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Structural and Luminescence Properties of Sm3+ Doped TTB -Type BaTa2O6 Ceramic Phosphors

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Abstract

Pure and 0.5 to 10 mole% Sm3+ doped TTB (tetragonal tungsten bronze)-type BaTa2O6 ceramic phosphor was produced by the solid state reaction method which performed at 1425 °C for 20 h. XRD and SEM analysis indicated single TTB phase for undoped and 0.5 to 10 mole% Sm3+ doped BaTa2O6 structures. SEM also showed that the BaTa2O6 grain size decreased with the increasing content of Sm3+. Optical analysis indicated significant emissions in the visible spectral region as green (λ = 562.7 nm) and orange-reddish (λ = 597.1 nm). The emission intensity increased with the increasing doping concentration up to 2.5 mole%, and then decreased due to the concentration quenching effect.

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Acknowledgments

The authors would like to thanks to Marmara University Research Fund (BAPKO) for supporting this research. Project No. FEN-A-150513-0167

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Correspondence to Mete Kaan Ekmekçi.

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Ekmekçi, M.K., İlhan, M., Başak, A.S. et al. Structural and Luminescence Properties of Sm3+ Doped TTB -Type BaTa2O6 Ceramic Phosphors. J Fluoresc 25, 1757–1762 (2015). https://doi.org/10.1007/s10895-015-1663-5

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  • DOI: https://doi.org/10.1007/s10895-015-1663-5

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