Abstract
Alcoholic strength is a fundamental variable in industry production and its determination is crucial in technological developments. This study offers a novel strategy for fluorescent sensing of alcoholic content based on a terbium coordination complex. In pure water, the emissive compound displays blue luminescence. However, the addition of ethanol into the aqueous solution has induced the recovery of terbium green emissions. In another case, the achieved Eu(III)-phenanthroline complex shows high sensitivity to solvent polarity and the detection of trace amount of water can be realized through an “on-off” change with a low detection limit of 32.4 ppm.
References
Deng J, Shi G, Zhou T (2016) Colorimetric assay for on-the-spot alcoholic strength sensing in spirit samples based on dual-responsive lanthanide coordination polymer particles with ratiometric fluorescence. Anal Chim Acta 942:96–103
Lin JT, Zheng YH, Wang QM, Zeng Z, Zhang CC (2014) Novel lanthanide pH fluorescent probes based on multiple emissions and its visible-light-sensitized feature. Anal Chim Acta 839:51–57
Xu J, Shen X, Jia L, Zhang M, Zhou T, Wei Y (2016) Facile ratiometric fluorapatite nanoprobes for rapid and sensitive bacterial spore biomarker detection. Biosens Bioelectron 87:991–997
Kumar B, Rai G (2016) Acetylsalicylic acid sensitized lasing luminescence of terbium complex in PVA: a case of energy avalanche via 1, 10-Phenanthroline. J Photochem Photobiol A Chem 332:413–421
Wang ZS, Zhang CC, Gao JW, Wang QM (2017) Copper clusters-based luminescence assay for tetracycline and cellular imaging studies. J Lumin 190:115–122
Sharma G, Narula AK (2015) Eu3+, Yb3+ and Eu3+ -Yb3+ complexes with salicylic acid and 1,10-Phenanthroline: synthesis, Photoluminescent properties and energy transfer. J Fluoresc 25:355–360
Bretonniere Y, Cann MJ, Parker D, Slater R (2004) Design, synthesis and evaluation of ratiometric probes for hydrogencarbonate based on europium emission. Org Biomol Chem 2:1624–1632
Wu W, Rong Y, Zhao B, Sun PP, Huang XH (2010) The study on the interaction between Tb(III) and ligand in Tb–acetylsalicylic acid complex and fluorescence mechanism. J Lumin 130:92–95
Hassanzadeh R, Lotfi A, Bagheri N, Bagheri N, Hassanzadeh J (2016) Ultrasensitive and rapid determination of folic acid using ag nanoparticles enhanced 1, 10-Phenantroline-terbium (III) sensitized fluorescence. J Fluoresc 26:1875–1883
Wen Q, Yang JL, Li SR, Gao JW, Lu XB, Wang QM (2017) Micropatterning of lanthanide compelx species onto self-cracking flexible transparent films and their photophysical properties. Mater Res Bull 88:98–104
Lin JT, Yang JL, Gao JW, Wang QM (2016) Template synthesis structure optical and catalytic properties derived from novel cadmium tungstates. Polyhedron 113:102–108
Yu AW, Zeng Z, Luo Q, Gao JW, Wang QM (2018) Establishment of a new analytical platform for glucose detection based on a terbium containing silica hybrid nanosensor. Appl Surf Sci 462:883–889
Chen MH, Wen Q, Gu FL, Gao JW, Zhang CC, Wang QM (2018) Mussel-chemistry assembly of a novel biosensing nanoplatform based on polydopamine fluorescent dot and its photophysical features. Chem Eng J 342:331–338
Tan HL, Zhang L, Ma CJ, Song YH, Xu FG, Chen SH, Wang L. (2013) Terbium-based coordination polymer nanoparticles for detection of ciprofloxacin in tablets and biological fluids. ACS applmaterinter 5: 11791–96
Lin JT, Zeng Z, Ma QM, Wang QM, Zhang YH (2014) Effects of multiple irradiations on luminescent materials and energy savings – a case study for the synthesis of BaMO4: ln3+ (M = W, Mo; Ln = Eu, Tb) phosphors. Energy 64:551–556
Eliseeva SV, Bunzli JCG (2010) Lanthanide luminescence for functional materials and bio-sciences. Chem Soc Rev 39:189–227
Vino Mohan AM, Windmiller JR, Mishra RK, Wang J (2017) Continuous minimally invasive alcohol monitoring using microneedle sensor arrays. Biosens Bioelectron 91:574–579
Zhou TT, Zhang T, Zhang R, Deng JN, Lou Z, Lu GY, Wang LL (2017) High sensitive sensing platform based on ZnSnO3 hollow cubes for detection of ethanol. Appl Surf Sci 400:262–268
Stathatos E, Lianos P, Evgeniou E, Keramidas AD (2003) Electroluminescence by a Sm3+-diketonate-phenanthroline complex. Synthetic Met 139:433–437
Lenaerts P, Gorller-Walrand C, Binnemans K (2006) Luminescent europium(III) and terbium (III) nicotinate complexes covalently linked to a 1,10-phenanthroline functionalized sol-gel glass. J Lumin 117:163–169
Gao F, Luo FB, Chen XX, Yao W, Yin J, Yao Z, Wang L (2009) Fluorometric determination of water in organic solvents using europium ion-based luminescent nanospheres. Microchim Acta 166:163–167
Wang TR, Li HR (2016) A red-emitting luminescent material capable of detecting low water content in organic solvents. Chem Eur J 22:12400–12405
Acknowledgements
Y. H. appreciates Research fund of higher education committee of Guangdong province (GDJ2016003) and Guangdong Science and Technology plan (2016A050502053).
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
ESM 1
(DOCX 132 kb)
Rights and permissions
About this article
Cite this article
Lu, D., Tang, Y. & Zheng, Y. Fluorescence Sensing Behavior for the Detection of Alcoholic Strength and Water Based on Two Novel Metallic Complex Edifices. J Fluoresc 28, 1269–1273 (2018). https://doi.org/10.1007/s10895-018-2300-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10895-018-2300-x