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Detection of HSO4 − Ion Based on the Hydrolysis of Diketopyrrolopyrrole-derived Schiff Base with Chromogenic and Fluorogenic Dual Signals

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Abstract

A new diketopyrrolopyrrole-based Schiff base L was synthesized and its anion sensing behavior was explored. L showed exclusive response toward HSO4 − ion and also distinguished HSO4 − from other anions by color changes (from dark red to orange) and 21 fold fluorescence enhancement at 370 nm in aqueous solution (THF/H2O = 8/1, v/v). The sensing mechanism was suggested to proceed via a hydrolysis process. The results provided colorimetric and fluorimetric assays to selectively detect the presence of a HSO4 − over a wide range of other interfering anions. The results could potentially be used as a dual colorimetric-fluorescent probe for monitoring HSO4 − levels in physiological and environmental systems.

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Acknowledgments

The supports by National Natural Science Foundation of China (No. 21274045), the Pearl River in Guangzhou city of Nova of Science and Technology Special Funded Projects (No. 2012J2200009), the Fundamental Research Funds for the Central Universities (2013ZZ067), the Natural Science Foundation of Guangdong Province (10351064101000000) and National Basic Research Program of China (2012CB720801) are gratefully acknowledged.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China, 510640

    Lingyun Wang, Lingling Yang & Derong Cao

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  1. Lingyun Wang
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  2. Lingling Yang
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  3. Derong Cao
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Correspondence to Lingyun Wang.

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Wang, L., Yang, L. & Cao, D. Detection of HSO4 − Ion Based on the Hydrolysis of Diketopyrrolopyrrole-derived Schiff Base with Chromogenic and Fluorogenic Dual Signals. J Fluoresc 24, 1347–1355 (2014). https://doi.org/10.1007/s10895-014-1421-0

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  • DOI: https://doi.org/10.1007/s10895-014-1421-0

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