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Synthesis and Properties of Novel Selenium containing Polyimides with Various Dianhydrides

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Abstract

Novel selenium-containing polyimides were prepared from bis(1,3-di-p-dimethylaminobenzylpyrimidine- 2-selenon) and bis(1,3-di-p-dimethylaminobenzyldiazepane-2-selenon) and with various aromatic dianhydrides in a one-stage polycondensation at high temperature in N-methyl-2-pyrrolidone. The polyimides have inherent viscosities that range from 1.55 to 2.05 dL/g in NMP at 30°C. These polymers showed glass transition temperatures between 188 and 268°C, and an initial decomposition temperature from 421 to 502°C with a 10% mass loss occurring from 480 to 547°C in air.

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Authors and Affiliations

  1. Faculty of Science and Literature, Chemistry Department, Inonu University, Malatya, 44069, Turkey

    Süleyman Köytepe, Turgay Seçkin & Yetkin Gök

  2. Faculty of Science, Chemistry Department, Ege University, Izmir, Turkey

    Engin Çetinkaya

Authors
  1. Süleyman Köytepe
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  2. Turgay Seçkin
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  3. Engin Çetinkaya
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  4. Yetkin Gök
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Corresponding author

Correspondence to Turgay Seçkin.

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Köytepe, S., Seçkin, T., Çetinkaya, E. et al. Synthesis and Properties of Novel Selenium containing Polyimides with Various Dianhydrides. J Inorg Organomet Polym 15, 269–279 (2005). https://doi.org/10.1007/s10904-005-5544-2

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  • DOI: https://doi.org/10.1007/s10904-005-5544-2

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