBlackieGlasgowGoogle Scholar
  4. 4.
    Ghosh, M. K., Mittal, K. L. 1996Polyimides: Fundamentals and ApplicationsMarcel DekkerNew YorkGoogle Scholar
  5. 5.
    Oishi, Y., Ishida, M., Kakimoto, M., Imai, Y., Kurosaki, T. 1992J. Polym Sci. Part A: Polym. Chem301027CrossRefGoogle Scholar
  6. 6.
    Kakimoto, M., Akiyama, R., Negi, Y. S., Imai, Y. 1988J. Polym. Sci. Part A: Polym. Chem2699CrossRefGoogle Scholar
  7. 7.
    Hsiao, S. H., Chen, W. T. 2003J. Polym. Res1095CrossRefGoogle Scholar
  8. 8.
    Yamanaka, K., Jikei, M., Kakimoto, M. A. 2000Macromolecules336937CrossRefGoogle Scholar
  9. 9.
    Fang, J., Kita, H., Okamoto, K.-I. 2000Macromolecules334639CrossRefGoogle Scholar
  10. 10.
    Seino, H., Mochizuki, A., Ueda, M. 1999J. Polym. Sci. Part A: Polym. Chem.373584CrossRefGoogle Scholar
  11. 11.
    Tamai, S., Yamashita, A., Yamaguchi, A. 1998J. Polym. Sci. Part A: Polym. Chem361717CrossRefGoogle Scholar
  12. 12.
    Kim, H.-S., Kim, Y.-H., Ahn, S.-K., Kwon, S.-K. 2003Macromolecules362327CrossRefGoogle Scholar
  13. 13.
    Yang, C. P., Hsiao, S. H., Hsu, M. F. 2002J. Polym. Sci. Part A: Polym. Chem404, 524Google Scholar
  14. 14.
    Park, S. K. 2000Eur. Polym. J362621CrossRefGoogle Scholar
  15. 15.
    Hou, H. 1999Eur. Polym. J351993CrossRefGoogle Scholar
  16. 16.
    Dabral, M., Xia, X., Gerberich, W. W., Francis, L. F., Scriven,  L. E. 2001J. Polym. Sci. Part B: Polym. Phys391824CrossRefGoogle Scholar
  17. 17.
    Stoffel, N. C., Jramer, K. E., Volksen, W. I., Russell, T. P. 1998 J. Polym. Sci. Part B: Polym. Phys362247CrossRefGoogle Scholar
  18. 18.
    Reddy, D. S., Shu, C. F., Wu, F. I. 2002J. Polym. Sci.: Part A: Polym. Chem402262Google Scholar
  19. 19.
    Liu, J. G., He, M. H., Zhou, H. W., Qian, Z. G., Wang, F. S., Yang, S. Y. 2002J. Polym. Sci. Part A: Polym. Chem40110CrossRefGoogle Scholar
  20. 20.
    Seçkin, T., Çetinkaya, E., Köytepe, S., Yigit, B. 2003Polym. Bull50139CrossRefGoogle Scholar
  21. 21.
    Seçkin, T., Köytepe, S., Ozdemir, I. 2003Designed Monomers and Polymers6175CrossRefGoogle Scholar
  22. 22.
    Kannan, P., Sudhakar, S., Swaminathan, C. S., Murugavel, S. C. 1996J. Polym. Sci. Part A: Polym. Chem343559CrossRefGoogle Scholar
  23. 23.
    J. G. de la Campa, , Tauler, C., Lozano, A. E., Abajo, J. 1994Macromol. Rapid Commun15417CrossRefGoogle Scholar
  24. 24.
    Liaw, D. J., Liaw, B. Y., Yang, C. M. 1999Acta Polym50332CrossRefGoogle Scholar
  25. 25.
    Yang, C. P., Hasiao, S. H., Yang, H. W. 2000Macromol. Chem. Phys201409CrossRefGoogle Scholar
  26. 26.
    Zubkov, V. A., Koton, M. M., Kudryavtsev, V. V., Svetlichnyi,  V. M. 1981Zh. Org. Khim171501Google Scholar
  27. 27.
    Ardashnikov, A. Y., Kardash, I. Y., Pravednikov, A. N 1971Polym. Sci. USSR132092CrossRefGoogle Scholar
  28. 28.
    Koton, M. M., Kudryavtsev, V. V., Adrova, N. A., Kalnin, K. K., Dubnova, A. M., Svetlichnyi, V. M. 1974Polym. Sci. USSR162411CrossRefGoogle Scholar
  29. 29.
    Seçkin, T., Köytepe, S., Demir, S., Ozdemir, I., Çentinkaya, B. 2003J. Inorg. Organometal. Polym13223CrossRefGoogle Scholar
  30. 30.
    Seçkin, T., Köytepe, S., Ozdemir, I., Çetinkaya, B. 2003J. Inorg. Organometal. Polym139CrossRefGoogle Scholar
  31. 31.
    Seçkin, T., Ozdemir, I., Çetinkaya, B., Köytepe, S. 2002J. Mol. Cat. A: Chem179263CrossRefGoogle Scholar
  32. 32.
    Vora, R. H., Goh, S. H., Chung, T. S. 2000Polym. Eng. Sci401318CrossRefGoogle Scholar
  33. 33.
    Yang, C. P., Hsiao, S. H., Yang, H. Y. 2000Mat. Chem. Phys64116CrossRefGoogle Scholar
  34. 34.
    Yang, C. P., Hsiao, F. Z. 2003J. Polym. Res10181CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • Süleyman Köytepe
    • 1
  • Turgay Seçkin
    • 1
  • Engin Çetinkaya
    • 2
  • Yetkin Gök
    • 1
  1. 1.Faculty of Science and Literature, Chemistry DepartmentInonu UniversityMalatyaTurkey
  2. 2.Faculty of Science, Chemistry DepartmentEge UniversityIzmirTurkey

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